New directions in solid state chemistry : structure, synthesis, properties, reactivity and materials design

목차 (Table of Contents)

• CONTENTS
• Preface = ⅸ
• 1 Structure of solids : old and new facets = 1
• 1.1 Introduction = 1
• 1.2 Description of crystals = 2
• 1.3 Bonding in crystals = 4
• 1.4 Inorganic structures = 13
• 1.5 Silicates and aluminosilicates = 34
• 1.6 Nonbonded interactions in ionic crystals = 39
• 1.7 New ways of looking at the structures of inorganic solids = 42
• 1.8 Polytypism = 50
• 1.9 Organic crystal structures = 53
• 1.10 Inclusion compounds and clathrates = 56
• 1.11 Noncrystalline or amorphous solids = 60
• 1.12 Quasicrystals = 65
• 1.13 Models and graphics = 65
• 1.14 Solitons = 66
• 2 New and improved methods of characterization = 67
• 2.1 Introduction = 67
• 2.2 Structural characterization = 68
• 2.2.1. X-ray diffraction = 70
• 2.2.2. Electron diffraction = 71
• 2.2.3. Neutron diffraction and related techniques = 73
• 2.2.4. Electron microscopy = 75
• 2.2.5. X-ray absorption spectroscopy(EXAFS and XANES) = 84
• 2.2.6. Nuclear magnetic resonance spectroscopy(MASNMR) = 95
• 2.2.7. Electron spectroscopies = 99
• 2.2.8. Other spectroscopic techniques = 105
• 2.2.9. Concluding remarks = 106
• 2.3 Characterization of composition and purity = 107
• 3 Preparative strategies = 112
• 3.1 Introduction = 112
• 3.2 Preparation of crystalline materials = 116
• 3.2.1. Ceramic methods = 116
• 3.2.2. Chemical methods = 118
• 3.2.3. High pressure methods = 124
• 3.2.4. Arc techniques = 130
• 3.2.5. Skull melting = 132
• 3.2.6. Chemical vapour deposition(CVD) = 132
• 3.2.7. Synthesis of organic solids = 133
• 3.3 Microcrystalline particles and clusters(the finite solid state) = 136
• 3.4 Amorphous materials = 137
• 3.5 Crystal growth = 139
• 4 Phase transitions = 148
• 4.1 Introduction = 148
• 4.2 Thermodynamics = 148
• 4.3 Soft modes = 153
• 4.4 Central peaks = 156
• 4.5 Critical phenomena = 157
• 4.6 Structural changes in phase transitions = 158
• 4.7 Mechanisms of phase transitions = 161
• 4.8 Organic solids = 164
• 4.9 Incommensurate phases = 166
• 4.10 Cooperative Jahn-Teller effect = 176
• 4.11 Spin-state transitions = 181
• 4.12 The plastic crystalline state = 190
• 4.13 The liquid crystalline state = 195
• 4.14 Noncrystalline state and the glass transition = 200
• 4.15 Monte Carlo and molecular dynamics methods = 204
• 4.16 Applications of phase transitions = 206
• 5 New light on an old problem : defects and nonstoichiometry = 208
• 5.1 Introduction = 208
• 5.2 Point defects = 211
• 5.2.1 Point defect equilibria = 214
• 5.2.2 Paraelectric and molecular impurities in ionic solids = 220
• 5.2.3 Colour centres = 222
• 5.3 Dislocations = 223
• 5.4 Planar defects = 227
• 5.5 Ordered point defects and superstructures = 230
• 5.5.1 Doped alkali halides = 230
• 5.5.2 Metal chalcogenides and carbides = 231
• 5.5.3 Metal oxides of rocksalt structure = 234
• 5.5.4 Fluorite-related solids = 237
• 5.6 Crystallographic shear = 240
• 5.7 Block structures = 244
• 5.8 Infinitely adaptive structures = 247
• 5.9 Intergrowths = 248
• 5.10 Defect perovskite oxides: a case study = 252
• 6 Structure-property relations = 264
• 6.1 Introduction = 264
• 6.2 Electrons in solids = 264
• 6.2.1. Band model = 265
• 6.2.2. Localized electron model = 268
• 6.2.3. Chemical bond approach = 269
• 6.3 Properties = 272
• 6.3.1. Magnetic properties = 273
• 6.3.2. Electrical properties = 284
• 6.3.3. Superconductivity = 289
• 6.3.4. Dielectric and optical properties = 292
• 6.4 Case studies = 297
• 6.4.1. Metal oxides = 297
• 6.4.2. Metal sulphides = 311
• 6.4.3. Metal fluorides = 320
• 6.5 Metal-nonmetal transitions = 327
• 6.6 Metal clusters = 339
• 6.7 Mixed-valence compounds = 342
• 6.8 Low-dimensional solids = 351
• 6.9 Ferroics = 359
• 6.10 Liquid crystals = 372
• 7 Fashioning solids for specific purposes : aspects of materials design = 377
• 7.1 Introduction = 377
• 7.2 Fast ion conductors = 378
• 7.3 Photoelectrochemistry = 386
• 7.4 Magnetic materials = 394
• 7.5 Hydrogen storage materials = 399
• 7.6 Amorphous materials = 405
• 7.7 Organic materials = 409
• 7.8 Langmuir-Blodgett films = 413
• 7.9 Liquid crystals = 413
• 7.10 Nonlinear optical materials = 416
• 7.11 Luminescent inorganic materials = 418
• 7.12 Laser materials = 419
• 8 Reactivity of solids = 421
• 8.1 Introduction = 421
• 8.2 Nature of solid state reactions = 421
• 8.3 Reactions involving a single solid phase = 422
• 8.4 Solid-gas reactions = 426
• 8.5 Solid-solid reactions = 430
• 8.6 Solid-liquid reactions = 434
• 8.7 Intercalation chemistry = 434
• 8.8 Reactions of organic solids = 449
• 8.9 Heterogeneous catalysis = 460
• References = 475
• Index = 505