<P><B>Abstract</B></P> <P>Stability of metal-organic frameworks (MOFs) in aqueous medium and extreme solution conditions (acidic or basic) are important for the development of stable, reproducible, and sensitive electroc...
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https://www.riss.kr/link?id=A107450567
2018
-
SCOPUS,SCIE
학술저널
49-56(8쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>Stability of metal-organic frameworks (MOFs) in aqueous medium and extreme solution conditions (acidic or basic) are important for the development of stable, reproducible, and sensitive electroc...
<P><B>Abstract</B></P> <P>Stability of metal-organic frameworks (MOFs) in aqueous medium and extreme solution conditions (acidic or basic) are important for the development of stable, reproducible, and sensitive electrochemical biosensors. Herein, a base-stable chromium(III) dicarboxylate MOF was synthesized by microwave assisted solvothermal method for non-enzymatic detection of hydrogen peroxide (H<SUB>2</SUB>O<SUB>2</SUB>). The as-synthesized MOF exhibited excellent base stability without any obvious changes in crystallinity, morphology, and spectroscopic behaviors after base treatment. This MOF-modified glassy carbon electrode showed negligible change in charge transfer resistance at the electrode|electrolyte interface after redox cycling and good catalytic activity for the reduction of H<SUB>2</SUB>O<SUB>2</SUB> in 0.1 M NaOH<SUB>(aq.)</SUB>. The enhanced catalytic activity of H<SUB>2</SUB>O<SUB>2</SUB> reduction is enabled by the redox process of Cr<SUP>III/II</SUP> in the chromium (III) dicarboxylate. The sensor showed the sensitivity of ca. 11.9 μA mM<SUP>−1</SUP>, wide linear range from 25 to 500 μM, and a method detection limit of ca. 3.52 μM. The validation of this sensing platform was evaluated by standard addition method. Thus, the present biosensor could be used for the point of care detection of H<SUB>2</SUB>O<SUB>2</SUB>.</P> <P><B>Highlights</B></P> <P> <UL> <LI> A Cr-MOF (MIL-53-Cr<SUP>III</SUP>) was utilized for H<SUB>2</SUB>O<SUB>2</SUB> sensing for the first time. </LI> <LI> The Cr-MOF exhibits high chemical and electrochemical stability in NaOH solution. </LI> <LI> The redox processes of Cr<SUP>III/II</SUP> in MIL-53-Cr<SUP>III</SUP> have induced the direct reduction of H<SUB>2</SUB>O<SUB>2</SUB>. </LI> <LI> The sensor shows a wide linear range, good sensitivity, and low method detection limit. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>