노말프로판올과 노말데칸 혼합물의 최소자연발화온도 측정 및 예측 = Measurement and Prediction of Autoignition Temperature of n-Propanol+n-Decane Mixture

다국어 초록 (Multilingual Abstract)

The autoignition temperature (AIT) of a material is the lowest temperature at which the substance will spontaneously ignite in the absence of an external ignition source such as a spark or flame. The AIT may be used as combustion property to specify operating, storage, and materials handling procedures for processs safety. This study measured the AITs of n-Propanol+n-Decane system from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Decane which constituted binary system were 435℃ and 212℃, respectively. The experimental AITs of n-Propanol+n-Decane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D(average absolute deviation).

참고문헌 (Reference)

1 하동명, "n-Propanol과 n-Octane 혼합물의 최소자연발화온도의 예측" 한국가스학회 17 (17): 21-27, 2013

2 J. Gmehing, "Vapor-Liquid Equilibrium Data Collection" DECHEMA 1980

3 R. E. Lenga, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume Ⅰ ~ Ⅲ" Sigma Chemical Company and Aldrich Chemical Company Inc. 1993

4 하동명, "The Measurement of Fire and Explosion Properties of n-Pentadecane" 한국안전학회 28 (28): 53-57, 2013

5 C. F. Cullis, "Studies of the Spontaneous Ignition in the Air of Binary Hydrocarbon Mixtures" 23 : 347-356, 1974

6 J. L. Jackson, "Spontaneous Ignition Temperature -Commercial Fluids and Pure Hydrocarbons-" 43 (43): 2869-2870, 1951

7 N. N. Semenov, "Some Problems in Chemical Kinetics and Reactivity, Vol. 2" Princeton University Press 1959

8 A. M. Kanury, "SFPE Handbook of Fire Protection Engineering : Ignition of Liquid Fuels" SFPE 1995

9 R. J. Lewis, "SAX's Dangerous Properties of Industrial Materials" John Wiley & Son, Inc. 2004

10 M. G. Zabetakis, "Minimum Spontaneous Ignition Temperature of Combustibles in Air" 46 (46): 2173-2178, 1954

11 V. Babrauskas, "Ignition Handbook" Fire Science Publishers 2003

12 I. M. Smallwood, "Handbook of Organic Solvent Properties" John Wiley & Sons 1996

13 NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids"

14 G.E.P. Box, "Empirical Model-Building and Response Surface" John Wiley and Sons, Inc. 1987

15 G. S. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases" 20 (20): 238-241, 1948

16 C. J. Hilado, "Autoignition Temperature of Organic Chemicals" 4 : 75-80, 1972

17 D. Drysdale, "An Introduction to Fire Dynamics" Jone Wiley & Sons 1998