Rhodium-catalyzed reactions using alcohol as a carbon monoxide, nucleophile, hydration and alkylating source = 로듐촉매를 사용하여 알코올을 일산화탄소와 친핵체, 수화 및 알킬화 공급원으로 이용하는 반응 연구

다국어 초록 (Multilingual Abstract)

A CO-gas-free rhodium-catalyzed alkoxycarbonylation of aryl iodide with alcohols has been developed. Alcohols, with/without the aid of an aldehyde, were used as a carbon monoxide and nucleophile source.
Moreover, atom economic rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols has been developed. Benzyl alcohols were used as a hydration and alkylation source.

목차 (Table of Contents)

• Chapter 1. Rhodium-catalyzed synthesis of esters from aryl halides using alcohols as carbon monoxide and nucleophile sources 1
• 1.1. Introduction 1
• 1.2. Results and Discussion 3
• 1.3. Conclusion 14
• 1.4. Experimental Section 15
• 1.5. References 31
• Chapter 2. Rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols 34
• 2.1. Introduction 34
• 2.2. Results and Discussion 35
• 2.3. Conclusion 44
• 2.4. Experimental Section 45
• 2.5. References 54
• 국문초록 55