탈휘발화 과정에서 혼탄의 반응률과 열적 거동에 관한 연구 = Thermal Behavior and Kinetics of Coal Blends during Devolatilization

다국어 초록 (Multilingual Abstract)

The objective of this research is to predict the TG curve of blends of bituminous coal and sub-bituminous coal during devolatilization. TSL (Thermal Shock Large) TGA was used for Experiments, and Coats-redfern method was used for reaction order calculation. Based on reaction order, sum method was verified to be suitable for a single coal, then, prediction and comparison of TG curve of coal blends was conducted using both of WSM (Weight Sum Method) and MWSM (Modified Weight Sum Method), where the latter was developed in this research. The presented experiment results and WSM & MWSM were showed to be reasonable using linear least square method. MWSM performed more accurately than WSM for the case that TG curve had different slopes and the case that sharp weight loss happened due to release of volatile matter. The results showed that it`s possible to predict the thermal behavior of coal blends during devolatilization based on the thermal behavior of single coals