Efficient solar-light photocatalytic H2 evolution of Mn0.5Cd0.5S coupling with S,N-codoped carbon

다국어 초록 (Multilingual Abstract)

The low-cost and highly-efficient photocatalysts for solar-light induced water splitting had drawn greatattention to develop the renewable hydrogen economy. To enhance the solar-light driven H2 evolution ofMn0.5Cd0.5S, Mn0.5Cd0.5S was modified by S,N-codoped carbon (3-MCS/SN-C) via the in-situ sulfurizationat high temperature. In contrast with Mn0.5Cd0.5S (11.13 mmol g1 h1) and S-doped g-C3N4(0.35 mmol g1 h1), the optimal 3-MCS/SN-C with a mass ratio of Mn0.5Cd0.5S to S,N-codoped carbonof 1:3 exhibited the best H2 evolution rate of 27.58 mmol g1 h1 and an apparent quantum yield of27.43% at 400 nm. The photo-corrosion induced to the decreased H2 evolution capacity of 3-MCS/SN-Cfrom 131.13 to 126.52 mmol g1 after five cycles of 5 h. S,N-codoped carbon could efficiently capture visiblelight and absorb the photons, leading to the efficient transformation and separation of photogeneratedcarriers at the junction interface between Mn0.5Cd0.5S and S,N-codoped carbon.

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