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      전해 도금을 이용한 기가급 소자용 구리배선 공정 = Cu Metallization for Giga Level Devices Using Electrodeposition

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      https://www.riss.kr/link?id=A101102199

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      다국어 초록 (Multilingual Abstract)

      The transition of interconnection metal from aluminum alloy to copper has been introduced to meet the requirements of high speed, ultra-large scale integration, and high reliability of the semiconductor device. Since copper, which has low electrical resistivity and high resistance to degradation, has different electrical and material characteristics compared to aluminum alloy, new related materials and processes are needed to successfully fabricate the copper interconnection. In this review, some important factors of multilevel copper damascene process have been surveyed such as diffusion barrier, seed layer, organic additives for bottom-up electro/electroless deposition, chemical mechanical polishing, and capping layer to introduce the related issues and recent research trends on them.
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      The transition of interconnection metal from aluminum alloy to copper has been introduced to meet the requirements of high speed, ultra-large scale integration, and high reliability of the semiconductor device. Since copper, which has low electrical r...

      The transition of interconnection metal from aluminum alloy to copper has been introduced to meet the requirements of high speed, ultra-large scale integration, and high reliability of the semiconductor device. Since copper, which has low electrical resistivity and high resistance to degradation, has different electrical and material characteristics compared to aluminum alloy, new related materials and processes are needed to successfully fabricate the copper interconnection. In this review, some important factors of multilevel copper damascene process have been surveyed such as diffusion barrier, seed layer, organic additives for bottom-up electro/electroless deposition, chemical mechanical polishing, and capping layer to introduce the related issues and recent research trends on them.

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      참고문헌 (Reference)

      1 M. Hasegawa, "Void-Free Trench-Filling by Electroless Copper Deposition Usingthe Combination of Accelerating and Inhibiting Additives" 9 : C138 -, 2006

      2 "Via Fillingby Electrodeposition" 149 : C637 -, 2002

      3 "Transport Phenomena ThatControl Electroplated Copper Filling of Submicron Vias andTrenches" 146 : 4499-, 1999

      4 "Three-Additive Model of Superfilling of Copper" 148 : C466 -, 2001

      5 "Theory of Filling of High-Aspect Ratio Trenches andVias in Presence of Additives" 147 : 227-, 2000

      6 "TheEvolution of Interconnection Technology at IBM" 39 : 371-, 1995

      7 "The Effect of Tungsten and Boron on the Cu Barrier andOxidation Properties of Thin Electroless Cobalt-Tungsten-BoronFilms" 82 : 623-, 2005

      8 "The Decomposition of the SulfonateAdditive Sulfopropyl Sulfonate in Acid Copper ElectroplatingChemistries" 150 : C244 -, 2003

      9 "Superfilling Evolution in Cu Electrodeposition;Dependence on the Aging Time of the Accelerator" 7 : C98 -, 2004

      10 "SuperconformalFilm Growth: Mechanism and Quantification" 49 : 19-, 2005

      1 M. Hasegawa, "Void-Free Trench-Filling by Electroless Copper Deposition Usingthe Combination of Accelerating and Inhibiting Additives" 9 : C138 -, 2006

      2 "Via Fillingby Electrodeposition" 149 : C637 -, 2002

      3 "Transport Phenomena ThatControl Electroplated Copper Filling of Submicron Vias andTrenches" 146 : 4499-, 1999

      4 "Three-Additive Model of Superfilling of Copper" 148 : C466 -, 2001

      5 "Theory of Filling of High-Aspect Ratio Trenches andVias in Presence of Additives" 147 : 227-, 2000

      6 "TheEvolution of Interconnection Technology at IBM" 39 : 371-, 1995

      7 "The Effect of Tungsten and Boron on the Cu Barrier andOxidation Properties of Thin Electroless Cobalt-Tungsten-BoronFilms" 82 : 623-, 2005

      8 "The Decomposition of the SulfonateAdditive Sulfopropyl Sulfonate in Acid Copper ElectroplatingChemistries" 150 : C244 -, 2003

      9 "Superfilling Evolution in Cu Electrodeposition;Dependence on the Aging Time of the Accelerator" 7 : C98 -, 2004

      10 "SuperconformalFilm Growth: Mechanism and Quantification" 49 : 19-, 2005

      11 "SuperconformalElectrodeposition of Copper" 4 : C26 -, 2001

      12 "SuperconformalElectrodeposition Using Derivitized Substrates" 5 : C110 -, 2002

      13 "Superconformal Electrodepositionof Copper in 500-90 nm Features" 147 : 4524-, 2000

      14 "Superconformal Electrodepositionin Vias" 5 : C49 -, 2002

      15 "Superconformal Electrodeposition in Submicron Features" 87 : 016102-, 2001

      16 "Superconformal CuElectrodeposition on Various Substrates" 8 : C19 -, 2005

      17 "Superconformal CuElectrodeposition Using DPS; A Substitute Accelerator for Bis(3-sulfopropyl) Disulfide" 152 : C330 -, 2005

      18 "Structures of Ultra-ThinAtomic-Layer-Deposited TaNx Films" 95 : 6167-, 2004

      19 "Stress Migration Lifetime for Cu Interconnects With CoWPOnlyCap" 6 : 197-, 2006

      20 S. Kondo, "Slurry ChemicalCorrosion and Galvanic Corrosion During Copper ChemicalMechanical Polishing" 39 : 6216-, 2000

      21 "Self-Assembled Monolayers as Cu Diffusion Barriers forUltralow-k Dielectrics" 9 : F61 -, 2006

      22 "Reduced Electromigration of Cu Wires by Surface Coating" 81 : 1782-, 2002

      23 "Properties of Ta-Ge-(O)N as a Diffusion Barrierfor Cu on Si" 90 : 2007

      24 S. Balakumar, "Peeling and Delaminationin Cu/SiLKTM Process During Cu-CMP" 161 : 2004

      25 "Oxidation Resistive Cu Filmsby Room Temperature Surface Passivation with Thin Ag Layer" 6 : C17 -, 2003

      26 "Osmium Barriers for DirectCopper Electrodeposition in Damascene Processing" 9 : C41 -, 2006

      27 C. H. Lee, "Optimization of a Pretreatment for Copper Electroless Depositionon Ta Substrates" 154 : D182 -, 2007

      28 "Leveling and MicrostructuralEffects of Additives for Copper Electrodeposition" 146 : 2540-, 1999

      29 "Leveler Molecular Weight and ConcentrationImpact on Damascene Copper Electroplating Bath ElectrochemicalBehavior and Film Properties" Denver, Colorado 2006

      30 "Iridium Barriers for Direct Copper Electrodeposition inDamascene Processing" 9 : C48-, 2006

      31 "International Technology Roadmap for Semiconductor-2005 Update"

      32 "Inductively Coupled HydrogenPlasma-Assisted Cu ALD on Metallic and Dielectric Surfaces" 152 : C60 -, 2005

      33 P. P. Lau, "Improving Electroless Cu ViaFilling, with Optimized Pd Activation" 253 : 2357-, 2006

      34 C. H. Lee, "Improvement of ElectrolesslyGap-Filled Cu Using 2, 2’-Dipyridyl and Bis-(3-sulfopropyl)-disulfide (SPS)" 8 : C110 -, 2005

      35 "Growth Mechanism andDiffusion Barrier Property of Plasma-Enhanced Atomic LayerDeposition Ti-Si-N Thin Films" 24 : 1327-, 2006

      36 "Fundamentals of ElectrochemicalDeposition" John Wiley & Sons Inc., NY 182-, 1998

      37 "Fundamental Aspects and Applications ofElectrochemical Microfabrication" 45 : 2535-, 2000

      38 "Factors Influencing Fill of IC Features UsingElectroplated Copper" Orland, Florida 53-, 1999

      39 "Evaluation ofIntegrity and Barrier Performance of Atomic Layer DepositedWNxCy Films on Plasma Enhanced Chemical Vapor Deposited SiO2for Cu Metallization" 89 : 2006

      40 "Evaluating the Filling Performance of aCopper Plating Formula Using a Simple Galvanostat Method" 153 : C190 -, 2006

      41 "Electroless DepositedCobalt-Tungsten-Boron Capping Barrier Metal on DamasceneCopper Interconnection" 152 : C163 -, 2005

      42 C. H. Lee, "Electroless Cu Bottom-UpFilling Using 3-N,N-dimethylaminodithiocarbamoyl-1-propanesulfonicAcid" 8 : J27 -, 2005

      43 "Electroless CopperDeposition for ULSI" 262 : 93-, 1995

      44 "Electrodepositionof Copper Thin Film on Ruthenium; A Potential Diffusion Barrierfor Cu Interconnects" 150 : C347 -, 2003

      45 "Electrodeposition of Cu on Ru Barrier Layers forDamascene Processing" 153 : C37 -, 2006

      46 "Electrodeposition of Cu inthe PEI-PEG-Cl-SPS Additive System; Reduction of Overfill BumpFormation During Superfilling" 153 : C616-, 2006

      47 "Effects of NH3 Pulse Plasma on AtomicLayer Deposition of Tungsten Nitride Diffusion Barrier" 24 : 1432-, 2006

      48 "Direct Plating of LowResistivity Bright Cu Film onto TiN Barrier Layer via PdActivation" 151 : C97 -, 2004

      49 "Direct Evidence of Cu/Cap/Liner Edge Being the DominantElectromigration Path in Dual Damascene Cu Interconnects" 90 : 052106-1-, 2007

      50 "Direct Copper Electrodeposition on TaN Barrier Layers" 150 : C362 -, 2003

      51 "Diffusion Studies of Copper on RutheniumThin Film" 7 : G154 -, 2004

      52 "Development of Different Copper SeedLayers with Respect to the Copper Electroplating Process" 50 : 433-, 2000

      53 "Dependence of Cu/Ta?N/Ta Metallization Stability on the Characteristics of Low DielectricConstant Materials" 152 : G517 -, 2005

      54 "Damascene Cu Electrodeposition on Metal Organic ChemicalVapor Deposition-Grown Ru Thin Film Barrier" 22 : 2649-, 2004

      55 "Copper Metallization for ULSIand Beyond" 20 : 87-, 1995

      56 "Copper Electrodeposition: Principles and Recent Progress" 40 : 2650-, 2001

      57 D. DeNardis, "Chracterization of Copper-Hydrogen Peroxide Film GrowthKinetics" 513 : 311-, 2006

      58 "Chemical Vapor Deposition of anElectroplating Cu Seed Layer Using Hexafluoroacetylacetonate Cu(1,5-dimethylcyclooctadiene)" 19 : 2974-, 2001

      59 S. Pandija, "Chemical Mechanical Planarizationof Copper Using Abrasive-Free Solutions of Oxalic Acid andHydrogen Peroxide" Mat. Chem. Phys., in press

      60 "Characterization of Pd-FreeElectroless Co-Based Cap Selectively Deposited on Cu Surface ViaBorane-Based Reducing Agent" 515 : 1107-, 2006

      61 "Characterization of Additive Systems forDamascene Cu Electroplaing by the Superfilling Profile Monitor" 18 : 2835-, 2000

      62 J.-W. Lee, "Characterization of 5-Aminotetrazole as a Corrosion Inhibitor in Copper ChemicalMechanical Polishing" 152 : C827 -, 2005

      63 "Cationic Surfactants for theControl of Overfill Bumps in Cu Superfilling" 153 : C826 -, 2006

      64 "Catalytic Behavior of 3-Mercapto-1-Propane Sulfonic Acid on Cu Electrodeposition and ItsEffect on Cu Film Properties for CMOS Device Metallization" 542 : 61-, 2003

      65 C. H. Lee, "Bottom-up Filling in CuElectroless Deposition Using Bis-(3-sulfopropyl)-sidulfide (SPS)" 50 : 3563-, 2005

      66 Z. Wang, "Bottom-up FillMechanisms of Electroless Copper Plating with Addition of MercaptoAlkyl Carboxylic Acid" 24 : 803-, 2006

      67 S. Shingubara, "Bottom-Up Fill of Copper in Deep Submicrometer Holesby Electroless Plating" 7 : C78 -, 2004

      68 Y.-S. Kim, "Atomic Layer Deposition ofPd on TaN for Cu Electroless Plating" 152 : C376 -, 2005

      69 "Advanced Metallization for High Performance DevicesUsing Superconformal Cu Electrodeposition" 2004

      70 S. Kondo, "Abrasive-Free Polishing for Copper DamasceneInterconnection" 147 : 3907-, 2000

      71 "A Superfilling Model that Predicts Bump Formation" 4 : C50-, 2001

      72 T.-H. Tsai, "A Study of Copper ChemicalMechanical Polishing in Urea-Hydrogen Peroxide Slurry byElectrochemical Impedance Spectroscopy" 214 : 120-, 2003

      73 "A Simple Equation for Predicting SuperconformalElectrodeposition in Submicrometer Trenches" 148 : C767 -, 2001

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      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.24 0.24 0.28
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.25 0.21 0.514 0.1
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