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      KCI등재

      수분에 의한 페로브스카이트 박막의 분해 및 δ-phase 결정 형성을 억제하기 위한 표면 처리 기술

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      https://www.riss.kr/link?id=A107769274

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      다국어 초록 (Multilingual Abstract)

      Perovskite solar cells (PSCs) are currently attracting attention as a promising source of photovoltaic power generation for their rapid increase in efficiency within a short research period. However, the 2-step deposition method, which has been consid...

      Perovskite solar cells (PSCs) are currently attracting attention as a promising source of photovoltaic power generation for their rapid increase in efficiency within a short research period. However, the 2-step deposition method, which has been considered as a proper film fabrication route in commercialization point of view of PSC, requires a complicated control of environment to achieve high efficiency because each step of the process are affected by humidity in different manner. It is clearly a large hurdle for this technic to be transferred to industrialization. In this study, we developed a simple surface treatment by which high quality perovskite films can be fabricated through 2-step deposition method in a relatively wide humidity range without complicated humidity control at each step.

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      목차 (Table of Contents)

      • ABSTRACT
      • 1. 서론
      • 2. H₂O가 페로브스카이트 박막 형성에 미치는 영향
      • 3. 실험 방법
      • 4. 결과 및 고찰
      • ABSTRACT
      • 1. 서론
      • 2. H₂O가 페로브스카이트 박막 형성에 미치는 영향
      • 3. 실험 방법
      • 4. 결과 및 고찰
      • 5. 결론
      • References
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      참고문헌 (Reference)

      1 B. wook Park, "Understanding how excess lead iodide precursor improves halide perovskite solar cell performance" 9 (9): 1-8, 2018

      2 J. Zhang, "Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules" 8 (8): 8447-8454, 2020

      3 C. De Blasi, "Trapping levels in PbI2" 25 (25): 149-153, 1978

      4 C. H. Chiang, "The synergistic effect of H2O and DMF towards stable and 20%efficiency inverted perovskite solar cells" 10 (10): 808-817, 2017

      5 F. Jiang, "Synergistic Effect of PbI2 Passivation and Chlorine Inclusion Yielding High Open-Circuit Voltage Exceeding 1. 15 V in Both Mesoscopic and Inverted Planar CH3NH3PbI3(Cl)-Based Perovskite Solar Cells" 26 (26): 8119-8127, 2016

      6 Q. Jiang, "Surface passivation of perovskite film for efficient solar cells" 13 (13): 460-466, 2019

      7 F. Ma, "Stable α/δ phase junction of formamidinium lead iodide perovskites for enhanced near-infrared emission" 8 (8): 800-805, 2016

      8 P. Zhu, "Simultaneous Contact and Grain-Boundary Passivation in Planar Perovskite Solar Cells Using SnO2-KCl Composite Electron Transport Layer" 10 (10): 1-7, 2020

      9 D. Barrit, "Room-Temperature Partial Conversion of α-FAPbI3 Perovskite Phase via PbI2 Solvation Enables High-Performance Solar Cells" 30 (30): 1-10, 2020

      10 Z. Chen, "Room Temperature Formation of Semiconductor Grade α-FAPbI3Films for Efficient Perovskite Solar Cells" 1 (1): 100205-, 2020

      1 B. wook Park, "Understanding how excess lead iodide precursor improves halide perovskite solar cell performance" 9 (9): 1-8, 2018

      2 J. Zhang, "Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules" 8 (8): 8447-8454, 2020

      3 C. De Blasi, "Trapping levels in PbI2" 25 (25): 149-153, 1978

      4 C. H. Chiang, "The synergistic effect of H2O and DMF towards stable and 20%efficiency inverted perovskite solar cells" 10 (10): 808-817, 2017

      5 F. Jiang, "Synergistic Effect of PbI2 Passivation and Chlorine Inclusion Yielding High Open-Circuit Voltage Exceeding 1. 15 V in Both Mesoscopic and Inverted Planar CH3NH3PbI3(Cl)-Based Perovskite Solar Cells" 26 (26): 8119-8127, 2016

      6 Q. Jiang, "Surface passivation of perovskite film for efficient solar cells" 13 (13): 460-466, 2019

      7 F. Ma, "Stable α/δ phase junction of formamidinium lead iodide perovskites for enhanced near-infrared emission" 8 (8): 800-805, 2016

      8 P. Zhu, "Simultaneous Contact and Grain-Boundary Passivation in Planar Perovskite Solar Cells Using SnO2-KCl Composite Electron Transport Layer" 10 (10): 1-7, 2020

      9 D. Barrit, "Room-Temperature Partial Conversion of α-FAPbI3 Perovskite Phase via PbI2 Solvation Enables High-Performance Solar Cells" 30 (30): 1-10, 2020

      10 Z. Chen, "Room Temperature Formation of Semiconductor Grade α-FAPbI3Films for Efficient Perovskite Solar Cells" 1 (1): 100205-, 2020

      11 Q. Jiang, "Planar-Structure Perovskite Solar Cells with Efficiency beyond 21%" 29 (29): 1-7, 2017

      12 P. Cui, "Planar p-n homojunction perovskite solar cells with efficiency exceeding 21. 3%" 4 (4): 150-159, 2019

      13 Y. Zhao, "Perovskite seeding growth of formamidiniumlead-iodide-based perovskites for efficient and stable solar cells" 9 (9): 1-10, 2018

      14 Y. Chen, "Mechanism of PbI2 in Situ Passivated Perovskite Films for Enhancing the Performance of Perovskite Solar Cells" 11 (11): 44101-44108, 2019

      15 C. J. Tong, "Long Carrier Lifetimes in PbI2-Rich Perovskites Rationalized by Ab Initio Nonadiabatic Molecular Dynamics" 3 (3): 1868-1874, 2018

      16 A. Ariyarit, "Improvement of the dynamic spin-washing effect with an optimized process of a perovskite solar cell in ambient air by the Kriging method" 56 (56): 11142-11150, 2017

      17 J. Huang, "Impact of H2O on organic-inorganic hybrid perovskite solar cells" 10 (10): 2284-2311, 2017

      18 S. Xiao, "Good or evil : What is the role of water in crystallization of organometal halide perovskites?" 5 (5): 1147-1154, 2020

      19 Q. Jiang, "Enhanced electron extraction using SnO2 for high-efficiency planar-structure HC(NH2)2 PbI3-based perovskite solar cells" 2 (2): 1-7, 2017

      20 Q. Tai, "Efficient and stable perovskite solar cells prepared in ambient air irrespective of the humidity" 7 : 1-8, 2016

      21 K. Shoyama, "Effects of water on the forward and backward conversions of lead(II)iodide to methylammonium lead perovskite" 5 (5): 23815-23821, 2017

      22 J. Koo, "Effects of water and iso-propyl alcohol relative humidities on single wafer cleaning system performance" 50 (50): 4275-4285, 2007

      23 J. Robinson, "Effects of ambient humidity on the optimum annealing time of mixed-halide Perovskite solar cells" 2 : 0-31, 2020

      24 C. Xin, "Defects Healing in Two-Step Deposited Perovskite Solar Cells via Formamidinium Iodide Compensation" 3 (3): 3318-3327, 2020

      25 Y. Cui, "Correlating Hysteresis and Stability with Organic Cation Composition in the Two-Step Solution-Processed Perovskite Solar Cells" 12 (12): 10588-10596, 2020

      26 Y. Zhang, "CH3NH3PbI3and HC(NH2)2PbI3 Powders Synthesized from Low-Grade PbI2 : Single Precursor for High-Efficiency Perovskite Solar Cells" 11 (11): 1813-1823, 2018

      27 "Best Research-Cell Efficiency Chart | Photovoltaic Research |NREL"

      28 J. Cao, "Alkali-cation-enhanced benzylammonium passivation for efficient and stable perovskite solar cells fabricated through sequential deposition" 8 (8): 19357-19366, 2020

      29 K. Zhang, "A prenucleation strategy for ambient fabrication of perovskite solar cells with high device performance uniformity" 11 (11): 1-11, 2020

      30 Y. Zhao, "A Polymerization-Assisted Grain Growth Strategy for Efficient and Stable Perovskite Solar Cells" 32 (32): 1-8, 2020

      31 Y. Cheng, "18% High-Efficiency Air-Processed Perovskite Solar Cells Made in a Humid Atmosphere of 70% RH" 1 (1): 1-8, 2017

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