난분해성 산업폐수 처리를 위한 고도산화기술 = Advanced oxidation technologies for the treatment of nonbiodegradable industrial wastewater

다국어 초록 (Multilingual Abstract)

Industrial wastewater often contains a number of recalcitrant organic contaminants. These contaminants are hardly degradable by biological wastewater treatment processes, which requires a more powerful treatment method based on chemical oxidation. Advanced oxidation technology (AOT) has been extensively studied for the treatment of nonbiodegradable organics in water and wastewater. Among different AOTs developed up to date, ozonation and the Fenton process are the representative technologies that widely used in the field. Based on the traditional ozonation and the Fenton process, several modified processes have been also developed to accelerate the production of reactive radicals. This article reviews the chemistry of ozonation and the Fenton process as well as the cases of application of these two AOTs to industrial wastewater treatment. In addition, research needs to improve the cost efficiency of ozonation and the Fenton process were discussed.

참고문헌 (Reference)

1 Rice, R. G., "Uses of ozone in drinking water treatment" 73 (73): 44-57, 1981

2 Lucas, M. S., "Treatment of winery wastewater by ozone-based advanced oxidation processes (O3, O3/UV and O3/UV/H2O2) in a pilot-scale bubble column reactor and process economics" 72 (72): 235-241, 2010

3 Godini, K., "Treatment of waste sludge : a comparison between anodic oxidation and electro-Fenton processes" 13 (13): 188-193, 2013

4 Liu, J., "Treatment of recalcitrant organic silicone wastewater by fluidized-bed Fenton process" 132 : 16-22, 2014

5 Gulyas, H., "Treatment of industrial wastewaters with ozone/hydrogen peroxide" 32 (32): 127-134, 1995

6 Barbusiński, K., "Toxicity of industrial wastewater treated by Fenton’s reagent" 14 (14): 11-16, 2005

7 Yan-yang, C., "Three advanced oxidation processes for the treatment of the wastewater from acrylonitrile production" 60 (60): 2991-2999, 2009

8 Ershov, B. G., "The kinetics of ozone decomposition in water, the influence of pH and temperature" 83 (83): 1295-1299, 2009

9 Schwarzenbach, R. P., "The challenge of micropollutants in aqueous systems" 313 (313): 1072-1077, 2006

10 Ingles, D. L., "Studies of oxidation by Fenton's reagent using redox titration. I. Oxidation of some organic compounds" 25 (25): 87-95, 1972

11 Bard, A. J., "Standard Potentials in Aqueous Solution" Marcel Dekker Inc. 1985

12 Babu, B. R., "Removal of fatty acids from palm oil effluent by combined electro-fenton and biological oxidation process" 211 (211): 203-210, 2010

13 Yao, C. C. D., "Rate constants for direct reactions of ozone with several drinking water contaminants" 25 (25): 761-773, 1991

14 Lee, Y., "Quantitative structureactivity relationships(QSARs)for the transformation of organic micropollutants during oxidative water treatment" 46 (46): 6177-6195, 2012

15 Neta, P., "Pulse radiolysis studies. XIII. Rate constants for the reaction of hydroxyl radicals with aromatic compounds in aqueous solutions" 81 : 222-230, 1968

16 Martınez, N. S. S., "Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent" 101 (101): 315-322, 2003

17 Kim, J., "Platinized WO3as an environmental photocatalyst that generates OH radicals under visible light" 44 (44): 6849-6854, 2010

18 Buffle, M. -O., "Phenols and amine induced HO generation during the initial phase of natural water ozonation" 40 (40): 3057-3063, 2006

19 Adams, C. D., "Ozone, hydrogen peroxide/ozone and UV/ozone treatment of chromium-and copper-complex dyes : Decolorization and metal release" 17 (17): 149-162, 1995

20 Baig, S., "Ozone treatment for biorefractory COD removal" 43 (43): 197-204, 2001

21 Büehler, R. E., "Ozone decomposition in water studied by pulse radiolysis. 1. HO2/O2− and HO3/O3− as intermediates" 88 (88): 2560-2564, 1984

22 Gähr, F., "Ozonation – An important technique to comply with new german laws for textile wastewater treatment" 30 (30): 255-263, 1994

23 Bailey, P. S., "Ozonation in Organic Chemistry Volume II Nonolefinic Compounds" Academic Press Inc. 1982

24 Eisenhauer, H. R., "Oxidation of phenolic wastes" 36 (36): 1116-1128, 1964

25 Boopathy, R., "New approach of integrated advanced oxidation processes for the treatment of lube oil processing wastewater" 43 (43): 6229-6236, 2018

26 Daghrir, R., "Modified TiO2 for environmental photocatalytic applications: a review" 52 (52): 3581-3599, 2013

27 Kim, M. S., "Modeling of ozone decomposition, oxidant exposure, and the abatement of micropollutants during ozonation processes" 169 : 115230-, 2020

28 Li, M., "Micropollutant degradation by the UV/H2O2 process : kinetic comparison among various radiation sources" 53 (53): 5241-5248, 2019

29 Criegee, R., "Mechanism of ozonolysis" 14 (14): 745-752, 1975

30 Fenton, H. J. H., "LXXIII. -Oxidation of tartaric acid in presence of iron" 65 : 899-910, 1894

31 Trizaoui, C., "Kinetics of the ozone oxidation of Reactive Orange 16 azo-dye in aqueous solution" 173 (173): 463-473, 2011

32 Boonrattanakij, N., "Iron crystallization in a fluidized-bed Fenton process" 45 (45): 3255-3262, 2011

33 He, D., "Influence of different nominal molecular weight fractions of humic acids on phenol oxidation by permanganate" 43 (43): 8332-8337, 2009

34 Elovitz, M. S., "Hydroxyl radical/ozone ratios during ozonation processes. I. The Rct concept" 21 (21): 239-260, 1999

35 Zepp, R. G., "Hydroxyl radical formation in aqueous reactions (pH 3-8) of iron(II) with hydrogen peroxide: the photo-Fenton reaction" 26 (26): 313-319, 1992

36 Garcia-Segura, S., "Fluidized-bed Fenton process as alternative wastewater treatment technology-A review" 67 : 211-225, 2016

37 Wang, L., "Ferrous–tetrapolyphosphate complex induced dioxygen activation for toxic organic pollutants degradation" 120 : 148-155, 2013

38 Lin, S. H., "Fenton process for treatment of desizing wastewater" 31 (31): 2050-2056, 1997

39 Messele, S. A., "Enhanced degradation of phenol by a Fenton-like system(Fe/EDTA/H2O2)at circumneutral pH" 9 (9): 474-, 2019

40 Siddiqui, M., "Empirically and theoretically-based models for predicting brominated ozonated by-products" 16 (16): 157-178, 1994

41 Koppenol, W. H., "Electrode potentials of partially reduced oxygen species, from dioxygen to water" 49 (49): 317-322, 2010

42 Maamar, M., "Electrochemical oxidation of bromothymol blue : Application to textile industrial wastewater treatment" 18 (18): 105-113, 2015

43 Brillas, E., "Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry" 109 (109): 6570-6631, 2009

44 Su, C. C., "Effect of operating parameters on the decolorization and oxidation of textile wastewater by the fluidized-bed Fenton process" 83 : 100-105, 2011

45 Chen, M., "Effect of different carriers and operating parameters on degradation of flax wastewater by fluidized-bed Fenton process" 71 (71): 1760-1767, 2015

46 Wu, J., "Disinfection of recycled red-meat-processing wastewater by ozone" 80 (80): 828-833, 2005

47 Sohn, J., "Disinfection decay and disinfection by-products formation model development : chlorination and ozonation by-products" 38 (38): 2461-2478, 2004

48 Khadhraoui, M., "Discoloration and detoxicification of a Congo red dye solution by means of ozone treatment for a possible water reuse" 161 (161): 974-981, 2009

49 Lee, M., "Development of prediction models for the reactivity of organic compounds with ozone in aqueous solution by quantum chemical calculations : the role of delocalized and localized molecular orbitals" 49 (49): 9925-9935, 2015

50 Minakata, D., "Development of a group contribution method to predict aqueous phase hydroxyl radical(HO•)reaction rate constants" 43 (43): 6220-6227, 2009

51 Barder, H., "Determination of ozone in water by the indigo method" 15 (15): 449-456, 1981

52 Karami, M. A., "Degradation of reactive red 198 from aqueous solutions by advanced oxidation process : O3, O3/H2O2, and persulfate" 5 : 26-, 2016

53 Wols, B. A., "Degradation of 40 selected pharmaceuticals by UV/H2O2" 47 (47): 5876-5888, 2013

54 Staehelin, J., "Decomposition of ozone in water : Rate of initiation by hydroxide ions and hydrogen peroxide" 16 (16): 676-681, 1982

55 Staehelin, J., "Decomposition of ozone in the presence of organic solutes acting as promoters and inhibitors of radical chain reactions" 19 (19): 1206-1213, 1985

56 Bilińska, L., "Coupling of electrocoagulation and ozone treatment for textile wastewater reuse" 358 : 992-1001, 2019

57 Qi, L., "Coupling of biological methods with membrane filtration using ozone as pre-treatment for water reuse" 270 (270): 264-268, 2011

58 Güneş, E., "Comparison of Fenton process and adsorption method for treatment of industrial container and drum cleaning industry wastewater" 39 (39): 824-830, 2018

59 Ulucan, K., "Comparative study of electrochemical wastewater treatment processes for bilge water as oily wastewater : a kinetic approach" 747 : 104-111, 2015

60 Peng, R., "Coke plant wastewater posttreatment by Fenton and electro-Fenton processes" 34 (34): 89-95, 2017

61 von Gunten, U., "Bromate formation during ozonation of bromide-containing waters:interaction of ozone and hydroxyl radical reactions" 28 (28): 1234-1242, 1994

62 Joss, A., "Biological degradation of pharmaceuticals in municipal wastewater treatment : Proposing a classification scheme" 40 (40): 1686-1696, 2006

63 Ikehata, K., "Aqueous pesticide degradation by ozonation and ozone-based advanced oxidation processes : A review(Part I)" 27 (27): 83-114, 2005

64 Chachou, L., "Application of the electro-Fenton process for cutting fluid mineralization" 36 (36): 1924-1932, 2015

65 Perkowski, J., "Application of ozone in textile wastewater treatment" 18 (18): 73-85, 1996

66 Świetlik, J., "Application of fluorescence spectroscopy in the studies of natural organic matter fractions reactivity with chlorine dioxide and ozone" 38 (38): 3791-3799, 2004

67 Amor, C., "Application of advanced oxidation processes for the treatment of recalcitrant agro-industrial wastewater : A review" 11 (11): 205-, 2019

68 Lee, Y., "Advances in predicting organic contaminant abatement during ozonation of municipal wastewater effluent : reaction kinetics, transformation products, and changes of biological effects" 2 : 421-442, 2016

69 Bayar, S., "Advanced treatment of industrial wastewater from pistachio processing by Fenton process" 112 : 106-111, 2018

70 Ghanbari, F., "A comparative study of electrocoagulation, electrochemical Fenton, electro-Fenton and peroxi-coagulation for decolorization of real textile wastewater : electrical energy consumption and biodegradability improvement" 3 (3): 499-506, 2015

71 Gu, Z., "A comparative study of dinitrodiazophenol industrial wastewater treatment : Ozone/hydrogen peroxide versus microwave/persulfate" 130 : 39-47, 2019