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      KCI등재 SCI SCIE SCOPUS

      Influence of Porosity on Mechanical Behavior of Porous Cu Fabricated via De‑Alloying of Cu–Fe Alloy

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      https://www.riss.kr/link?id=A105994735

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      다국어 초록 (Multilingual Abstract)

      We report on a study of the mechanical behavior of porous Cu containing micron-sized pores and fabricated by de-alloyingof a Cu–Fe precursor alloy. Our results show that the minimum volume fraction of pores that can be obtained by using anapproach that involves de-alloying of a Cu–Fe precursor alloy is approximately 40 vol%. Moreover, the average pore sizeformed by de-alloying Cu–Fe of varying compositions is in the range of 1.5–4.0 μm. Our mechanical behavior results revealthat the yield stress increases from 3.9 to 58.6 MPa as the volume fraction of porosity decreases from 78.9% to 39.3%.
      Moreover, our data shows that the influence of porosity on the relative yield stress and relative Young’s modulus conformsto the scaling equations of Gibson and Ashby as formulated for open-cell porous metals. The pore cell characteristics anddeformation modes of porous Cu produced by de-alloying Cu–Fe alloys were discussed in the context of the observed fluctuationsin the value of the constants C and n in the Gibson-Ashby scaling equation. The evolution of microstructure duringcompressive deformation of porous Cu was studied and the results reveal an increase in the fraction of low-angle grainboundaries, an increase in the number of twins and a decrease in the average grain size with increasing strain from 0% to 70%.
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      We report on a study of the mechanical behavior of porous Cu containing micron-sized pores and fabricated by de-alloyingof a Cu–Fe precursor alloy. Our results show that the minimum volume fraction of pores that can be obtained by using anapproach t...

      We report on a study of the mechanical behavior of porous Cu containing micron-sized pores and fabricated by de-alloyingof a Cu–Fe precursor alloy. Our results show that the minimum volume fraction of pores that can be obtained by using anapproach that involves de-alloying of a Cu–Fe precursor alloy is approximately 40 vol%. Moreover, the average pore sizeformed by de-alloying Cu–Fe of varying compositions is in the range of 1.5–4.0 μm. Our mechanical behavior results revealthat the yield stress increases from 3.9 to 58.6 MPa as the volume fraction of porosity decreases from 78.9% to 39.3%.
      Moreover, our data shows that the influence of porosity on the relative yield stress and relative Young’s modulus conformsto the scaling equations of Gibson and Ashby as formulated for open-cell porous metals. The pore cell characteristics anddeformation modes of porous Cu produced by de-alloying Cu–Fe alloys were discussed in the context of the observed fluctuationsin the value of the constants C and n in the Gibson-Ashby scaling equation. The evolution of microstructure duringcompressive deformation of porous Cu was studied and the results reveal an increase in the fraction of low-angle grainboundaries, an increase in the number of twins and a decrease in the average grain size with increasing strain from 0% to 70%.

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      참고문헌 (Reference)

      1 K. A. Erk, "Titanium with controllable pore fractions by thermoreversible gelcasting of TiH2" 56 : 5147-5157, 2008

      2 N. Bekoz, "The role of pore wall microstructure and micropores on the mechanical properties of Cu–Ni–Mo based steel foams" 612 : 387-397, 2014

      3 A. Rohatgi, "The influence of stacking fault energy on the mechanical behavior of Cu and Cu–Al alloys:deformation twinning, work hardening, and dynamic recovery" 32 : 135-145, 2001

      4 A. M. Parvanian, "The effects of manufacturing parameters on geometrical and mechanical properties of copper foams produced by space holder technique" 53 : 681-690, 2014

      5 A. E. Markaki, "The effect of cell wall microstructure on the deformation and fracture of aluminium-based foams" 49 : 1677-1686, 2001

      6 P. Quadbeck, "Synthesis and properties of open-celled metal foams" 534 (534): 1005-1008, 2007

      7 L. P. Lefebvre, "Reviews : porous metals and metallic foams : current status and recent developments" 10 : 775-787, 2008

      8 J. Banhart, "Review: manufacture, characterisation and application of cellular metals and metal foams" 46 : 559-632, 2001

      9 C. Y. Zhao, "Review on thermal transport in high porosity cellular metal foams with open cells" 55 : 3618-3632, 2012

      10 C. Körner, "Review : processing of metal foams challenges and opportunities" 2 (2): 159-165, 2000

      1 K. A. Erk, "Titanium with controllable pore fractions by thermoreversible gelcasting of TiH2" 56 : 5147-5157, 2008

      2 N. Bekoz, "The role of pore wall microstructure and micropores on the mechanical properties of Cu–Ni–Mo based steel foams" 612 : 387-397, 2014

      3 A. Rohatgi, "The influence of stacking fault energy on the mechanical behavior of Cu and Cu–Al alloys:deformation twinning, work hardening, and dynamic recovery" 32 : 135-145, 2001

      4 A. M. Parvanian, "The effects of manufacturing parameters on geometrical and mechanical properties of copper foams produced by space holder technique" 53 : 681-690, 2014

      5 A. E. Markaki, "The effect of cell wall microstructure on the deformation and fracture of aluminium-based foams" 49 : 1677-1686, 2001

      6 P. Quadbeck, "Synthesis and properties of open-celled metal foams" 534 (534): 1005-1008, 2007

      7 L. P. Lefebvre, "Reviews : porous metals and metallic foams : current status and recent developments" 10 : 775-787, 2008

      8 J. Banhart, "Review: manufacture, characterisation and application of cellular metals and metal foams" 46 : 559-632, 2001

      9 C. Y. Zhao, "Review on thermal transport in high porosity cellular metal foams with open cells" 55 : 3618-3632, 2012

      10 C. Körner, "Review : processing of metal foams challenges and opportunities" 2 (2): 159-165, 2000

      11 B. Bay, "Overview no. 96: evolution of fcc deformation structures in polyslip" 40 : 205-219, 1992

      12 S. H. Joo, "Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles" 412 : 169-172, 2001

      13 E. Zhang, "On the compressive behaviour of sintered porous coppers with low to medium porosities-Part I : experimental study" 47 : 744-756, 2005

      14 Z. Dan, "Nanoporous palladium fabricated from an amorphousPd42.5Cu30Ni7.5P20precursor and its ethanol electro-oxidation performance" 108 : 512-519, 2013

      15 J. Y. Huang, "Microstructures and dislocation configurations in nanostructured Cu processed by repetitive corrugation and straightening" 49 : 1497-1505, 2001

      16 D. Farkas, "Mechanical response of nanoporous gold" 61 : 3249-3256, 2013

      17 N. Bekoz, "Mechanical properties of low alloy steel foams : dependency on porosity and pore size" 576 : 82-90, 2013

      18 A. M. Parvanian, "Mechanical behavior improvement of open-pore copper foams synthesized through space holder technique" 49 : 834-841, 2013

      19 G. Stephani, "Iron based cellular structures—status and prospects" 8 : 847-852, 2006

      20 Y. Hangai, "Friction powder compaction process for fabricating opencelled Cu foam by sintering-dissolution process route using NaCl space holder" 585 : 468-474, 2013

      21 Z. Qi, "Formation and characterization of monolithic nanoporous copper by chemical dealloying of Al–Cu Alloys" 113 : 6694-6698, 2009

      22 M. Kashihara, "Fabrication of lotus-type porous carbon steel via continuous zone melting and its mechanical properties" 524 : 112-118, 2009

      23 J. F. Huang, "Fabrication and surface functionalization of nanoporous gold by electrochemical alloying/dealloying of Au–Zn in an ionic liquid, and the self-assembly of l-cysteine monolayers" 15 : 989-994, 2005

      24 L. J. Zou, "Fabrication and mechanical behavior of porous Cu via chemical de-alloying of Cu25Fe75 alloys" 689 : 6-14, 2016

      25 Q. Q. Kong, "Fabrication and compression properties of bulk hierarchical nanoporous copper with fine ligament" 127 : 59-62, 2014

      26 C. C. Zhao, "Fabrication and characterization of monolithic nanoporous copper through chemical dealloying of Mg–Cu alloys" 51 : 2120-2125, 2009

      27 Y. Tang, "Experimental study on the tensile strength of a sintered porous metal composite" 607 : 536-541, 2014

      28 A. F. Bastawros, "Experimental analysis of deformation mechanisms in a closed-cell aluminum alloy foam" 48 : 301-322, 2000

      29 J. Erlebacher, "Evolution of nanoporosity in dealloying" 410 : 450-453, 2001

      30 Y. C. K. Chen-Wiegart, "Effect of Ag-Au composition and acid concentration on dealloying front velocity and cracking during nanoporous gold formation" 61 : 5561-5570, 2013

      31 N. Tuncer, "Designing compressive properties of titanium foams" 44 : 1477-1484, 2009

      32 M. Hakamada, "Density dependence of the compressive properties of porous copper over a wide density range" 55 : 2291-2299, 2007

      33 B. Bay, "Deformation structures in light rolled pure aluminum" 113 : 385-397, 1989

      34 A. C. Kaya, "Deformation behavior of open-cell stainless steel foams" 615 : 447-456, 2014

      35 J. C. Qiao, "Compressive property and energy absorption of porous sintered fiber metals" 49 : 2919-2921, 2008

      36 Y. Yamada, "Compressive deformation characteristics of opencell Mg alloys with controlled cell structure" 43 : 1298-1305, 2002

      37 J. Weissmueller, "Charge-induced reversible strain in a metal" 300 : 312-315, 2003

      38 T. You, "Characterization of platinum nanoparticle-embedded carbon film electrode and its detection of hydrogen peroxide" 75 : 2080-2085, 2003

      39 L.J. Gibson, "Cellular solids: structure and properties" Cambridge University Press 1997

      40 G. C. Bond, "Catalysis by gold" 413 : 19-388, 1999

      41 C. X. Huang, "An ideal ultrafine-grained structure for high strength and high ductility" 3 : 88-94, 2015

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