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      Sensitivity analysis of volatile organic compounds to PM2.5 concentrations in a representative industrial city of Korea

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      https://www.riss.kr/link?id=A108562333

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      다국어 초록 (Multilingual Abstract)

      This study aims to analyze the sensitivity of volatile organic compounds (VOCs) to ambient concentrations of fine particles ( PM2.5) in the representative industrial city of Ulsan, Korea. For the calculation of sensitivity coefficients between VOCs and PM2.5 (SVOCs-PM2.5), PM2.5 data were obtained from an air quality monitoring station, and their corresponding 6-h average concentrations of VOCs (alkanes, alkenes, aromatics, and total VOCs) were measured at the Yeongnam intensive air monitoring station. The air monitoring period was divided into the warm-hot season (May–October 2020) and the cold season (November 2020–January 2021). The sensitivity coefficients in the low pollution period of PM2.5 (5 < PM2.5 ≤ 15 μg/m3) were higher and much higher than those in the medium pollution period (15 < PM2.5 ≤ 35 μg/m3) and high pollution period (35 < PM2.5 ≤ 50 μg/m3), respectively. This result indicates that the change ratios of PM2.5 concentrations to the background ( PM2.5 ≤ 5 μg/m3) per unit concentration change of VOCs (particularly alkenes) in the high PM2.5 pollution period were much higher than those in the low pollution period. This also indicates that PM2.5 concentrations above 35 μg/m3 were more easily affected by the unit concentration change of VOCs (particularly alkenes) than those below 15 μg/m3. The average sensitivity coefficients during the cold season increased in a range of 23–125% as compared to those during the warm-hot season, except the alkenes-PM2.5 sensitivity with a decrease of 7%. It means that the impact of VOCs (except alkenes) on PM2.5 concentrations was relatively low in the cold season. However, in the cold season, the alkenes might contribute more to PM2.5 formation, particularly over the high pollution period, having PM2.5 > 35 μg/m3, than other VOC groups. The result of this study can be a basis for establishing PM2.5 management plans in industrial cities with large VOC emissions.
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      This study aims to analyze the sensitivity of volatile organic compounds (VOCs) to ambient concentrations of fine particles ( PM2.5) in the representative industrial city of Ulsan, Korea. For the calculation of sensitivity coefficients between VOCs an...

      This study aims to analyze the sensitivity of volatile organic compounds (VOCs) to ambient concentrations of fine particles ( PM2.5) in the representative industrial city of Ulsan, Korea. For the calculation of sensitivity coefficients between VOCs and PM2.5 (SVOCs-PM2.5), PM2.5 data were obtained from an air quality monitoring station, and their corresponding 6-h average concentrations of VOCs (alkanes, alkenes, aromatics, and total VOCs) were measured at the Yeongnam intensive air monitoring station. The air monitoring period was divided into the warm-hot season (May–October 2020) and the cold season (November 2020–January 2021). The sensitivity coefficients in the low pollution period of PM2.5 (5 < PM2.5 ≤ 15 μg/m3) were higher and much higher than those in the medium pollution period (15 < PM2.5 ≤ 35 μg/m3) and high pollution period (35 < PM2.5 ≤ 50 μg/m3), respectively. This result indicates that the change ratios of PM2.5 concentrations to the background ( PM2.5 ≤ 5 μg/m3) per unit concentration change of VOCs (particularly alkenes) in the high PM2.5 pollution period were much higher than those in the low pollution period. This also indicates that PM2.5 concentrations above 35 μg/m3 were more easily affected by the unit concentration change of VOCs (particularly alkenes) than those below 15 μg/m3. The average sensitivity coefficients during the cold season increased in a range of 23–125% as compared to those during the warm-hot season, except the alkenes-PM2.5 sensitivity with a decrease of 7%. It means that the impact of VOCs (except alkenes) on PM2.5 concentrations was relatively low in the cold season. However, in the cold season, the alkenes might contribute more to PM2.5 formation, particularly over the high pollution period, having PM2.5 > 35 μg/m3, than other VOC groups. The result of this study can be a basis for establishing PM2.5 management plans in industrial cities with large VOC emissions.

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      참고문헌 (Reference)

      1 WHO, "WHO issues latest global air quality report: Some progress, but more attention needed to avoid dangerously high levels of air pollution" World Health Organization

      2 Han, D., "Volatile organic compounds (VOCs) during non-haze and haze days in Shanghai: Characterization and secondary organic aerosol (SOA) formation" 24 : 18619-18629, 2017

      3 Kim, Y. P., "Trend of air quality in Seoul: Policy and science" 18 : 2141-2156, 2018

      4 Brown, J. S., "Thoracic and respirable particle definitions for human health risk assessment" 10 : 12-, 2013

      5 Lelieveld, J., "The contribution of outdoor air pollution sources to premature mortality on a global scale" 525 : 367-371, 2015

      6 Kim, S. -J., "Spatial and temporal variations of volatile organic compounds using passive air samplers in the multi-industrial city of Ulsan, Korea" 26 : 5831-5841, 2019

      7 Nguyen, T. N. T., "Seasonal variation, phase distribution, and source identification of atmospheric polycyclic aromatic hydrocarbons at a semi-rural site in Ulsan, South Korea" 236 : 529-539, 2018

      8 US EPA, "Revised air quality standards for particle pollution and updates to the air quality index (AQI)" United States Environmental Protection Agency

      9 Heo, J., "Public health costs of primary PM2.5 and inorganic PM2.5 precursor emissions in the United States" 50 : 6061-6070, 2016

      10 EEA, "Premature deaths attributable to PM2.5, NO2 and O3 exposure in 41 European countries and the EU-28, 2014" European Environment Agency

      1 WHO, "WHO issues latest global air quality report: Some progress, but more attention needed to avoid dangerously high levels of air pollution" World Health Organization

      2 Han, D., "Volatile organic compounds (VOCs) during non-haze and haze days in Shanghai: Characterization and secondary organic aerosol (SOA) formation" 24 : 18619-18629, 2017

      3 Kim, Y. P., "Trend of air quality in Seoul: Policy and science" 18 : 2141-2156, 2018

      4 Brown, J. S., "Thoracic and respirable particle definitions for human health risk assessment" 10 : 12-, 2013

      5 Lelieveld, J., "The contribution of outdoor air pollution sources to premature mortality on a global scale" 525 : 367-371, 2015

      6 Kim, S. -J., "Spatial and temporal variations of volatile organic compounds using passive air samplers in the multi-industrial city of Ulsan, Korea" 26 : 5831-5841, 2019

      7 Nguyen, T. N. T., "Seasonal variation, phase distribution, and source identification of atmospheric polycyclic aromatic hydrocarbons at a semi-rural site in Ulsan, South Korea" 236 : 529-539, 2018

      8 US EPA, "Revised air quality standards for particle pollution and updates to the air quality index (AQI)" United States Environmental Protection Agency

      9 Heo, J., "Public health costs of primary PM2.5 and inorganic PM2.5 precursor emissions in the United States" 50 : 6061-6070, 2016

      10 EEA, "Premature deaths attributable to PM2.5, NO2 and O3 exposure in 41 European countries and the EU-28, 2014" European Environment Agency

      11 Lee, S. -J., "Pollution characteristics of PM2.5 during high concentration periods in summer and winter in Ulsan, the largest industrial city in South Korea" 292 : 119418-, 2023

      12 NICS, "Pollutant release and transfer register (PRTR)" National Institute of Chemical Safety

      13 Luo, Y., "PM2.5 pollution in a petrochemical industry city of northern China: Seasonal variation and source apportionment" 212 : 285-295, 2018

      14 Querol, X., "PM10 and PM2.5 source apportionment in the Barcelona Metropolitan Area, Catalonia. Spain" 35 : 6407-6419, 2001

      15 Yang, G. H., "Numerical sensitivity tests of volatile organic compounds emission to PM2.5 formation during heat wave period in 2018 in two southeast Korean cities" 11 : 331-, 2020

      16 NIOSH, "NIOSH Manual of Analytical Methods (NMAM)" Department of Health and Human Services 2-6, 1998

      17 Zhang, X., "Impact of VOCs emission from iron and steel industry on regional O3 and PM2.5 pollutions" 27 : 28853-28866, 2020

      18 Vallero, D., "Fundamentals of air pollution" Academic press. Elsevier Inc 2014

      19 Goodkind, A. L., "Fine-scale damage estimates of particulate matter air pollution reveal opportunities for location-specific mitigation of emissions" 116 : 8775-8780, 2019

      20 Phillips, H., "Evaluation of aldehydes, polycyclic aromatic hydrocarbons, and PM2.5 levels in food trucks: A pilot study" 68 : 443-451, 2020

      21 Delfino, R. J., "Epidemiologic evidence for asthma and exposure to air toxics: Linkages between occupational, indoor, and community air pollution research" 110 : 573-589, 2002

      22 Vuong, Q. T., "Driving factors to air pollutant reductions during the implementation of intensive controlling policies in 2020 in Ulsan. South Korea" 292 : 118380-, 2022

      23 Han, D., "Do volatile organic compounds (VOCs) emitted from petrochemical industries affect regional PM2.5?" 209 : 123-130, 2018

      24 Bari, M. A., "Concentrations, sources and human health risk of inhalation exposure to air toxics in Edmonton" 173 : 160-171, 2017

      25 Sun, Y., "Chemical characteristics of PM2.5 and PM10 in haze−fog episodes in Beijing" 40 : 3148-3155, 2006

      26 Yan, G., "Chemical characteristics and source apportionment of PM2.5 in a petrochemical city: Implications for primary and secondary carbonaceous component" 103 : 322-335, 2021

      27 Park, Y. -M., "Characterizing isotopic compositions of TC-C, NO3−-N, and NH4+-N in PM2.5 in South Korea: Impact of China’s winter heating" 233 : 735-744, 2018

      28 Kim, S. -J., "Characteristics of volatile organic compounds in the metropolitan city of Seoul, South Korea: Diurnal variation, source identification, secondary formation of organic aerosol, and health risk" 838 : 156344-, 2022

      29 Park, S. -S., "Characteristics of PM2.5 haze episodes revealed by highly time-resolved measurements at an air pollution monitoring supersite in Korea" 13 : 957-976, 2013

      30 Saini, P., "Cause and age-specific premature mortality attributable to PM2.5 exposure: An analysis for million-plus Indian cities" 710 : 135230-, 2020

      31 EEA, "Air quality in Europe — 2017 report" European Environment Agency

      32 Apte, J. S., "Addressing global mortality from ambient PM2.5" 49 : 8057-8066, 2015

      33 NIER, "2019 National air pollutants emission" National Institute of Environmental Research

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