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    마이크로파 보조 수열 합성법으로 제조한 Rhombohedral In2O3 나노입자의 α-pinene 감지 특성 = α-Pinene Sensing Properties of Rhombohedral In2O3 Nanoparticles Prepared using the Microwave-assisted Hydrothermal Method

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    https://www.riss.kr/link?id=A108364740

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    다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

    α-pinene is a natural volatile organic compound secreted by coniferous trees to protect themselves from attacks by insects, microorganisms, and viruses. Recently, studies have reported that α-pinene possesses pharmacological effects on various biological reactions such as anxiolytic, sleep-enhancing, anti-nociceptive, and inflammatory activity. Thus, forest bathing has recently received great attention as a novel therapy for treating severe diseases as well as psychological issues. However, appropriate places and timings for effective therapies are still veiled, because on-site monitoring of α-pinene gas in forests is barely possible. Although portable chemosensors could allow real-time analysis of α-pinene gas in forests, the α-pinene sensing properties of chemosensors have never been reported thus far. Herein, we report for the first time, the α-pinene sensing properties of an oxide semiconductor gas sensor based on rhombohedral In2O3 (h-In2O3) nanoparticles prepared by a microwave-assisted hydrothermal reaction. The h-In2O3 nanoparticle sensor showed a high response to α-pinene gas at ppm levels, even under humid conditions (for example, relative humidity of 50 %). The purpose of this research is to identify the potential of oxide semiconductor gas sensors for implementing portable devices that can detect α-pinene gas in forests in real-time.
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    α-pinene is a natural volatile organic compound secreted by coniferous trees to protect themselves from attacks by insects, microorganisms, and viruses. Recently, studies have reported that α-pinene possesses pharmacological effects on various biolo...

    α-pinene is a natural volatile organic compound secreted by coniferous trees to protect themselves from attacks by insects, microorganisms, and viruses. Recently, studies have reported that α-pinene possesses pharmacological effects on various biological reactions such as anxiolytic, sleep-enhancing, anti-nociceptive, and inflammatory activity. Thus, forest bathing has recently received great attention as a novel therapy for treating severe diseases as well as psychological issues. However, appropriate places and timings for effective therapies are still veiled, because on-site monitoring of α-pinene gas in forests is barely possible. Although portable chemosensors could allow real-time analysis of α-pinene gas in forests, the α-pinene sensing properties of chemosensors have never been reported thus far. Herein, we report for the first time, the α-pinene sensing properties of an oxide semiconductor gas sensor based on rhombohedral In2O3 (h-In2O3) nanoparticles prepared by a microwave-assisted hydrothermal reaction. The h-In2O3 nanoparticle sensor showed a high response to α-pinene gas at ppm levels, even under humid conditions (for example, relative humidity of 50 %). The purpose of this research is to identify the potential of oxide semiconductor gas sensors for implementing portable devices that can detect α-pinene gas in forests in real-time.

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    참고문헌 (Reference)

    1 김연정 ; 조봉재 ; 고명수 ; 정재민 ; 김희래 ; 송호선 ; 이지윤 ; 심상수 ; 김창종, "소나무 잎과 가지의 정유와 그 성분들의 항산화 및 항노화 작용" 대한약학회 54 (54): 215-225, 2010

    2 이대행 ; 박강수 ; 이세행 ; 송형명 ; 이기원 ; 정희윤 ; 서광엽 ; 조영관 ; 김은선, "무등산 숲과 도심에서 휘발성유기화합물질의 분포 특성" 한국분석과학회 28 (28): 246-254, 2015

    3 H. Yang, "α-Pinene, a major Constituent of pine tree oils, enhances non-rapid eye movement sleep in mice through GABAA-benzodiazepine receptors" 90 (90): 530-539, 2016

    4 A. L. Matsuo, "α-Pinene isolated from Schinus terebinthifolius Raddi(Anacardiaceae)induces apoptosis and confers antimetastatic protection in a melanoma model" 411 (411): 449-454, 2011

    5 D. S. Kim, "α-Pinene exhibits anti-inflammatory activity through the suppression of MAPKs and the NF-κB pathway in mouse peritoneal macrophages" 43 (43): 731-742, 2015

    6 J. W. Yoon, "Trimodally porous SnO2 nanospheres with three-dimensional interconnectivity and size tunability : a one-pot synthetic route and potential application as an extremely sensitive ethanol detector" 8 (8): e244-, 2016

    7 S. M. Majhi, "Recent advances in energy-saving chemiresistive gas sensors : A review" 79 : 105369-, 2021

    8 T. T. Liang, "Rapid synthesis of rhombohedral In2O3 nanoparticles via a microwave-assisted hydrothermal pathway and their application for conductometric ethanol sensing" 346 : 130578-, 2021

    9 B. Chen, "Localized surface plasmon resonance gas sensor of Au nano-islands coated with molecularly imprinted polymer : Influence of polymer thickness on sensitivity and selectivity" 231 : 787-792, 2016

    10 W. Q. Chen, "Inhibitory effects of α-pinene on hepatoma carcinoma cell proliferation" 15 (15): 3293-3297, 2014

    1 김연정 ; 조봉재 ; 고명수 ; 정재민 ; 김희래 ; 송호선 ; 이지윤 ; 심상수 ; 김창종, "소나무 잎과 가지의 정유와 그 성분들의 항산화 및 항노화 작용" 대한약학회 54 (54): 215-225, 2010

    2 이대행 ; 박강수 ; 이세행 ; 송형명 ; 이기원 ; 정희윤 ; 서광엽 ; 조영관 ; 김은선, "무등산 숲과 도심에서 휘발성유기화합물질의 분포 특성" 한국분석과학회 28 (28): 246-254, 2015

    3 H. Yang, "α-Pinene, a major Constituent of pine tree oils, enhances non-rapid eye movement sleep in mice through GABAA-benzodiazepine receptors" 90 (90): 530-539, 2016

    4 A. L. Matsuo, "α-Pinene isolated from Schinus terebinthifolius Raddi(Anacardiaceae)induces apoptosis and confers antimetastatic protection in a melanoma model" 411 (411): 449-454, 2011

    5 D. S. Kim, "α-Pinene exhibits anti-inflammatory activity through the suppression of MAPKs and the NF-κB pathway in mouse peritoneal macrophages" 43 (43): 731-742, 2015

    6 J. W. Yoon, "Trimodally porous SnO2 nanospheres with three-dimensional interconnectivity and size tunability : a one-pot synthetic route and potential application as an extremely sensitive ethanol detector" 8 (8): e244-, 2016

    7 S. M. Majhi, "Recent advances in energy-saving chemiresistive gas sensors : A review" 79 : 105369-, 2021

    8 T. T. Liang, "Rapid synthesis of rhombohedral In2O3 nanoparticles via a microwave-assisted hydrothermal pathway and their application for conductometric ethanol sensing" 346 : 130578-, 2021

    9 B. Chen, "Localized surface plasmon resonance gas sensor of Au nano-islands coated with molecularly imprinted polymer : Influence of polymer thickness on sensitivity and selectivity" 231 : 787-792, 2016

    10 W. Q. Chen, "Inhibitory effects of α-pinene on hepatoma carcinoma cell proliferation" 15 (15): 3293-3297, 2014

    11 B. Ince, "Effect of cineole, α-pinene, and camphor on survivability of skin flaps" 48 (48): 644-652, 2018

    12 K. A. Weerakoon, "Detecting insect infestation using a polymer based sensor array" 174 : 506-512, 2012

    13 G. Misra, "Aerobic biodegradation of selected monoterpenes" 45 (45): 831-838, 1996

    14 우준성 ; 양혜진 ; Changdev G. Gadhe ; Ae Nim Pae ; 조승목 ; 윤민석 ; 이창준, "3-Carene, a Phytoncide from Pine Tree Has a Sleep-enhancing Effect by Targeting the GABAA-benzodiazepine Receptors" 한국뇌신경과학회 28 (28): 593-601, 2019

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