Novel Lanthanide Coordination Polymers Prepared by Microwave Heating: [Ln(L)3(H2O)2](H2O)3 (Ln = Eu, Tb, Gd; L = trans-(3-py)–CH=CH–COO)

다국어 초록 (Multilingual Abstract)

Three isostructural lanthanide coordination polymers, [Ln(L)3(H2O)2](H2O)3 {Ln = Eu (1), Tb (2), Gd (3); L = trans-3-(3-pyridyl)acrylate, (3-py)–CH=CH–COO}, were prepared from HL, lanthanide nitrate, and NaOH in H2O by microwave heating. In all coordination polymers, the metal is bonded to eight oxygen atoms, and all pyridyl nitrogen atoms do not coordinate to the metals. All polymers have a 1-D loop-connected chain structure. The hydrogen atoms in the aqua ligands and lattice water molecules all participate in the hydrogen bonds of the O–H···O or O–H···N type. The hydrogen bonds connect the 1-D chains to create a 2-D network. Polymer 1 exhibited red luminescence in the solid state at room temperature.

참고문헌 (Reference)

1 Medina, M. E., 23 : 5283-5292, 2011

2 Liu, Z.-H., 27 : 3493-3499, 2008

3 Farha, O. K., 43 : 1166-1175, 2010

4 McKinlay, A. C., 49 : 6260-6266, 2010

5 Düren, T., 38 : 1237-1247, 2009

6 Teoa, P., 255 : 273-289, 2011

7 Hou, K.-L., 13 : 3884-3894, 2011

8 Liu, Y.-H., 12 : 1779-1783, 2010

9 Jang, Y. O., 29 : 2731-2738, 2010

10 Sun, Y. G., 35 : 916-919, 2009

11 Yun, S. Y., 935 : 75-81, 2009

12 Jiang, H.-L., 47 : 3351-3370, 2011

13 Chen, M.-S., 12 : 3267-3276, 2010

14 Muller, G., 9692-9707, 2009

15 Zhuang, G.-L., 4640-4642, 2009

16 Phetmun, H., 362 : 2435-2439, 2009

17 Yao, J.-C., 13 : 1178-1183, 2010

18 Tang, Y.-Z., 13 : 924-928, 2010

19 Liu, G.-X., 363 : 3727-3732, 2010

20 Peng, G., 13 : 599-602, 2010

21 Andruh, M., 48 : 3342-3359, 2009

22 Gunning, N. S., 2788-2792, 2005

23 Kurmoo, M., 44 : 217-224, 2005

24 Ayyappan, P., 40 : 4627-4632, 2001

25 Zhang, J., 20 : 4118-4121, 2001

26 Zhang, J., 2898-2900, 2000

27 Zhang, J., 1495-1496, 2000

28 Liu, C.-B., 62 : 2319-, 2006

29 Prior, T. J., 30 : 259-268, 2011

30 Patrícia, S., 10 : 2025-2028, 2010

31 Liang, P.-C., 11 : 699-708, 2011

32 Huh, S., 39 : 1261-1265, 2010

33 Bruker, SHELXTL, "Structure Determination Software Programs" Bruker Analytical X-ray Instruments Inc 1997

34 Sheldrick, G. M., "SADABS, Program for Absorption Correction" University of Göttingen 1996

35 Zhen Nu Zheng, "Microwave-assisted Preparation, Structures, and Photoluminescent Properties of [Ln(NO_3)_2(H_2O)_3(L)_2](NO_3)(H_2O) {Ln = Tb, Eu; L = 2-(4-pyridylium)ethanesulfonate, (4-pyH)^+-CH_2CH_2-SO_3^–}" 대한화학회 32 (32): 1859-1864, 2011

36 Ji Sun Lee, "Microwave Synthesis of a Porous Metal-Organic Framework, Nickel(II) Dihydroxyterephthalate and its Catalytic Properties in Oxidation of Cyclohexene" 대한화학회 31 (31): 1489-1495, 2010

37 허현수, "Lanthanide-Oxalate Coordination Polymers Formed by Reductive Coupling of Carbon Dioxide to Oxalate: [Ln2(3,5-pdc)2(C2O4)(H2O)4]？2H2O (Ln = Eu, Sm, Ho, Dy; pdc = Pyridinedicarbox" 대한화학회 27 (27): 1839-1843, 2006