Nuclear moments

목차 (Table of Contents)

• CONTENTS
• 1. INTRODUCTION TO NUCLEAR MOMENTS AND STATISTICS
• A. General Characteristics = 1
• 2. INTERACTION OF A NUCLEUS WITH ATOMIC AND MOLECULAR FIELDS
• A. Electrostatic Interaction = 3
• B. Magnetic Interaction = 9
• C. Appendix A. Form of Nuclear Electrical Quad겨pole Moment Interaction = 16
• D. Appendix B. Theoretical Restrictions on the Orders of Electrical Multiples = 23
• E. Appendix C. Magnetic Hyperfine Structure Constants = 24
• 3. EXPERIMENTAL METHODS or MEASURING NUCLEAR MOMENTS AND STATISTICS
• A. Hyperfine Structure in Optical Atomic Spectra = 27
• B. Band Spectra Measurements = 31
• C. Molecular and Atomic Beam Non-Resonance Methods = 33
• D. Molecular Beam Resonance Methods = 37
• E. Neutron Beam Resonance Method = 52
• F. Nuclear Resonance Absorption and Induction Methods = 54
• G. Microwave Spectroscopy Methods = 64
• H. Miscellaneous Methods = 67
• 4. RESULTS OF MEASUREMENTS OF NUCLEAR MOMENTS AND STATISTICS
• A. Results of Experiments to Determine an Absolute Scale for Nuclear Magnetic Moment Measurements = 70
• B. Magnetic Shielding and Resonance Shifts = 71
• C. Nuclear Moment Tables = 77
• D. Significance of Some Nuclear Moment Results = 90
• 5. APPLICATIONS TO CHEMISTRY AND SOLID STATE PHYSICS
• A. Introduction = 99
• B. Nuclear Quadrupole Interactions in Molecules. Nature of Chemical Bonds = 99
• C. Nuclear Quadrupole Interactions in Rigid Crystals = 101
• D. Direct Nuclear Spin-Spin Interactions in Free Molecules. Internuclear Spacings and Shapes of Molecular Vibrational Potential = 103
• E. Direct Nuclear Spin-Spin Interactions in Rigid Solids. Atomic Spacings and Bond Angles = 104
• F. Nuclear Paramagnetic Resonance Line Widths in Liquids and Gases. Collision Narrowing = 106
• G. The Effect of Nuclear Motion on Nuclear Resonance Spectra in Crystals. Hindered Rotation, Oscillation, Exchange, and Tunneling Effects = 109
• H. Thermal Relaxation Times = 110
• I. Shift of Resonance Frequency in Metals. Electron Distribution in Metals = 113
• J. Magnetic Shielding and Chemical Shifts = 114
• K. Temperature and Concentration Dependence of Magnetic Shielding. Molecular Association, Dissociation, and Chemical Exchange = 116
• L. Electron-Coupled Nuclear Spin-Spin Interactions = 117
• M. Spin-Rotational Magnetic Interaction = 119
• N. Rotational Magnetic Moments. Mean Square Radii of Electron Distribution in Molecules = 121
• O. Dependence of Diamagnetic Susceptibility on Molecular Orientation. Principal Second Moments of Electron Distribution in Molecules = 123
• P. Effects of Vibration and Centrifugal Stretching = 123
• Q. Microwave Spectroscopy = 124
• R. Paramagnetic and Ferromagnetic Resonance = 129
• APPENDIX A. Nuclear Shell Structure = 137
• REFERENCES = 142
• AUTHOR INDEX = 161
• SUBJECT INDEX = 167