Dynamic processes on solid surfaces

목차 (Table of Contents)

• CONTENTS
• CHAPTER 1. THEORY OF ATOMIC AND ELECTRONIC STRUCTURE OF SURFACES / Akio Yoshimori
• 1.1. Introduction = 1
• 1.2. Electronic Structures of Surface Systems = 7
• 1.3. Statistical Mechanics of Surface Systems = 18
• 1.4. Conclusion = 25
• References = 26
• CHAPTER 2. THEORY OF DYNAMICAL PROCESSES OF SURFACES / Masaru Tsukada
• 2.1. Introduction = 29
• 2.2. Mechanism of Dissociative Chemisorption = 30
• 2.3. Dynamics of Atoms and Molecules on Surfaces = 33
• 2.4. Effect of the Medium in the Nonadiabatic Processes = 42
• 2.5. Dynamics Involving Electron Transfer = 44
• 2.6. Mechanism of the Field-Induced Desorption = 49
• 2.7. Conclusion = 57
• References = 58
• CHAPTER 3. REAL-TIME MONITORING OF SURFACE PROCESSES BY A NOVEL FORM OF LOW-ENERGY ION SCATTERING / Masakazu Aono ; Mitsuhiro Katayama ; Eiichi Nomura
• 3.1. Introduction = 59
• 3.2. What Is CAICISS? = 61
• 3.3. Real-Time Monitoring by CAICISS = 61
• 3.4. Conclusion = 66
• References = 67
• CHAPTER 4. IN-SITU OBSERVATION OF SURFACE PROCESSES BY HIGH-RESOLUTION UHV ELECTRON MICROSCOPY / Kunio Takayanagi ; Katsumichi Yagi
• 4.1. Introduction = 69
• 4.2. Transmission Electron Microscopy of Surfaces = 70
• 4.3. Reflection Electron Microscopy of Surfaces = 80
• 4.4. Conclusion = 87
• References = 88
• CHAPTER 5. CATALYSIS BY STRUCTURALLY DESIGNED SURFACES / Yasuhiro Iwasawa
• 5.1. Introduction = 91
• 5.2. Strategy for Chemical Design of Metal Monomers and Dimers on Surfaces = 92
• 5.3. Dynamic Behavior of Intermediates and Active Sites during Catalytic Reactions = 101
• 5.4. Conclusion = 112
• References = 112
• CHAPTER 6. SURFACE COMPOUNDS FORMED ON SINGLE CRYSTAL METAL SURFACES DURING CATALYSIS / Ken-ichi Tanaka
• 6.1. Introduction = 115
• 6.2. OH Layer Formed on Ni(100) Surface = 117
• 6.3. Surface Nitrides Formed on Pd(100) and Rh(100) Surfaces = 127
• 6.4. Dynamical Behavior of a Pt-Rh Alloy on Single-Crystal Surfaces during Catalysis = 140
• References = 146
• CHAPTER 7. SURFACE-SUPPORTED METAL CLUSTERS : MOLECULAR APPROACHES TO HETEROGENEOUS CATALYSIS IN CO HYDROGENATION / Masaru Ichikawa
• 7.1. Metal Clusters as Molecular Precursors for Heterogeneous Catalysts = 149
• 7.2. Surface-Supported Clusters as Precursors for Tailored Metal Catalysts = 168
• 7.3. Bimetallic Clusters in Heterogeneous Catalysis = 171
• 7.4. Bimetallic Clusters in Zeolites = 193
• 7.5. Conclusion = 211
• References = 212
• CHAPTER 8. LASER-INDUCED SURFACE REACTIONS / Maki Kawai ; Tomoji Kawai
• 8.1. Introduction = 215
• 8.2. Interaction between a Solid Surface and a Photon = 215
• 8.3. Vibrationally Excited Phenomena = 218
• 8.4. Electronically Excited Phenomena = 224
• 8.5. Why Laser-Induced Surface Chemistry? = 232
• 8.6. Conclusion = 233
• References = 234
• CHAPTER 9. IR SPECTROSCOPIC STUDIES ON SURFACE REACTIONS / Takaharu Onishi
• 9.1. Introduction = 237
• 9.2. Experimental = 237
• 9.3. Hydrogen Adsorption over ZrO₂ = 238
• 9.4. Co Hydrogenation over ZrO₂ = 244
• 9.5. Dioxygen Adsorption and Isotope Exchange Reaction on Cerium Oxide = 247
• References = 257
• CHAPTER 10. CATALYSIS BY HETEROPOLY COMPOUNDS IN THE PSEUDOLIQUID PHASE / Toshio Okuhara ; Makoto Misono
• 10.1. Overview of Catalysis by Heteropoly Compounds = 259
• 10.2. Pseudoliquid Phase = 263
• 10.3. Bulk-Type(Ⅰ) Reactions = 267
• 10.4. Bulk-Type(Ⅱ) Reactions = 276
• 10.5. Future Aspects = 280
• References = 280
• CHAPTER 11. SURFACE REACTIONS CONTROLLED BY THE BULK MIGRATION OF OXIDE IONS : WORKING MECHANISM OF MULTICOMPONENT BISMUTH MOLYBDATE AND SCHEELITE-TYPE OXIDE CATALYSTS / Yoshihiko Moro-oka ; Wataru Ueda ; De-Hua He
• 11.1. Introduction = 283
• 11.2. Characterization and Working Mechanism of Multicomponent Bismuth Molybdate Catalysts = 284
• 11.3. Application of the Principle to the Multicomponent Metal Oxide Catalysts Having the Scheelite Structure = 297
• References = 305
• CHAPTER 12. CHIRALITY RECOGNITION BY A CLAY SURFACE MODIFIED WITH AN OPTICALLY ACTIVE METAL CHELATE / Akihiko Yamagishi
• 12.1. Introduction = 307
• 12.2. Structures of Clay Minerals = 308
• 12.3. Adsorption Structures of Metal Complexes on a Clay Surface = 310
• 12.4. X-Ray Diffraction Studies on the Bound Structures of Chelates in the Interlayer Space of a Clay = 315
• 12.5. Electron Spin Resonance Studies on Adsorption of Metal Complexes = 322
• 12.6. Electro-Optical Studies on the Adsorption of Chelates by a Colloidal Clay = 325
• 12.7. Stopped-Flow Electric Dichroism Studies on the Adsorption Mechanism of a Chelate by a Clay = 328
• 12.8. Molecular Models for Racemic and Enantiomeric Adsorptions of Chelates on a Clay Surface = 332
• 12.9. Chirality Recognition by a Clay Surface Modified with an Optically Active Chelate = 335
• 12.10. Application of Clay - Chelate Adducts to Liquid Chromatographic Resolution of Organic Enantiomers = 339
• 12.11. Asymmetric Syntheses on a Clay Surface Modified with Optically Active Metal Chelates = 342
• References = 346
• INDEX = 349