Porphyrin-Functionalized Mesoporous Organosilicas: Bridging Molecular Design and Practical Chem-Bio Use = 포피린 기반 메조다공성 유기실리카: 분자 설계와 화학·생물 기반 응용

목차 (Table of Contents)

• Contents
• Abstract i
• 국문 초록 iv
• Contents vii
• List of Figures x
• List of Tables xvii
• I. General Introduction 1
• 1.1. Organosilica 2
• 1.2. Synthesis Methods of Mesoporous Materials 10
• 1.2.1. Sol-Gel Method 10
• 1.2.2. Porphyrinosilica 11
• 1.3. References 12
• II. Synthesis of Organosilica 14
• 2.1. Introduction 15
• 2.2. Experimental section 18
• 2.2.1. Materials 18
• 2.2.2. Synthesis 18
• 2.2.3. Spectrophotometric characterization 22
• 2.2.4. Characterizations and Measurements 25
• 2.3. Result and discussion 26
• 2.4. Conclusion 38
• 2.5. References 39
• III. Porphyrin-Derivatized Silica 41
• 3.1. Introduction 42
• 3.2. Chemical warfare agents (Nerve agents) 43
• 3.3. Experimental section 50
• 3.3.1. Preparation 50
• 3.3.2. Chemicals and Reagents 52
• 3.3.3. Synthesis of Fe3O4@PD@UiO-66 52
• 3.3.4. Modification of the surface of the Fe3O4 core with polydopamine 53
• 3.3.5. Synthesis of Fe3O4@PD@UiO-66/Arg 54
• 3.4. Result and discussion 61
• 3.5. Conclusion 93
• 3.6. References 94
• IV. Porphyrin-Derivatized Nanofibers 99
• 4.1. Introduction 100
• 4.2. Experimental section 104
• 4.2.1. Materials 104
• 4.3. Results and discussion 107
• 4.4. Conclusion 129
• 4.5. References 129
• V. Synthesis of Porphyrinosilica 133
• 5.1. Introduction 134
• 5.2. Experimental section 136
• 5.3. Results and discussion 140
• 5.4. Conclusion 184
• 5.5. References 185
• VI. Summary 188
• VII. Acknowledgement in Korean 190