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      알칼리용액에서 La0.8Sr0.2MnO3 페롭스카이트 촉매의 산소환원 및 발생반응에서 도전재의 영향 = Effect of Conductive Additives in La0.8Sr0.2MnO3 Perovskite Electrodes for Oxygen Reduction and Evolution in Alkaline Solution

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      https://www.riss.kr/link?id=A103557430

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      The effects of conductive additives in a La0.8Sr0.2MnO3 perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM).
      The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.
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      The effects of conductive additives in a La0.8Sr0.2MnO3 perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder ...

      The effects of conductive additives in a La0.8Sr0.2MnO3 perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM).
      The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.

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      참고문헌 (Reference)

      1 정문국, "나노사이즈 불화탄소수지 용액 농도에 따른 GDL 발수 코팅" 한국수소및신에너지학회 20 (20): 323-330, 2009

      2 N. Staud, "The Corrosion of Carbon Black Anodes in Alkaline Electrolyte: II. Acetylene Black and the Effect of Oxygen Evolution Catalysts on Corrosion" 133 : 1079-, 1986

      3 T. Hang, "Super-hydrophobic nickel films with micro-nano hierarchical structure prepared by electrodeposition" 256 : 2400-, 2010

      4 F. Bidault, "Review of gas diffusion cathodes for alkaline fuel cells" 187 : 39-, 2009

      5 심중표, "Preparation and Characterization for Carbon Composite Gas Diffusion Layer on Polymer Electrolyte Membrane Fuel Cells" 한국수소및신에너지학회 23 (23): 34-42, 2012

      6 F.A.L. Dullien, "Porous Media: Fluid Transport and Pore Structure" Academic Press 1992

      7 A.W. Adamson, "Physical Chemistry of Surfaces" John Wiley and Sons 1982

      8 K. Nishio, "Oxygen reduction and evolution reactions of air electrodes using a perovskite oxide as an electrocatalyst" 278 : 645-, 2015

      9 김재호, "Ni-PTFE 복합도금기술을 이용한 알칼리형 연료전지용 전극 제조" 한국수소및신에너지학회 20 (20): 361-370, 2009

      10 O. Meincke, "Mechanical properties and electrical conductivity of carbonnanotube filled polyamide-6 and its blends with acrylonitrile/butadiene/styrene" 45 : 739-, 2004

      1 정문국, "나노사이즈 불화탄소수지 용액 농도에 따른 GDL 발수 코팅" 한국수소및신에너지학회 20 (20): 323-330, 2009

      2 N. Staud, "The Corrosion of Carbon Black Anodes in Alkaline Electrolyte: II. Acetylene Black and the Effect of Oxygen Evolution Catalysts on Corrosion" 133 : 1079-, 1986

      3 T. Hang, "Super-hydrophobic nickel films with micro-nano hierarchical structure prepared by electrodeposition" 256 : 2400-, 2010

      4 F. Bidault, "Review of gas diffusion cathodes for alkaline fuel cells" 187 : 39-, 2009

      5 심중표, "Preparation and Characterization for Carbon Composite Gas Diffusion Layer on Polymer Electrolyte Membrane Fuel Cells" 한국수소및신에너지학회 23 (23): 34-42, 2012

      6 F.A.L. Dullien, "Porous Media: Fluid Transport and Pore Structure" Academic Press 1992

      7 A.W. Adamson, "Physical Chemistry of Surfaces" John Wiley and Sons 1982

      8 K. Nishio, "Oxygen reduction and evolution reactions of air electrodes using a perovskite oxide as an electrocatalyst" 278 : 645-, 2015

      9 김재호, "Ni-PTFE 복합도금기술을 이용한 알칼리형 연료전지용 전극 제조" 한국수소및신에너지학회 20 (20): 361-370, 2009

      10 O. Meincke, "Mechanical properties and electrical conductivity of carbonnanotube filled polyamide-6 and its blends with acrylonitrile/butadiene/styrene" 45 : 739-, 2004

      11 K.A. Striebel, "Laboratory-scale evaluation of secondary alkaline zinc batteries for electric vehicles" 47 : 1-, 1994

      12 S.L. Medway, "In situ studies of the oxidation of nickel electrodes in alkaline solution" 587 : 172-, 2006

      13 J. Shim, "Improved performance of Raney nickel electrode by the addition of electrically conductive materials for hydrogen oxidation reaction" 69 : 72-, 2001

      14 J. Shim, "Hydrogen oxidation characteristics of Raney nickel electrodes with carbon black in an alkaline fuel cell" 74 : 151-, 1998

      15 Z. Chen, "Highly durable and active non-precious air cathode catalyst for zinc air battery" 196 : 3673-, 2011

      16 J. Geertsma, "Estimating the coefficient of inertial resistance in fluid flow through porous media" 10 : 445-, 1974

      17 K. Lopez, "Electrochemical characterizations of LaMO3 (M = Co, Mn, Fe, and Ni) and partially substituted LaNixM1-xO3 (x = 0.25 or 0.5) for oxygen reduction and evolution in alkaline solution" 45 : 313-, 2015

      18 K. Miyasaka, "Electrical conductivity of carbon-polymer composites as a function of carbon content" 17 : 1610-, 1982

      19 C. Han, "Effect of Carbon Content on the Physical Properties of Carbon Composite Gas Diffusion Layer in PEMFCs" 7 : 8627-, 2012

      20 T. Poux, "Dual role of carbon in the catalytic layers of perovskite/carbon composites for the electrocatalytic oxygen reduction reaction" 189 : 83-, 2012

      21 J. Suntivich, "Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries" 3 : 546-, 2011

      22 K. Kinoshita, "Carbon - Electrochemical and physicochemical properties" John Wiley & Sons 334-, 1988

      23 J.T. Gostick, "Capillary pressure and hydrophilic porosity in gas diffusion layers for polymer electrolyte fuel cells" 156 : 375-, 2006

      24 J.W. Evans, "A zinc-air cell employing a packed bed anode" 21 : 105-, 1991

      25 V. Neburchilov, "A review on air cathodes for zinc-air fuel cells" 195 : 1271-, 2010

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