수소저장용 나노구조 탄소재료의 기체-고체간 상호작용거동 = Gas-Solid Interaction Behaviors of Nanostructured Carbon Materials for Hydrogen Storage

목차 (Table of Contents)

• Chapter 1. Overview of Hydrogen Energy 1
• 1.1. General Background 1
• 1.2. Unique Properties of Hydrogen 4
• 1.3. Hydrogen as an Energy Carrier 6
• 1.4. Hydrogen Storage Technologies 10
• 1.4.1. Introduction 10
• 1.4.2. Compressed Hydrogen 13
• 1.4.3. Liquefied Hydrogen 14
• 1.4.4. Chemically Absorbed Hydrogen 15
• 1.4.5. Physically Adsorbed Hydrogen 17
• Chapter 2. Literature of Various Solid Materials for Hydrogen Storage 20
• 2.1. Introduction 20
• 2.2. Carbon Materials for Hydrogen Storage 25
• 2.2.1. Carbon Nanotubes 25
• 2.2.2. Activated Carbons 29
• 2.2.3. Templated Carbons 31
• 2.2.4. Graphene and their Derived Carbon 35
• 2.3. Non-carbonaceous Materials for Hydrogen Storage 37
• 2.3.1. Zeolite 37
• 2.3.2. Metal-organic Frameworks (MOF) 39
• Chapter 3. Theoretical Backgrounds and Objectives of The Works for Hydrogen Storage 43
• 3.1. Carbon Nanotubes 43
• 3.1.1. Physically Activated Carbon Nanotubes 43
• 3.1.2. Chemically Activated Carbon Nanotubes 44
• 3.2. Templated Nanoporous Carbons 47
• 3.2.1. Ordered Nanoporous Carbons Prepared with Carbonization Temperatures 47
• 3.2.2. Acid-treated Nanoporous Carbons 49
• 3.2.3. Zeolite-casted Microporous Carbons 50
• 3.3. Hybrid Carbonaceous Composites 53
• 3.3.1. Platinum-doped Activated Carbon/MOF-5 Hybrid Composites 53
• 3.3.2. Nickel-doped Graphite Oxide/MIL-101 Hybrid Composites 57
• 3.4. Graphite-Derived Materials 58
• 3.4.1. Chemically Modified Graphite Oxides with Tunable Interlayer Distances and Different Oxygen Functionalities 58
• Chapter 4. Experimental Section 60
• 4.1. Activation Process of Carbon Nanotubes 60
• 4.1.1. Purification of Carbon Nanotubes 60
• 4.1.2. Physically Activated Carbon Nanotubes 61
• 4.1.3. Chemically Activated Carbon Nanotubes 62
• 4.2. Synthesis of Templated Nanoporous Carbons 64
• 4.2.1. Scheme on the Synthesis of SBA-15 and Templated Nanoporous Carbons 64
• 4.2.2. Ordered Nanoporous Carbons Prepared with Carbonization Temperatures 65
• 4.2.3. Acid-treated Nanoporous Carbons 67
• 4.2.4. Scheme on the Synthesis of Microporous Carbon by Nanocasting Technique 69
• 4.2.5. Zeolite-casted Microporous Carbons 70
• 4.3. Optimization of Hybrid Carbonaceous Composites 72
• 4.3.1. Platinum-doped Activated Carbon/MOF-5 Hybrid Composites 72
• 4.3.2. Nickel-doped Graphite Oxide/MIL-101 Hybrid Composites 75
• 4.4. Graphite-derived Materials 77
• 4.4.1. Chemically Modified Graphite Oxides with Tunable Interlayer Distances and Different Oxygen Functionalities 77
• 4.5. Evaluation of Hydrogen Storage Capacities 79
• Chapter 5. Results and Discussion 80
• 5.1. Carbon Nanotubes for Hydrogen Storage Behaviors 80
• 5.1.1. Physically Activated Carbon Nanotubes 80
• 5.1.2. Chemically Activated Carbon Nanotubes 94
• 5.2. Hydrogen Storage Behaviors of Templated Nanoporous Carbons 108
• 5.2.1. Ordered Nanoporous Carbons Prepared with Carbonization Temperatures 108
• 5.2.2. Acid-treated Nanoporous Carbons 122
• 5.2.3. Zeolite-casted Microporous Carbons 133
• 5.3. Hybrid Carbonaceous Composites 144
• 5.3.1. Platinum-doped Activated Carbon/MOF-5 Hybrid Composites 144
• 5.3.2. Nickel-doped Graphite Oxide/MIL-101 Hybrid Composites 156
• 5.4. Graphite-derived Materials 156
• 5.4.1. Chemically Modified Graphite Oxides with Tunable Interlayer Distances and Different Oxygen Functionalities 166
• CONCLUSIONS 177
• REFERENCES 181