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      비생물기원 수소 생산성의 지질학적 평가 관련 해외 연구 동향: 리뷰 논문 = Research Trends of Foreign Countries on Geological Evaluation of Abiotic Hydrogen Productivity: A Review

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      https://www.riss.kr/link?id=A108415873

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      다국어 초록 (Multilingual Abstract)

      The world’s long reliance on fossil fuels (e.g., oil, coal, and natural gas) is severely changing its environment and climate. Energy research has focused on developing hydrogen as the most promising energy carrier and a key technology for sustainab...

      The world’s long reliance on fossil fuels (e.g., oil, coal, and natural gas) is severely changing its environment and climate. Energy research has focused on developing hydrogen as the most promising energy carrier and a key technology for sustainable energy development. Hydrogen can be classified as gray, blue, green, and otherwise according to the raw materials and methods used for production and processing. For the development of hydrogen energy, geologists are attempting to identify the mechanism of abiotic hydrogen generation by serpentinization or hydrothermal alteration. Teams in the United States, France, and Australia have researched laboratory-scale hydrogen production through water-rock interactions under various conditions, whereas there has been almost no research on abiotic hydrogen in South Korea. This paper reviews the current state of international research on hydrothermal alteration and offers suggestions for future investigations of abiotic hydrogen production in South Korea.

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      국문 초록 (Abstract)

      최근까지 전 세계 에너지 수요는 화석연료(석유, 석탄, 천연가스)에 의존해왔으며, 이로 인해 지구온난화와 같은 심각한 전 지구적 환경 변화를 유발하고 있다. 에너지 관련 분야의 연구자들...

      최근까지 전 세계 에너지 수요는 화석연료(석유, 석탄, 천연가스)에 의존해왔으며, 이로 인해 지구온난화와 같은 심각한 전 지구적 환경 변화를 유발하고 있다. 에너지 관련 분야의 연구자들은 가장 유망한 에너지 운반체이자 지속 가능한 에너지 개발의 핵심 기술인 수소 에너지에 주목하고 있다. 수소 연료는 생산을 위해 사용되는 연료와 공정처리과정에 따라 그레이수소, 블루수소, 그린수소 등으로 분류된다. 지질학자들은 수소 에너지 개발을 위해 사문암화작용 또는 열수변질작용에 의한 비생물기원 수소 생산메커니즘 규명 연구를 진행하고 있다. 특히, 미국, 호주, 프랑스 등의 국가에서는 실내실험 규모의 물-암석 반응 실험을 통해 다양한 조건에서의 수소생산성을 연구하였으나, 국내에서는 비생물기원 수소에 대한 연구가 거의 진행된 바 없는 실정이다. 이에 본 리뷰에서는 비생물기원 수소 생산을 위해 물-암석 반응 실험을 진행한 해외 연구 사례의 현황을 파악하고 향후 국내 비생물기원 수소 생산 실험을 위한 발전방향을 제시하였다.

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      참고문헌 (Reference) 논문관계도

      1 김진호 ; 박동규 ; 김지현 ; 김현지 ; 김효식 ; 강석환 ; 유재홍, "탄소중립을 위한 CO2 free 수소 생산 기술 동향" 한국에너지기후변화학회 16 (16): 103-127, 2021

      2 Lazar, C., "Using silica activity to model redox-dependent fluid compositions in serpentinites from 100 to 700°C and from 1 to 20 kbar" 61 (61): egaa101-, 2020

      3 Bach, W., "Unraveling the sequence of serpentinization reactions : Petrography, mineral chemistry, and petrophysics of serpentinites from MAR 15°N(ODP Leg 209, Site 1274)" 33 (33): L13306-, 2006

      4 Ehhalt, D. H., "The tropospheric cycle of H2 : A critical review" 61 (61): 500-535, 2009

      5 Frost, B. R., "The process of serpentinization in dunite from New Caledonia" 178 : 24-39, 2013

      6 Kyser, T. K., "The origin of fluids associated with serpentinization; evidence from stableisotope compositions" 37 (37): 223-237, 1999

      7 Deville, E., "The origin of N2-H2-CH4-rich natural gas seepages in ophiolitic context : A major and noble gases study of fluid seepages in New Caledonia" 440 : 139-147, 2016

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      10 Bowers, T. S., "Stable isotope signatures of water-rock interaction in mid-ocean ridge hydrothermal systems: Sulfur, oxygen, and hydrogen" 94 (94): 5775-5786, 1989

      1 김진호 ; 박동규 ; 김지현 ; 김현지 ; 김효식 ; 강석환 ; 유재홍, "탄소중립을 위한 CO2 free 수소 생산 기술 동향" 한국에너지기후변화학회 16 (16): 103-127, 2021

      2 Lazar, C., "Using silica activity to model redox-dependent fluid compositions in serpentinites from 100 to 700°C and from 1 to 20 kbar" 61 (61): egaa101-, 2020

      3 Bach, W., "Unraveling the sequence of serpentinization reactions : Petrography, mineral chemistry, and petrophysics of serpentinites from MAR 15°N(ODP Leg 209, Site 1274)" 33 (33): L13306-, 2006

      4 Ehhalt, D. H., "The tropospheric cycle of H2 : A critical review" 61 (61): 500-535, 2009

      5 Frost, B. R., "The process of serpentinization in dunite from New Caledonia" 178 : 24-39, 2013

      6 Kyser, T. K., "The origin of fluids associated with serpentinization; evidence from stableisotope compositions" 37 (37): 223-237, 1999

      7 Deville, E., "The origin of N2-H2-CH4-rich natural gas seepages in ophiolitic context : A major and noble gases study of fluid seepages in New Caledonia" 440 : 139-147, 2016

      8 Zgonnik, V., "The occurrence and geoscience of natural hydrogen: A comprehensive review" 203 : 103140-, 2020

      9 Lollar, B. S., "The contribution of the Precambrian continental lithosphere to global H2 production" 516 (516): 379-382, 2014

      10 Bowers, T. S., "Stable isotope signatures of water-rock interaction in mid-ocean ridge hydrothermal systems: Sulfur, oxygen, and hydrogen" 94 (94): 5775-5786, 1989

      11 Berndt, M. E., "Reduction of CO2 during serpentinization of olivine at 300°C and 500bar" 24 (24): 351-354, 1996

      12 Magaritz, M., "Oxygen and hydrogen isotope studies of serpentinization in the Troodos ophiolite complex, Cyprus" 23 (23): 8-14, 1974

      13 Frost, B. R., "On the stability of sulfides, oxides, and native metals in serpentinite" 26 (26): 31-63, 1985

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      15 Lang, S. Q., "Microbial utilization of abiogenic carbon and hydrogen in a serpentinite-hosted system" 92 : 82-99, 2012

      16 Flores, G. E., "Microbial community structure of hydrothermal deposits from geochemically different vent fields along the Mid-Atlantic Ridge" 13 (13): 2158-2171, 2011

      17 Siegel, K., "Magmatic evolution and controls on rare metal-enrichment of the Strange Lake A-type peralkaline granitic pluton, Québec-Labrador" 308 : 34-52, 2018

      18 Proskurowski, G., "Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer" 229 (229): 331-343, 2006

      19 Miller, H. M., "Low temperature hydrogen production during experimental hydration of partially-serpentinized dunite" 209 : 161-183, 2017

      20 Pokrovsky, O. S., "Kinetics of brucite dissolution at 25°C in the presence of organic and inorganic ligands and divalent metals" 69 : 905-918, 2005

      21 Blattner, P., "Isotope shift data and the natural evolution of geothermal systems" 49 (49): 187-203, 1985

      22 Holm, N. G., "Initial indications of abiotic formation of hydrocarbons in the Rainbow ultramafic hydrothermal system, Mid-Atlantic Ridge" 191 (191): 1-8, 2001

      23 Janecky, D. R., "Hydrothermal serpentinization of peridotite within the oceanic crust: Experimental investigations of mineralogy and major element chemistry" 50 (50): 1357-1378, 1986

      24 Marques, J. M., "Hydrothermal alteration of Hercynian granites, its significance to the evolution of geothermal systems in granitic rocks" 39 (39): 152-160, 2010

      25 Wood Mackenzie, "Hydrogen: the US$600 billion investment opportunity"

      26 Wenner, D. B., "Hydrogen, oxygen and carbon isotopic evidence for the origin of rodingites in serpentinized ultramafic rocks" 43 (43): 603-614, 1979

      27 Bryanchaninova, N. I., "Hydrogen isotope geochemistry of chromite-bearing ultramafic rocks of the Urals" 395 (395): 359-363, 2004

      28 Boreham, C. J., "Hydrogen in Australian natural gas : Occurrences, sources and resources" 61 (61): 163-191, 2021

      29 Neal, C., "Hydrogen generation from mantle source rocks in Oman" 66 : 315-320, 1983

      30 Mayhew, L. E., "Hydrogen generation from lowtemperature water-rock reactions" 6 (6): 478-484, 2013

      31 Truche, L., "Hydrogen generation during hydrothermal alteration of peralkaline granite" 308 : 42-59, 2021

      32 McCollom, T. M., "Hydrogen generation and iron partitioning during experimental serpentinization of an olivine-pyroxene mixture" 282 : 55-75, 2020

      33 Angino, E. E., "Hydrogen and nitrogen-origin, distribution, and abundance, a followup" 82 : 142-146, 1984

      34 Truche, L., "Hydrogen and abiotic hydrocarbons: Molecules that change the world" 16 (16): 13-18, 2020

      35 Sleep, N. H., "H2-rich fluids from serpentinization: Geochemical and biotic implications" 101 (101): 12818-12823, 2004

      36 Schroeder, T., "Geologic implications of seawater circulation through peridotite exposed at slow-spreading mid-ocean ridges" 30 (30): 367-370, 2002

      37 Charlou, J. L., "Geochemistry of high H2 and CH4 vent fluids issuing from ultramafic rocks at the Rainbow hydrothermal field(36°14'N, MAR)" 191 (191): 345-359, 2002

      38 Morrill, P. L., "Geochemistry and geobiology of a present-day serpentinization site in California: The Cedars" 109 : 222-240, 2013

      39 McCollom, T. M., "Generation of hydrogen and methane during experimental low-temperature reaction of ultramafic rocks with water" 16 (16): 389-406, 2016

      40 Wenner, D. B., "D/H and O18/O16 studies of serpentinization of ultramaflc rocks" 38 (38): 1255-1286, 1974

      41 Des Marais, D. J., "Ciba Foundation Symposium 202 - Evolution of Hydrothermal Ecosystems on Earth (And Mars?)" John Wiley & Sons, Ltd 83-98, 2007

      42 Jones, L. C., "Carbonate control of H2 and CH4 production in serpentinization systems at elevated P-Ts" 37 (37): L14306-, 2010

      43 Moore, B. J., "Analyses of natural gases, 1917-85 (No. 9129)" US Department of the Interior, Bureau of Mines 1987

      44 Klein, F., "Abiotic sources of molecular hydrogen on Earth, Elements: An International Magazine of Mineralogy" 16 (16): 19-24, 2020

      45 Etiope, G., "Abiotic methane flux from the Chimaera seep and Tekirova ophiolites (Turkey): Understanding gas exhalation from low temperature serpentinization and implications for Mars" 310 (310): 96-104, 2011

      46 Murray, J., "Abiotic hydrogen generation from biotite-rich granite : A case study of the Soultz-sous-Forêts geothermal site, France" 119 : 104631-, 2020

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