본 연구에서는 50 wt%에 달하는 매우 높은 Pt 담지량에서도 장기내구성이 우수한 연료전지용 Pt/MWCNT 촉매를 마이크로파를 이용한 폴리올법을 이용하여 제조하였다. X선 회절분석법과 투과전자...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=A101102310
이태규 (울산대학교) ; 허승현 (울산대학교) ; Lee, Tae Kyu ; Hur, Seung Hyun
2012
Korean
KCI등재,ESCI
학술저널
264-269(6쪽)
0
0
상세조회0
다운로드국문 초록 (Abstract)
본 연구에서는 50 wt%에 달하는 매우 높은 Pt 담지량에서도 장기내구성이 우수한 연료전지용 Pt/MWCNT 촉매를 마이크로파를 이용한 폴리올법을 이용하여 제조하였다. X선 회절분석법과 투과전자...
본 연구에서는 50 wt%에 달하는 매우 높은 Pt 담지량에서도 장기내구성이 우수한 연료전지용 Pt/MWCNT 촉매를 마이크로파를 이용한 폴리올법을 이용하여 제조하였다. X선 회절분석법과 투과전자현미경 분석결과 마이크로파 조사시간이 늘어남에 따라 Pt의 크기가 증가하였다. 마이크로파 조사시간이 10분, 20분, 30분일 경우 Pt 크기는 각각 4.1, 4.9, 8.5 nm로 나타났다. 마이크로파를 사용하지 않은 기존 폴리올 방법에 의해 제조된 촉매와 비교하였을 경우 Pt 분산도와 장기내구성이 증가한 것으로 나타났다.
다국어 초록 (Multilingual Abstract)
In this study, highly loaded(50 wt%) and very stable Pt/MWCNT catalysts for Polymer Electrolyte Membrane Fuel Cells(PEMFCs) are synthesized in short time scale by microwave assisted polyol method with different microwave irradiation time. The XRD and ...
In this study, highly loaded(50 wt%) and very stable Pt/MWCNT catalysts for Polymer Electrolyte Membrane Fuel Cells(PEMFCs) are synthesized in short time scale by microwave assisted polyol method with different microwave irradiation time. The XRD and TEM results show that the Pt size becomes bigger as the microwave irradiation time increases. The mean Pt sizes of fabricated catalysts are 4.1, 4.9 and 8.5 nm when the microwave are irradiated for 10, 20 and 30 min, respectively. When compared with Pt catalyst made by conventional polyol method, it shows better long term durability due to the better Pt dispersion on the MWCNT surface.
참고문헌 (Reference)
1 Y. Shao, "Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cell" 171 : 558-, 2007
2 L. Gan, "The effect of particle size on the interaction of Pt catalyst particles with a carbon black support" 25 : 53-, 2010
3 Y. Takasu, "Size effects of ultrafine Pt-Ru particles on the electrocatalytic oxidation of methanol" 341 : 2001
4 X. Yan, "Size control of polymer-stabilized ruthenium nanoparticles by polyol reduction" 11 : 3387-, 2001
5 X. Yu, "Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC" 172 : 145-, 2007
6 W. X. Chen, "Preparation of Pt and PtRu nanoparticles supported on carbon nanotubes by microwave-assisted heating polyol process" 58 : 3166-, 2004
7 S. Chen, "Preparation and characerization of surface-coated ZnS nanoparticles" 15 : 8100-, 1999
8 E. Lebegue, "Polyol synthesis of nanosized Pt/C electrocatalysts assisted by pulse microwave activation" 196 : 920-, 2011
9 Y. Y. Chu, "Performance of Pt/C catalysts prepared by microwaveassistedpolyol process for methanol electrooxidation" 195 : 1799-, 2010
10 L. K. Kurihara, "Nanocrystalline metallic powders and films produced by the polyol method" 5 : 607-, 1995
1 Y. Shao, "Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cell" 171 : 558-, 2007
2 L. Gan, "The effect of particle size on the interaction of Pt catalyst particles with a carbon black support" 25 : 53-, 2010
3 Y. Takasu, "Size effects of ultrafine Pt-Ru particles on the electrocatalytic oxidation of methanol" 341 : 2001
4 X. Yan, "Size control of polymer-stabilized ruthenium nanoparticles by polyol reduction" 11 : 3387-, 2001
5 X. Yu, "Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC" 172 : 145-, 2007
6 W. X. Chen, "Preparation of Pt and PtRu nanoparticles supported on carbon nanotubes by microwave-assisted heating polyol process" 58 : 3166-, 2004
7 S. Chen, "Preparation and characerization of surface-coated ZnS nanoparticles" 15 : 8100-, 1999
8 E. Lebegue, "Polyol synthesis of nanosized Pt/C electrocatalysts assisted by pulse microwave activation" 196 : 920-, 2011
9 Y. Y. Chu, "Performance of Pt/C catalysts prepared by microwaveassistedpolyol process for methanol electrooxidation" 195 : 1799-, 2010
10 L. K. Kurihara, "Nanocrystalline metallic powders and films produced by the polyol method" 5 : 607-, 1995
11 K. W. Nam, "Monodispersed PtCo nanoparticles on hexadecyltrimethylammonium bromide treated graphene as an effective oxygen reduction reaction catalyst for proton exchange membrane fuel cells" PERGAMON-ELSEVIER SCIENCE LTD 50 (50): 3739-3747, 2012
12 W. X. Chen, "Microwave-assisted synthesis of carbon supported Pt nanoparticles for fuel cell applications" 2588 : 2002
13 S. Yoshida, "Microwave-assisted chemical modification of carbon nanohorns: Oxidation and Pt deposition" 433 : 97-, 2006
14 J. Zhao, "Microwave polyol synthesis of Pt/C catalysts with sizecontrolled Pt particles for methanol electrocatalytic oxidation" 41 : 5514-, 2006
15 W. Chen, "Microwave heated polyol synthesis of carbon nanotubes supported Pt nanoparticles for methanol electrooxidation" 91 : 124-, 2005
16 F. Lufrano, "Improvement in the diffusion characteristics of low Pt-loaded electrodes for PEFCs" 29 : 445-, 1999
17 T. Lee, "Improved durability of Pt/CNT catalysts by the low temperature selfcatalyzed reduction for the PEM fuel cells" 37 : 17992-18000, 2012
18 L. Li, "Electrochemical durability of carbon nanotubes at 80oC" 178 : 75-, 2008
19 S. J. Yoo, "Effects of particle size on surface electronic and electrocatalytic properties of Pt/TiO2 nanocatalysts" ROYAL SOC CHEMISTRY 46 : 794-796, 2010
20 J. Zheng, "Effect of the microwave thermal treatment condition on Pt-Fe/C alloy catalyst performance" 37 : 12994-, 2012
21 Z. Xu, "Effect of particle size on the activity and durability ofthe Pt/C electrocatalyst for proton exchange membranefuel cells" 111 : 264-, 2012
22 E. S. Sayin, "Durability of PEM fuel cell electrocatalysts prepared by microwave irradiation technique" 37 : 16663-, 2012
23 X. Wang, "Durability investigation of carbon nanotube as catalystsupport for proton exchange membrane fuel cell" 158 : 154-, 2006
24 A. Pozio, "Comparison of high surface Pt/C catalysts by cyclic voltammetry" 105 : 13-, 2002
25 S. H. Kim, "Catalytic performance of acid-treated multi-walled carbon nanotube-supported platinum catalyst for PEM fuel cells" PERGAMON-ELSEVIER SCIENCE LTD 47 : 2760-2764, 2012
26 Z. Liu, "Carbon-supported Pt nanoparticles as catalysts forproton exchange membrane fuel cells" 139 : 73-, 2005
27 S. Koh, "Activity of ordered and disordered Pt-Co alloy phasesfor the electroreduction of oxygen in catalysts withmultiple coexisting phases" 172 : 50-, 2007
28 S. Zhang, "A review of accelerated stress tests of MEA durability in PEM fuel cells" 34 : 388-, 2009
KNiFe(CN)6 전기화학적 이온교환체를 이용한 세슘 양이온의 분리에 관한 연구
리튬이온전지용 소프트카본 음극 소재의 인산 처리에 대한 연구
Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine 복합체 고분자 양극재료의 합성과 전기화학적 특성
학술지 이력
연월일 | 이력구분 | 이력상세 | 등재구분 |
---|---|---|---|
2027 | 평가예정 | 재인증평가 신청대상 (재인증) | |
2021-01-01 | 평가 | 등재학술지 유지 (재인증) | |
2018-01-01 | 평가 | 등재학술지 선정 (계속평가) | |
2017-12-01 | 평가 | 등재후보로 하락 (계속평가) | |
2013-01-01 | 평가 | 등재 1차 FAIL (등재유지) | |
2010-01-01 | 평가 | 등재학술지 유지 (등재유지) | |
2008-01-01 | 평가 | 등재학술지 유지 (등재유지) | |
2005-01-01 | 평가 | 등재학술지 선정 (등재후보2차) | |
2004-01-01 | 평가 | 등재후보 1차 PASS (등재후보1차) | |
2003-01-01 | 평가 | 등재후보학술지 선정 (신규평가) |
학술지 인용정보
기준연도 | WOS-KCI 통합IF(2년) | KCIF(2년) | KCIF(3년) |
---|---|---|---|
2016 | 0.24 | 0.24 | 0.28 |
KCIF(4년) | KCIF(5년) | 중심성지수(3년) | 즉시성지수 |
0.25 | 0.21 | 0.514 | 0.1 |