Graphene oxide nano-sheets loading with praseodymium cations: Adsorption-desorption study, quantum mechanics calculations and dual active-barrier effect for smart coatings fabrication

다국어 초록 (Multilingual Abstract)

In the current paper, the graphene oxide (GO) nano-sheets were benefited as a promising nano-carrier forPr3+ cations for corrosion inhibition. The optimal experimental condition for Pr3+ cations loading wasobtained. The thermodynamic and kinetic of adsorption process were studied in detail. According to theresults of ICP analysis, the highest adsorption capacity of GO was found in the initial pH of 7, 0.00319 g ofadsorbent dosage, 600 ppm of initial Pr3+ concentration, 30 min contact time and at the temperature of35 C. The loading and desorption efficiency of Pr3+ cations were characterized by series of techniquessuch as UV–vis, XPS, and HR-TEM. Adsorption of Pr3+ cations onto GO was simulated by quantummechanics calculations. Electrochemical analysis showed dual active-barrier protective functioning ofPr3+ loaded GO nano-sheets in the silane matrix. The formation of a protectivefilm was confirmed by theSEM images.

참고문헌 (Reference)

1 A. Atkinson, Springer Science and Business Media LLC 13 (13): 133-139, 1998

2 G. Frankel, 2002

3 B. Hirschorn, 55 (55): 6218-, 2010

4 M. Kasaeian, 145 : 119-, 2018

5 C. Motte, 74 (74): 326-, 2012

6 E. Alibakhshi, 9 (9): 2016

7 Xiangxue Wang, "Synthesis of novel nanomaterials and their application in efficient removal of radionuclides" Springer Science and Business Media LLC 62 (62): 933-967, 2019

8 Krystyna Pyrzynska, "Sorption of Cd(II) onto carbon-based materials—a comparative study" Springer Science and Business Media LLC 169 (169): 7-13, 2010

9 M. L. Zheludkevich, "Sol–gel coatings for corrosion protection of metals" Royal Society of Chemistry (RSC) 15 (15): 5099-, 2005

10 G. Williams, "Smart release corrosion inhibitor pigments based on organic ion-exchange resins" Elsevier BV 57 : 139-147, 2012

11 Eunjoo Koh, "Renewable Polyurethane Microcapsules with Isosorbide Derivatives for Self-Healing Anticorrosion Coatings" American Chemical Society (ACS) 52 (52): 15541-15548, 2013

12 Di Xu, "Removal of Pb(II) from aqueous solution by oxidized multiwalled carbon nanotubes" Elsevier BV 154 (154): 407-416, 2008

13 Han Wang, "Recent progress in covalent organic framework thin films: fabrications, applications and perspectives" Royal Society of Chemistry (RSC) 48 (48): 488-516, 2019

14 Shujun Yu, "Rational design of carbonaceous nanofiber/Ni-Al layered double hydroxide nanocomposites for high-efficiency removal of heavy metals from aqueous solutions" Elsevier BV 242 : 1-11, 2018

15 William S. Hummers, "Preparation of Graphitic Oxide" American Chemical Society (ACS) 80 (80): 1339-1339, 1958

16 E. Alibakhshi, "Persian Liquorice extract as a highly efficient sustainable corrosion inhibitor for mild steel in sodium chloride solution" Elsevier BV 210 : 660-672, 2019

17 R. B. Figueira, "Organic–inorganic hybrid sol–gel coatings for metal corrosion protection: a review of recent progress" Springer Science and Business Media LLC 12 (12): 1-35, 2015

18 E. Alibakhshi, "Optimization of potassium zinc phosphate anticorrosion pigment by Taguchi experimental design" Elsevier BV 76 (76): 224-230, 2013

19 S.V. Lamaka, "Novel hybrid sol–gel coatings for corrosion protection of AZ31B magnesium alloy" Elsevier BV 53 (53): 4773-4783, 2008

20 Chi-Hao Chang, "Novel anticorrosion coatings prepared from polyaniline/graphene composites" Elsevier BV 50 (50): 5044-5051, 2012

21 M.L. Zheludkevich, "Nanostructured sol–gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3" Elsevier BV 51 (51): 208-217, 2005

22 D. G. Shchukin, "Layer-by-Layer Assembled Nanocontainers for Self-Healing Corrosion Protection" Wiley 18 (18): 1672-1678, 2006

23 B.H. Hameed, "Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash" Elsevier BV 133 (133): 195-203, 2007

24 Hakkim Vovusha, "Interaction of Nucleobases and Aromatic Amino Acids with Graphene Oxide and Graphene Flakes" American Chemical Society (ACS) 4 (4): 3710-3718, 2013

25 Ting Xiong, "Insight into highly efficient removal of cadmium and methylene blue by eco-friendly magnesium silicate-hydrothermal carbon composite" Elsevier BV 427 : 1107-1117, 2018

26 G. Williams, "Inhibition of corrosion-driven organic coating disbondment on galvanised steel by smart release group II and Zn(II)-exchanged bentonite pigments" Elsevier BV 55 (55): 1740-1748, 2010

27 Zhen Xu, "In situ Polymerization Approach to Graphene-Reinforced Nylon-6 Composites" American Chemical Society (ACS) 43 (43): 6716-6723, 2010

28 S.H. Sonawane, "Improved active anticorrosion coatings using layer-by-layer assembled ZnO nanocontainers with benzotriazole" Elsevier BV 189-190 : 464-472, 2012

29 Ianina Santana, "Hybrid sol-gel coatings containing clay nanoparticles for corrosion protection of mild steel" Elsevier BV 203 : 396-403, 2016

30 G. Kickelbick, "Hybrid materials: synthesis, characterization, and applications" Wiley - VCH 2007

31 Marco Faustini, "History of Organic-Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications" Wiley 28 (28): 1704158-, 2018

32 Ting Xiong, "Highly efficient removal of diclofenac sodium from medical wastewater by Mg/Al layered double hydroxide-poly(m-phenylenediamine) composite" Elsevier BV 366 : 83-91, 2019

33 Yuri M. Lvov, "Halloysite Clay Nanotubes for Controlled Release of Protective Agents" American Chemical Society (ACS) 2 (2): 814-820, 2008

34 Xiaolu Liu, "Graphene oxide-based materials for efficient removal of heavy metal ions from aqueous solution: A review" Elsevier BV 252 : 62-73, 2019

35 Ali Asghar Javidparvar, "Graphene oxide as a pH-sensitive carrier for targeted delivery of eco-friendly corrosion inhibitors in chloride solution: Experimental and theroretical investigations" 한국공업화학회 72 : 196-213, 2019

36 Jian Zhao, "Graphene in the Aquatic Environment: Adsorption, Dispersion, Toxicity and Transformation" American Chemical Society (ACS) 48 (48): 9995-10009, 2014

37 John P. Perdew, "Generalized Gradient Approximation Made Simple" American Physical Society (APS) 77 (77): 3865-3868, 1996

38 Ashish Kumar Mishra, "Functionalized graphene sheets for arsenic removal and desalination of sea water" Elsevier BV 282 : 39-45, 2011

39 J. J. Hernández Rosas, "First principles calculations of the electronic and chemical properties of graphene, graphane, and graphene oxide" Springer Science and Business Media LLC 17 (17): 1133-1139, 2011

40 Guixia Zhao, "Few-Layered Graphene Oxide Nanosheets As Superior Sorbents for Heavy Metal Ion Pollution Management" American Chemical Society (ACS) 45 (45): 10454-10462, 2011

41 E. Alibakhshi, "Fabrication and characterization of layered double hydroxide/silane nanocomposite coatings for protection of mild steel" Elsevier BV 80 : 924-934, 2017

42 E. Alibakhshi, "Evaluation of the corrosion protection performance of mild steel coated with hybrid sol-gel silane coating in 3.5 wt.% NaCl solution" Elsevier BV 123 : 190-200, 2018

43 F. Andreatta, "Electrochemical behaviour of ZrO2 sol–gel pre-treatments on AA6060 aluminium alloy" Elsevier BV 52 (52): 7545-7555, 2007

44 M. J. Palimi, "Electrochemical Investigations of the Corrosion Protection Properties of an Epoxy-Ester Coating Filled with Cerium Acetyl Acetonate Anticorrosive Pigment" The Electrochemical Society 164 (164): C709-C716, 2017

45 Shujun Yu, "Efficient removal of uranium(VI) by layered double hydroxides supported nanoscale zero-valent iron: A combined experimental and spectroscopic studies" Elsevier BV 365 : 51-59, 2019

46 Bimal P. Singh, "Development of oxidation and corrosion resistance hydrophobic graphene oxide-polymer composite coating on copper" Elsevier BV 232 : 475-481, 2013

47 Mohammad Mahdavian, "Corrosion of mild steel in hydrochloric acid solution in the presence of two cationic gemini surfactants with and without hydroxyl substituted spacers" Elsevier BV 137 : 62-75, 2018

48 E. Alibakhshi, "Corrosion inhibition by lithium zinc phosphate pigment" Elsevier BV 77 : 222-229, 2013

49 Reza Samiee, "Corrosion Inhibition Performance and Healing Ability of a Hybrid Silane Coating in the Presence of Praseodymium (III) Cations" The Electrochemical Society 165 (165): C777-C786, 2018

50 Shujun Yu, "Constructing sphere-like cobalt-molybdenum-nickel ternary hydroxide and calcined ternary oxide nanocomposites for efficient removal of U(VI) from aqueous solutions" Elsevier BV 352 : 360-370, 2018

51 Reza Samiee, "Assessment of the smart self-healing corrosion protection properties of a water-base hybrid organo-silane film combined with non-toxic organic/inorganic environmentally friendly corrosion inhibitors on mild steel" Elsevier BV 220 : 340-356, 2019

52 Hou Wang, "Adsorption characteristics and behaviors of graphene oxide for Zn(II) removal from aqueous solution" Elsevier BV 279 : 432-440, 2013

53 Clemonne J. Madadrang, "Adsorption Behavior of EDTA-Graphene Oxide for Pb (II) Removal" American Chemical Society (ACS) 4 (4): 1186-1193, 2012

54 E. Alibakhshi, "Active corrosion protection of Mg-Al-PO 4 3− LDH nanoparticle in silane primer coated with epoxy on mild steel" Elsevier BV 75 : 248-262, 2017

55 E. Alibakhshi, "Active corrosion protection of Mg-Al-PO 4 3− LDH nanoparticle in silane primer coated with epoxy on mild steel" Elsevier BV 75 : 248-262, 2017

56 Weijun Peng, "A review on heavy metal ions adsorption from water by graphene oxide and its composites" Elsevier BV 230 : 496-504, 2017

57 Seyed A. Dastgheib, "A model for the adsorption of single metal ion solutes in aqueous solution onto activated carbon produced from pecan shells" Elsevier BV 40 (40): 1843-1851, 2002

58 B. Ramezanzadeh, "A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO2-GO); fabrication of SiO2-GO/epoxy composite coating with superior barrier and corrosion protection performance" Elsevier BV 303 : 511-528, 2016

59 Seyyed Arash Haddadi, "A detailed atomic level computational and electrochemical exploration of the Juglans regia green fruit shell extract as a sustainable and highly efficient green corrosion inhibitor for mild steel in 3.5 wt% NaCl solution" Elsevier BV 284 : 682-699, 2019

60 Y. Hayatgheib, "A comparative study on fabrication of a highly effective corrosion protective system based on graphene oxide-polyaniline nanofibers/epoxy composite" Elsevier BV 133 : 358-373, 2018

61 E. Alibakhshi, "A comparative study on corrosion inhibitive effect of nitrate and phosphate intercalated Zn-Al- layered double hydroxides (LDHs) nanocontainers incorporated into a hybrid silane layer and their effect on cathodic delamination of epoxy topcoat" Elsevier BV 115 : 159-174, 2017

62 Mojtaba Kasaeian, "A combined experimental and electronic-structure quantum mechanics approach for studying the kinetics and adsorption characteristics of zinc nitrate hexahydrate corrosion inhibitor on the graphene oxide nanosheets" Elsevier BV 462 : 963-979, 2018