Chemical kinetics of bean straw biofuel pyrolysis using maximum volatile release method

다국어 초록 (Multilingual Abstract)

Maximum volatile release (MVR) methods, including single point (MVR-S) and multiple (MVR-M) points, are proposed to extract the kinetics used to predict the fuel bean straw pyrolysis process. The simulation results were compared to those of the distributed activation energy model (DAEM). For the TGA (thermogravimetric analysis) experiments, fuels were heated from ambient temperature to 1,173 K at the heating rates of 10, 20, 40, 60, 80 K min−1, and the corresponding maximum volatile release points were obtained. For the MVR-S method, both the activation energy (E) and pre-exponential factor (B) increased with increasing heating rates. For the pyrolysis weight loss process, the DAEM showed best agreement with the experimental data, followed by the MVR-M, and then the MVR-S method. However, for weight loss rate prediction, MVR-S method had the best match with the experimental data, whereas the DAEM and MVR-M method generated more errors.

참고문헌 (Reference)

1 G. Gordillo, 34 : 2789-, 2009

2 E. L. K. Mui, 47 : 5710-, 2008

3 D. Chen, 169 : 313-, 2014

4 H. Yang, 85 : 1781-, 2007

5 J. Cai, 42 : 949-, 2006

6 J. Cai, 99 : 2795-, 2008

7 T. Mani, 48 : 1464-, 2009

8 H. Yang, 86 : 1781-, 2007

9 A. Anca-Couce, 123 : 130-, 2014

10 H. Cao, 172 : 219-, 2014

11 M. Jeguirim, 23 : 188-, 2014

12 Y. F. Huang, 110 : 1-, 2013

13 S. A. El-Sayed, 85 : 165-, 2014

14 T. Sonobe, 87 : 414-, 2008

15 K. Q. Tran, 136 : 759-, 2014

16 C. R. Cardoso, 92 : 392-, 2011

17 M. J. Antal, 34 : 703-, 1995

18 L. Sørum, 80 : 1217-, 2001

19 J. Caia, 36 : 236-, 2014

20 A. Soria-Verdugo, 65 : 239-, 2013

21 G. J. Pitt, 41 : 267-, 1962

22 D. B. Anthony, 15 : 1303-, 1974

23 M. Güneş, 30 : 1460-, 2008

24 B. Caprariis, 26 : 6153-, 2012

25 A. Soria-Verdugo, 134 : 360-, 2015

26 K. Kirtania, 107 : 476-, 2012

27 P. Tiwari, 58 : 505-, 2012

28 J. Cai, 132 : 423-, 2013

29 R. L. Braun, 1 : 153-, 1987

30 A. K. Burnham, 108 : 47-, 2005

31 Chaiyot Tangsathitkulchai, "Thermogravimetric analysis of longan seed biomass with a two-parallel reactions model" 한국화학공학회 27 (27): 791-801, 2010

32 Yeon Seok Choi, "Synergetic effect of biomass mixture on pyrolysis kinetics and biocrude-oil characteristics" 한국화학공학회 33 (33): 603-609, 2016

33 B. Martin, "Pyrolysis and ignition of behavior of coal, cattle biomass, and coal/cattle biomass blends" Texas A&M University 2006

34 W. Chen, "Kinetics of Pyrolysis of Mesquite Fuel: Comparison of Different Methods" 2014

35 W. Chen, "Fixed bed counter current low temperature gasification of mesquite and juniper biomass using air-steam as oxidizer" Mechanical Engineering, Texas A&M University, College Station 2012

36 Sasiporn Chayaporn, "Evaluation of biomass component effect on kinetic values for biomass pyrolysis using simplex lattice design" 한국화학공학회 32 (32): 1081-1093, 2015

37 K. Annamalai, "Combustion Science and Engineering" Taylor & Francis Group 2007