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    용매열처리에 따른 PEDOT:PSS 암모니아 가스 감지막 특성 변화 = Effect of Solvent Annealing on the Characteristics of PEDOT:PSS as a Ammonia Gas Sensor Film

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    https://www.riss.kr/link?id=A103660554

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    Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammo- nia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a post annealingprocess for organic devices based on PEDOT:PSS significantly increases the device performance. In this study, we propose the solventannealing of PEDOT:PSS and investigated its effects. As a results, post solvent annealing on PEDOT:PSS lead to the surface chemical and physical properties change. These changes result in improved conductivity of the PEDOT:PSS. In additional, ammonia sensitivityof solvent annealed PEDOT:PSS become higher than pristine polymer film. The enhancement is mainly caused by the depletion of gasbarrier PSS and structural re-forming PEDOT networks. We believe that the post solvent annealing is a promising method to achieve highly sensitivity PEDOT:PSS films for applications in efficient, low-cost and flexible ammonia gas sensor.
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    Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammo- nia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a p...

    Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammo- nia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a post annealingprocess for organic devices based on PEDOT:PSS significantly increases the device performance. In this study, we propose the solventannealing of PEDOT:PSS and investigated its effects. As a results, post solvent annealing on PEDOT:PSS lead to the surface chemical and physical properties change. These changes result in improved conductivity of the PEDOT:PSS. In additional, ammonia sensitivityof solvent annealed PEDOT:PSS become higher than pristine polymer film. The enhancement is mainly caused by the depletion of gasbarrier PSS and structural re-forming PEDOT networks. We believe that the post solvent annealing is a promising method to achieve highly sensitivity PEDOT:PSS films for applications in efficient, low-cost and flexible ammonia gas sensor.

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    참고문헌 (Reference)

    1 계지원, "잉크젯 프린팅 기술을 이용한 플렉서블 온·습도센서 개발" 한국센서학회 24 (24): 119-123, 2015

    2 김진희, "솔벤트 도핑과 후처리 공정에 따른 전도성 고분자 PEDOT : PSS의 특성 변화" 한국공업화학회 26 (26): 275-279, 2015

    3 N. Yamazoe, "Toward innovations of gas sensor technology" 108 : 2-14, 2005

    4 정진욱, "SnO2 나노섬유를 이용한 고신뢰성 후막 가스센서 설계" 한국센서학회 25 (25): 271-274, 2016

    5 U. Lang, "Microscopical Investigations of PEDOT : PSS Thin Films" 19 : 1215-1220, 2009

    6 Y. Seekaew, "Low-cost and flexible printed graphene-PEODT : PSS gas sensor for ammonia detection" 2014

    7 Y. Seekaew, "Low-cost and flexible printed graphene-PEDOT : PSS gas sensor for ammonia detection" 15 : 2971-2981, 2014

    8 M. Vosgueritchian, "Highly Conductive and Transparent PEDOT : PSS Films with a Fluorosurfactant for Stretchable and Flexible Transparent Electrodes" 22 : 421-428, 2012

    9 Y. H. Kim, "Highly Conductive PEDOT : PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells" 21 : 1076-1081, 2011

    10 J. Ouyang, "High-Conductivity Poly(3, 4-Ethylenedioxythiophene) : Poly(styrenesulfonate)Film and Its Application in Polymer Optoelectronic Devices" 2005

    1 계지원, "잉크젯 프린팅 기술을 이용한 플렉서블 온·습도센서 개발" 한국센서학회 24 (24): 119-123, 2015

    2 김진희, "솔벤트 도핑과 후처리 공정에 따른 전도성 고분자 PEDOT : PSS의 특성 변화" 한국공업화학회 26 (26): 275-279, 2015

    3 N. Yamazoe, "Toward innovations of gas sensor technology" 108 : 2-14, 2005

    4 정진욱, "SnO2 나노섬유를 이용한 고신뢰성 후막 가스센서 설계" 한국센서학회 25 (25): 271-274, 2016

    5 U. Lang, "Microscopical Investigations of PEDOT : PSS Thin Films" 19 : 1215-1220, 2009

    6 Y. Seekaew, "Low-cost and flexible printed graphene-PEODT : PSS gas sensor for ammonia detection" 2014

    7 Y. Seekaew, "Low-cost and flexible printed graphene-PEDOT : PSS gas sensor for ammonia detection" 15 : 2971-2981, 2014

    8 M. Vosgueritchian, "Highly Conductive and Transparent PEDOT : PSS Films with a Fluorosurfactant for Stretchable and Flexible Transparent Electrodes" 22 : 421-428, 2012

    9 Y. H. Kim, "Highly Conductive PEDOT : PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells" 21 : 1076-1081, 2011

    10 J. Ouyang, "High-Conductivity Poly(3, 4-Ethylenedioxythiophene) : Poly(styrenesulfonate)Film and Its Application in Polymer Optoelectronic Devices" 2005

    11 R. Pandeeswari, "High sensing response of β-Ga2O3 thin film towards ammonia vapours : Influecing factors at room temperature" 195 : 206-214, 2014

    12 M. W. Ahn, "Gas sensing properties of defect-controlled ZnO-nanowire gas sensor" 93 : 263103-, 2008

    13 G. Wang, "Fabrication and characterization of Polycrystalline Nanofiber WO3 and Their Application for Ammonia Sensing" 110 : 23777-23782, 2006

    14 B. Friedel, "Effects of Layer Thickness and Annealing of PEDOT : PSS Layers in Organic Photodetectors" 42 : 6741-6747, 2009

    15 A. Airoudj, "Development of an optical ammonia sensor based on polyaniline/epoxy resin(SU-8)composite" 77 : 1590-1596, 2009

    16 Y. Chung, "Control of the Surface Composition of a Conducting-Polymer Complex film to Tune the Work Function" 18 : 2246-2252, 2008

    17 C. S. Rout, "Ammonia sensor based on metal oxide nanostructures" 18 : 205504-, 2007

    18 S. Carquigny, "Ammonia gas sensor based on electrosynthesized polypyrrole films" 78 : 199-206, 2009

    19 M. Aslam, "A highly selective ammonia gas sensor using surface-ruthenated zinc oxid" 75 : 162-167, 1999

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