Acrylic polymers such as polyacrylonitrile, poly(acryl-onitrile-co-4-vinyl pyridine), poly(acrylonitrile-co-acrylicacid) were prepared. And then the polymers-cu(Ⅱ)complexes were prepared. We studied on the electrical conductivities of the complexes....
Acrylic polymers such as polyacrylonitrile, poly(acryl-onitrile-co-4-vinyl pyridine), poly(acrylonitrile-co-acrylicacid) were prepared. And then the polymers-cu(Ⅱ)complexes were prepared. We studied on the electrical conductivities of the complexes.
The results were below. The resistivity of PAN-Cu(Ⅱ) complex was about 10⁴Ω-cm, and it had the lowest value at PH 11.
The good Electrical conductivity could be shown when the Iodine amount was above 1 perlent. and cupric chloride amount was above l percent, and cupric chloride amount was above l percent, and cupric chloride amount was above 20 percent.
The electrical conductivities of th PAN-4VP-Cu(Ⅱ) complex and the ANAA-Cu(Ⅱ) complex showed all about 10-5 Ω -¹cm-¹.