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      Promising ZnO-based DSSC performance using HMP molecular dyes of high extinction coefficients

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      https://www.riss.kr/link?id=A107644011

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      <P>Employing newly synthesized di-substituted tri-phenyl amine (HMP-9) and carbazole (HMP-11) dyes (with limited acidic carboxyl anchor groups), a power conversion efficiency as high as 7.03% in ZnO nanocrystallite (NC)-based dye-sensitized solar cells (DSSCs) is achieved. The specific molecular designs of HMP-09 and HMP-11 consisting of with and without hexyloxy spacer groups, and added tri-phenyl amine or 9-phenyl-9<I>H</I>-carbazole donor groups, respectively, attached on the ancillary ligands are advantageous, evidenced from electrochemical impedance spectroscopy measurements, for ZnO NC-based DSSCs.</P>

      <P>Graphic Abstract</P><P>Employing newly synthesized di-substituted tri-phenyl amine (HMP-9) and carbazole (HMP-11) dyes, a power conversion efficiency as high as 7.03% in ZnO nanocrystallite-based dye-sensitized solar cells under AM 1.5 G illumination is achieved.
      <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4dt01179a'>
      </P>
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      <P>Employing newly synthesized di-substituted tri-phenyl amine (HMP-9) and carbazole (HMP-11) dyes (with limited acidic carboxyl anchor groups), a power conversion efficiency as high as 7.03% in ZnO nanocrystallite (NC)-based dye-sensitized sola...

      <P>Employing newly synthesized di-substituted tri-phenyl amine (HMP-9) and carbazole (HMP-11) dyes (with limited acidic carboxyl anchor groups), a power conversion efficiency as high as 7.03% in ZnO nanocrystallite (NC)-based dye-sensitized solar cells (DSSCs) is achieved. The specific molecular designs of HMP-09 and HMP-11 consisting of with and without hexyloxy spacer groups, and added tri-phenyl amine or 9-phenyl-9<I>H</I>-carbazole donor groups, respectively, attached on the ancillary ligands are advantageous, evidenced from electrochemical impedance spectroscopy measurements, for ZnO NC-based DSSCs.</P>

      <P>Graphic Abstract</P><P>Employing newly synthesized di-substituted tri-phenyl amine (HMP-9) and carbazole (HMP-11) dyes, a power conversion efficiency as high as 7.03% in ZnO nanocrystallite-based dye-sensitized solar cells under AM 1.5 G illumination is achieved.
      <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4dt01179a'>
      </P>

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