Thermal Sensitive Polyurethane Membranes with Desirable Switch Temperatures

다국어 초록 (Multilingual Abstract)

Chemical synthesis and physical blending methods were used to prepare thermal sensitive polyurethanes (TSPU) with single or double thermal switches. In the design of the formula, polycaprolactone diol (PCL) with a molecular weight 10,000 and 4,000 and polytetramethylene glycol (PTMG) with a molecular weight 3,000 and 2,000 were used as the soft segments. The effects of the crystallinity and compatibility of the soft segments on the phase transition temperatures of the soft segments of TSPU (defined as switch temperature, Ts) were investigated in detail. To examine the thermal sensitivity of the thermal switch, water vapor permeability (WVP) experiments were performed to investigate the mass transport as a function of temperature. Differential scanning calorimetry (DSC)indicated that all the original TSPUs had a phase separated structure that was independent of the phase transition temperature of the soft and hard segments. The Ts values are determined mostly by the melting temperatures of the soft segments. On the other hand, for their blends, the Ts values are determined by the compatibility of the soft segments and the blending weight ratio. The blends of the PCL-based TSPUs showed good compatibility and single Ts due to the similar structure of the soft segments (just a difference in molecular weight), whereas for the PCL-based and PTMG-based TSPUs (the molecular structure is very different) blends, the Ts two independent values and blending weight ratio-dependent features due to the difference in the structure of the soft segments. Water vapor permeability analysis revealed the mass transport showed switching features to thermal stimuli, i.e. when the temperature reached the Ts, the WVPs of membranes showed rapid changes. On the other hand, the sensitivity of the thermal switch characterized by WVP improvement showed a dependence on the degree of crystallinity of the soft segments,i.e. well-organized soft segment structure is beneficial for improving the thermal sensitivity. Overall, TSPU membranes with a single Ts and different thermal sensitivity can be prepared using different crystalline poly-diols as the soft segments and blending two types of TSPUs with similar soft segments in the molecule structure, whereas TSPU with a double Ts can be achieved easily by blending two types of TSPUs with different soft segments.

참고문헌 (Reference)

1 H. M. Jeong, 35 : 279-, 2000

2 Y. C. Jean, 33 : 2365-, 1995

3 X. M. Ding, 74 : 39-, 2004

4 H. M. Jeong, 38 : 3009-, 2000

5 Y. C. Jean, 33 : 2365-, 1995

6 W. Y. Jeong, 36 : 4797-, 2001

7 S. Hayashi, 51 : 29-, 1995

8 S. Hayashi, 23 : 74-, 1993

9 C. P. Chwang, 86 : 2002-, 2002

10 H. J. Fan, 89 : 121-, 2005

11 Y. Chen, 287 : 192-, 2007

12 A. S. Mohammad, 17 : 431-, 2008

13 A. S. Mohammad, 16 : 819-, 2007

14 C. Hepburn, 1 : 84-, 1992

15 S. Mondal, 67 : 282-, 2007

16 T. Takahashi, 60 : 1061-, 1996

17 H. Zhou, 109 : 3002-, 2008

18 H. Zhou, 318 : 71-, 2008

19 Z. F. Wang, 88 : 212-, 2004

20 M. Z. Khalid, 44 : 18-, 2009

21 S. Mondal, 280 : 427-, 2006

22 HyungTakLee, "Thermoresponsive Phase Transitions of PLA-block-PEO-block-PLA Triblock Stereo-Copolymers in Aqueous Solution" 한국고분자학회 10 (10): 359-364, 2002

23 Soo-Young Park, "Thermal Transitions of the Drawn Film of a Nylon 6/Layered Silicate Nanocomposite" 한국고분자학회 13 (13): 156-161, 2005

24 R. J. Young, "Introduction to Polymers" Chapman& Hall 12-, 1991

25 SeongGeunKim, "Effect of Polymerization Procedure on Thermal and Mechanical Properties of Polyether Based Thermoplastic Polyurethanes [Communications]" 한국고분자학회 10 (10): 365-368, 2002