<P><B>Abstract</B></P> <P>To realize graphene-encapsulated semiconductor nanocrystals (NCs), an additional graphene coating process, which causes shape destruction and chemical contamination, has so far been inevitable. ...
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https://www.riss.kr/link?id=A107459270
2018
-
SCOPUS,SCIE
학술저널
553-559(7쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>To realize graphene-encapsulated semiconductor nanocrystals (NCs), an additional graphene coating process, which causes shape destruction and chemical contamination, has so far been inevitable. ...
<P><B>Abstract</B></P> <P>To realize graphene-encapsulated semiconductor nanocrystals (NCs), an additional graphene coating process, which causes shape destruction and chemical contamination, has so far been inevitable. We report herein one-pot growth of uniform graphene-germanium core–shell nanocrystals (Ge@G NCs) in gram scale by the addition of methane as a carbon source during the thermal pyrolysis of germane. The methane plays a critical role in the growth of the graphene shell, as well as in the determination of the nucleation density and diameter of the NCs, similar to a surfactant in the liquid-phase growth of monodisperse NCs. By adjusting the gas ratio of precursors, a mixture of germane and methane, we can control the size of the Ge@G NCs in the range of ∼5–180 nm. The Ge@G NCs were characterized by various microscopic and spectroscopic tools, which indicated that the Ge core is single crystalline, and is completely covered by the graphene shell. We further investigated the merits of the graphene shell, which can enhance the electrical conductivity of nanocrystalline materials.</P> <P><B>Highlights</B></P> <P> <UL> <LI> The Ge-graphene core-shell nanocrystals (Ge@G NCs) are synthesized in gram scale. </LI> <LI> The role of CH<SUB>4</SUB> is critical for determination of the density and diameter of the NCs. </LI> <LI> The size of the Ge@G NCs can be controlled by tuning the gas ratio of GeH<SUB>4</SUB> and CH<SUB>4</SUB>. </LI> <LI> The graphene shell enhances the electrical conductivity of NCs. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
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