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      ALD ZnO 버퍼층 증착 온도가 전착 Cu2O 박막 태양전지 소자 특성에 미치는 영향 = The Influence of Deposition Temperature of ALD n-type Buffer ZnO Layer on Device Characteristics of Electrodeposited Cu2O Thin Film Solar Cells

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      https://www.riss.kr/link?id=A105934744

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      Beside several advantages, the PV power generation as a clean energy source, is still below the supply level due to high power generation cost. Therefore, the interest in fabricating low-cost thin film solar cells is increasing continuously. Cu2O, a low cost photovoltaic material, has a wide direct band gap of ~2.1 eV has along with the high theoretical energy conversion efficiency of about 20%. On the other hand, it has other benefits such as earth-abundance, low cost, non-toxic, high carrier mobility (100 cm2/Vs). In spite of these various advantages, the efficiency of Cu2O based solar cells is still significantly lower than the theoretical limit as reported in several literatures. One of the reasons behind the low efficiency of Cu2O solar cells can be the formation of CuO layer due to atmospheric surface oxidation of Cu2O absorber layer. In this work, atomic layer deposition method was used to remove the CuO layer that formed on Cu2O surface. First, Cu2O absorber layer was deposited by electrodeposition. On top of it buffer (ZnO) and TCO (AZO) layers were deposited by atomic layer deposition and rf-magnetron sputtering respectively. We fabricated the cells with a change in the deposition temperature of buffer layer ranging between 80°C to 140°C. Finally, we compared the performance of fabricated solar cells, and studied the influence of buffer layer deposition temperature on Cu2O based solar cells by J-V and XPS measurements.
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      Beside several advantages, the PV power generation as a clean energy source, is still below the supply level due to high power generation cost. Therefore, the interest in fabricating low-cost thin film solar cells is increasing continuously. Cu2O, a l...

      Beside several advantages, the PV power generation as a clean energy source, is still below the supply level due to high power generation cost. Therefore, the interest in fabricating low-cost thin film solar cells is increasing continuously. Cu2O, a low cost photovoltaic material, has a wide direct band gap of ~2.1 eV has along with the high theoretical energy conversion efficiency of about 20%. On the other hand, it has other benefits such as earth-abundance, low cost, non-toxic, high carrier mobility (100 cm2/Vs). In spite of these various advantages, the efficiency of Cu2O based solar cells is still significantly lower than the theoretical limit as reported in several literatures. One of the reasons behind the low efficiency of Cu2O solar cells can be the formation of CuO layer due to atmospheric surface oxidation of Cu2O absorber layer. In this work, atomic layer deposition method was used to remove the CuO layer that formed on Cu2O surface. First, Cu2O absorber layer was deposited by electrodeposition. On top of it buffer (ZnO) and TCO (AZO) layers were deposited by atomic layer deposition and rf-magnetron sputtering respectively. We fabricated the cells with a change in the deposition temperature of buffer layer ranging between 80°C to 140°C. Finally, we compared the performance of fabricated solar cells, and studied the influence of buffer layer deposition temperature on Cu2O based solar cells by J-V and XPS measurements.

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      참고문헌 (Reference)

      1 Y. S. Lee, "Ultrathin amorphous zinc-tin-oxide buffer layer for enhancing heterojunction interface quality in metal-oxide solar cells" 6 (6): 2112-2118, 2013

      2 B. G. Mendis, "The role of secondary phase precipitation on grain boundary electrical activity in Cu2ZnSnS4(CZTS)photovoltaic absorber layer material" 112 (112): 124508-, 2012

      3 Y. Nishi, "The impact of heterojunction formation temperature on obtainable conversion efficiency in n-ZnO/p-Cu2O solar cells" 528 : 72-76, 2013

      4 T. K. Galeev, "Surface-properties of platinum and palladium" 14 (14): 61-65, 1980

      5 K. Mizuno, "Structural and electrical characterizations of electrodeposited p-Type semiconductor Cu2O films" 152 (152): C179-C182, 2005

      6 R. Baños, "Optimization methods applied to renewable and sustainable energy : a review" 15 (15): 1753-1766, 2011

      7 S. Bijani, "Low-temperature electrodeposition of Cu2O thin films : modulation of micro-nanostructure by modifying the applied potential and electrolytic bath pH" 113 : 19482-19487, 2009

      8 Y. Ievskaya, "Improved heterojunction quality in Cu2O-based solar cells through the optimization of atmospheric pressure spatial atomic layer deposited Zn1-xMgxO" 113 : e53501-, 2016

      9 S. W. Lee, "Improved Cu2O-based solar cells using atomic layer deposition to control the Cu oxidation state at the p-n junction" 4 : 1301916-, 2014

      10 T. Minami, "High-efficiency oxide solar cells with ZnO/Cu2O heterojunction fabricated on thermally oxidized Cu2O sheets" 4 (4): 62301-, 2011

      1 Y. S. Lee, "Ultrathin amorphous zinc-tin-oxide buffer layer for enhancing heterojunction interface quality in metal-oxide solar cells" 6 (6): 2112-2118, 2013

      2 B. G. Mendis, "The role of secondary phase precipitation on grain boundary electrical activity in Cu2ZnSnS4(CZTS)photovoltaic absorber layer material" 112 (112): 124508-, 2012

      3 Y. Nishi, "The impact of heterojunction formation temperature on obtainable conversion efficiency in n-ZnO/p-Cu2O solar cells" 528 : 72-76, 2013

      4 T. K. Galeev, "Surface-properties of platinum and palladium" 14 (14): 61-65, 1980

      5 K. Mizuno, "Structural and electrical characterizations of electrodeposited p-Type semiconductor Cu2O films" 152 (152): C179-C182, 2005

      6 R. Baños, "Optimization methods applied to renewable and sustainable energy : a review" 15 (15): 1753-1766, 2011

      7 S. Bijani, "Low-temperature electrodeposition of Cu2O thin films : modulation of micro-nanostructure by modifying the applied potential and electrolytic bath pH" 113 : 19482-19487, 2009

      8 Y. Ievskaya, "Improved heterojunction quality in Cu2O-based solar cells through the optimization of atmospheric pressure spatial atomic layer deposited Zn1-xMgxO" 113 : e53501-, 2016

      9 S. W. Lee, "Improved Cu2O-based solar cells using atomic layer deposition to control the Cu oxidation state at the p-n junction" 4 : 1301916-, 2014

      10 T. Minami, "High-efficiency oxide solar cells with ZnO/Cu2O heterojunction fabricated on thermally oxidized Cu2O sheets" 4 (4): 62301-, 2011

      11 T. Minami, "Heterojunction solar cell with 6% efficiency based on an n-type aluminum-gallium-oxide thin film and p-type sodium-doped Cu2O sheet" 8 (8): 22301-, 2015

      12 A. Mittiga, "Heterojunction solar cell with 2% efficiency based on a Cu2O substrate" 88 : 163502-, 2006

      13 M. Hosenuzzaman, "Global prospects, progress, policies, and environmental impact of solar photovoltaic power generation" 41 : 284-297, 2015

      14 Y. Ievskaya, "Fabrication of ZnO/Cu2O heterojunctions in atmospheric conditions : Improved interface quality and solar cell performance" 135 : 43-48, 2015

      15 M. Abdelfatah, "Fabrication and characterization of low cost Cu2O/ZnO : Al solar cells for sustainable photovoltaics with earth abundant materials" 145 : 454-461, 2016

      16 M. Tadatsugu, "Efficiency enhancement using a Zn1−xGex-O thin film as an n-type window layer in Cu2O-based heterojunction solar cells" 9 (9): 52301-, 2016

      17 W. Wang, "Device characteristics of CZTSSe thin-film solar cells with 12. 6% efficiency" 4 (4): 1301465-, 2014

      18 Q. Guo, "Development of CulnSe2 nanocrystal and nanoring inks for low-cost solar cells" 8 (8): 2982-2987, 2008

      19 T. K. S. Wong, "Current status and future prospects of copper oxide heterojunction solar cells" 9 (9): 271-, 2016

      20 Y. S. Lee, "Atomic layer deposited gallium oxide buffer layer enables 1. 2 V open-circuit voltage in cuprous oxide solar cells" 26 (26): 4704-4710, 2014

      21 R. Munter, "Advanced oxidation processes-current status and prospect" 50 (50): 59-80, 2001

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