Site Preference and Hyperfine Structure in Doped Z-Type Hexaferrite Ba_1.5Sr_1.5Co₂(Fe_{1&#x2013;<i>x</i>}Al_<i>x</i>)₂₄O₄₁ Investigated by M&ouml;ssbauer Spectroscopy

다국어 초록 (Multilingual Abstract)

<P>The Ba1.5Sr1.5Co2(Fe1-xAlx)(24)O-41 (x = 0, 0.01, 0.03, and 0.05) polycrystalline samples were synthesized by the polymerizable complex method. Based on the Rietveld refinement, the crystal structures of samples were found to be single phased and determined to be rhombohedral with space group of P-63/mmc. The hysteresis curves of these samples were measured under 20 kOe at 295 K, showing that they were not saturated with increasing Al ion contents because spin structure was modified due to the reduction of magnetic anisotropy. With increasing Al ions contents, the value of M20kOe decreases due to the preferential occupation of non-magnetic Al ions in the up-spin site, while Hc increases. The Mossbauer spectra of the samples were obtained at 295 K, and analyzed as six distinguishable sextets (4f(IV), 4f(IV)*, 12k(V I)*, 4f(V I)* + 4e(IV), 12k(V I), and 2d(V) + 2a(V I) + 4f(V I) + 4e(V I)) below T-C due to the superposition of ten sextets of Fe sites corresponding to the Z-type hexagonal ferrite. The occupation number of up-spin site decreases with increasing Al ions. This suggests that the Al ions preferentially occupy the tetrahedral sublattices, leading to decrease in M-20kOe.</P>