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      KCI등재 SCOPUS

      H₂/Air 비예혼합화염의 화염신장율에 따른 NO 생성경로의 상세해석

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      https://www.riss.kr/link?id=A76349563

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      다국어 초록 (Multilingual Abstract)

      Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and N₂O route. Strain rate were varied to discuss the EINO reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result , as the strain rate increase, EINO decrease sharply until strain rate 100s<SUP>-1</SUP> and decrease slowly until strain rate 310s<SUP>-1</SUP> again, after that EINO keeps nearly constant. It can be identified that EINO trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and N₂O route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. . As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and N₂O route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.
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      Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature...

      Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and N₂O route. Strain rate were varied to discuss the EINO reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result , as the strain rate increase, EINO decrease sharply until strain rate 100s<SUP>-1</SUP> and decrease slowly until strain rate 310s<SUP>-1</SUP> again, after that EINO keeps nearly constant. It can be identified that EINO trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and N₂O route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. . As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and N₂O route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.

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      목차 (Table of Contents)

      • Abstract
      • 1. 서론
      • 2. 수치해석 방법
      • 3. 결과 및 검토
      • 4. 결론
      • Abstract
      • 1. 서론
      • 2. 수치해석 방법
      • 3. 결과 및 검토
      • 4. 결론
      • 후기
      • 참고문헌
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      참고문헌 (Reference)

      1 Tien, C. L, "Thermal Radiation Properties of Gases" 5 : 253-320, 1968

      2 Lee, C. E, "The Effect of Turbulence Intensity of Ambient Air Flow on NOx Emissions in H2/air Nonpremixed Jet Flames" 2007

      3 Konnov, A. A, "Temperature-dependent Rate Constant for the Reaction NNH+O→NH+" 125 : 1258-1264, 2001

      4 Peters, N, "Structure and Similarity of Nitric Oxide Production in Turbulent Diffusion Flames" 33-42, 1981

      5 Takeno, T, "Species Conservation and Emission Indices for Flames Described by Similarity Solutions" 92 : 448-465, 1993

      6 Drake, M. C, "Relative Importance of Nitric Oxide Formation Mechanisms in Laminar Opposed-flow Diffusion Flames" 83 : 185-203, 1991

      7 Ju, Y, "On the Extinction Limit and Flammability Limit of Non-adiabatic Stretched Methane-Air Premixed Flames" 342 : 315-334, 1997

      8 Lutz, A. E, "OPPDIF: A Fortran Program for Computing Opposed-Flow Diffusion Flames" 1994

      9 Bozzelli, J. W, "O+NNH : a Possible New Route for NOx Formation in Flames" 27 : 1097-1099, 1995

      10 Chen, R. H, "Nitric Oxide Levels of Jet Diffusion Flames : Effects of Coaxial Air and Other Mixing Parameters" 281-288, 1990

      1 Tien, C. L, "Thermal Radiation Properties of Gases" 5 : 253-320, 1968

      2 Lee, C. E, "The Effect of Turbulence Intensity of Ambient Air Flow on NOx Emissions in H2/air Nonpremixed Jet Flames" 2007

      3 Konnov, A. A, "Temperature-dependent Rate Constant for the Reaction NNH+O→NH+" 125 : 1258-1264, 2001

      4 Peters, N, "Structure and Similarity of Nitric Oxide Production in Turbulent Diffusion Flames" 33-42, 1981

      5 Takeno, T, "Species Conservation and Emission Indices for Flames Described by Similarity Solutions" 92 : 448-465, 1993

      6 Drake, M. C, "Relative Importance of Nitric Oxide Formation Mechanisms in Laminar Opposed-flow Diffusion Flames" 83 : 185-203, 1991

      7 Ju, Y, "On the Extinction Limit and Flammability Limit of Non-adiabatic Stretched Methane-Air Premixed Flames" 342 : 315-334, 1997

      8 Lutz, A. E, "OPPDIF: A Fortran Program for Computing Opposed-Flow Diffusion Flames" 1994

      9 Bozzelli, J. W, "O+NNH : a Possible New Route for NOx Formation in Flames" 27 : 1097-1099, 1995

      10 Chen, R. H, "Nitric Oxide Levels of Jet Diffusion Flames : Effects of Coaxial Air and Other Mixing Parameters" 281-288, 1990

      11 Turanyi, T, "Kinalc Homepage"

      12 Glaborg, P, "Kenitic Modeling of Hydrocarbon/nitric Oxide Interactions in a Flow Reactor" 115 : 1-27, 1998

      13 Rortveit, G, J, "Effects of Diluents on NOx Formation in Hydrogen Counterflow Flames" 130 : 48-61, 2002

      14 Kee, R. J, "Chemkin-Ⅱ: A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics" 1989

      15 Li, J, "An Updated Comprehensive Kinetic Model of Hydrogen" 36 : 566-575, 2004

      16 Haworth, N. L, "An Ab Initio Quantum Chemical and Kinetic Study of the NNH+O Reaction Potential Energy Surface: How Important is This Route to NO in Combustion?" 107 : 6792-6803, 2003

      17 Martin, S, "A study of NOx Formation in Hydrogen Flames" 32 : 3572-3585, 2007

      18 Lutz, R. J, "A Fortran Program for Computing Opposed-Flow Diffusion Flames" SAND 1994

      19 Kee, R. J, "A Fortran Computer Code Package for the Evaluation of Gas-Phase Multi-Component Transport" 1994

      20 Kee, R. J, "A Computational Model of the Structure and Extinction of Strained, Opposed Flow, Premixed Methane-Air Flame" 22 : 1479-1494, 1988

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      학술지 이력

      학술지 이력
      연월일 이력구분 이력상세 등재구분
      2023 평가예정 해외DB학술지평가 신청대상 (해외등재 학술지 평가)
      2020-01-01 평가 등재학술지 유지 (해외등재 학술지 평가) KCI등재
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      2008-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2006-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2004-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2001-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      1998-07-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.23 0.23 0.25
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.22 0.19 0.552 0.03
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