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      수적(垂滴)법을 이용한 이산화탄소 지중저장 조건에서의 염수-이산화탄소 간 계면장력 측정 = Measuring Interfacial Tension between Brine and Carbon Dioxide in Geological CO<sub>2</sub> Sequestration Conditions using Pendant Bubble Methods

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      https://www.riss.kr/link?id=A103028732

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      다국어 초록 (Multilingual Abstract)

      This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.
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      This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions...

      This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.

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      참고문헌 (Reference)

      1 Chiquet, P., "Wettability alteration of caprock minerals by carbon dioxide" 7 : 112-122, 2007

      2 Shah, V., "Water/acid gas interfacial tensions and their impact on acid gas geological storage" 2 : 594-604, 2008

      3 Esponoza, D.N., "Water-CO2-mineral systems: Interfacial tension, contact angle, and diffusion-Implications to CO2 geological storage" 46 : W07537-, 2010

      4 Arashiro, E.A., "Use of the pendant drop method to measure interfacial tension between molten polymers" 2 (2): 23-32, 1999

      5 Wiebe, R., "The binary system carbon dioxide-water under pressure" 29 : 475-489, 1941

      6 Akiba, H., "Surface tension between CO2gas and tetra-n-butylammonium bromide aqueous solution" 92 : 72-75, 2016

      7 Grigull, U., "Properties of Water and Steam in Si-Units" Springer-Verlag 190-, 1979

      8 Macleod, D.B., "On a relation between surface tension and density" 19 : 38-41, 1923

      9 Li, X., "Interfacial tension of (Brines + CO2): (0.864 NaCl + 0.136 KCl) at temperatures between (298 and 448) K, pressures between (2and 50) MPa, and total molalities of (1 to 5) mol·kg−1" 57 (57): 1078-1088, 2012

      10 Aggelopoulos, C.A., "Interfacial tension between CO2 and brine (NaCl + CaCl2) at elevated pressures and temperatures: The additive effect of different salts" 34 : 505-511, 2011

      1 Chiquet, P., "Wettability alteration of caprock minerals by carbon dioxide" 7 : 112-122, 2007

      2 Shah, V., "Water/acid gas interfacial tensions and their impact on acid gas geological storage" 2 : 594-604, 2008

      3 Esponoza, D.N., "Water-CO2-mineral systems: Interfacial tension, contact angle, and diffusion-Implications to CO2 geological storage" 46 : W07537-, 2010

      4 Arashiro, E.A., "Use of the pendant drop method to measure interfacial tension between molten polymers" 2 (2): 23-32, 1999

      5 Wiebe, R., "The binary system carbon dioxide-water under pressure" 29 : 475-489, 1941

      6 Akiba, H., "Surface tension between CO2gas and tetra-n-butylammonium bromide aqueous solution" 92 : 72-75, 2016

      7 Grigull, U., "Properties of Water and Steam in Si-Units" Springer-Verlag 190-, 1979

      8 Macleod, D.B., "On a relation between surface tension and density" 19 : 38-41, 1923

      9 Li, X., "Interfacial tension of (Brines + CO2): (0.864 NaCl + 0.136 KCl) at temperatures between (298 and 448) K, pressures between (2and 50) MPa, and total molalities of (1 to 5) mol·kg−1" 57 (57): 1078-1088, 2012

      10 Aggelopoulos, C.A., "Interfacial tension between CO2 and brine (NaCl + CaCl2) at elevated pressures and temperatures: The additive effect of different salts" 34 : 505-511, 2011

      11 Yang, D., "Interfacial interactions between reservoir brine and CO2 at high pressure and elevated temperature" 19 : 216-223, 2005

      12 Song, Y., "Geothermal development in Korea: Country Update 2005-2009" 241-, 2010

      13 Misak, M.D., "Equations for determining 1/H versus S values in computer calculations of interfacial tension by the pendent drop method" 27 (27): 141-142, 1968

      14 Bachu and Bennion, "Dependence of CO2-brine interfacial tension on aquifer pressure, temperature and water salinity" 1 (1): 3157-3164, 2009

      15 IPCC (Intergovernmental Panel on Climate Change), "Carbon dioxide capture and storage" Cambridge University Press 431-, 2005

      16 Aggelopoulos, C.A., "CO2/CaCl2 solution interfacial tensions under CO2 geological storage conditions: influence of cation valence on interfacial tension" 33 : 691-697, 2010

      17 Chalbaud, C., "Brine/CO2 interfacial properties and effects on CO2 storage in deep saline aquifers" 65 (65): 541-555, 2010

      18 Andreas, J.M., "Boundary tension by pendant drops" 42 : 1001-1019, 1938

      19 Duana, Z., "An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar" 193 : 257-271, 2003

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      학술지 이력

      학술지 이력
      연월일 이력구분 이력상세 등재구분
      2026 평가예정 재인증평가 신청대상 (재인증)
      2020-01-01 평가 등재학술지 유지 (재인증) KCI등재
      2017-01-01 평가 등재학술지 유지 (계속평가) KCI등재
      2013-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2010-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2008-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2006-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2003-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      2002-01-01 평가 등재후보 1차 PASS (등재후보1차) KCI등재후보
      2000-07-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      학술지 인용정보
      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.3 0.3 0.35
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.35 0.36 0.568 0.05
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