As an application of wavepacket dynamics in multichannel systems, the time evolution of the nonadiabatically coupled 1,2,3 ?? staes of Al are considered. The metastable 2,3 ?? states can radiationlessly decay to the dissociative 1?? state. The wavepac...
As an application of wavepacket dynamics in multichannel systems, the time evolution of the nonadiabatically coupled 1,2,3 ?? staes of Al are considered. The metastable 2,3 ?? states can radiationlessly decay to the dissociative 1?? state. The wavepacket of resonance (metastable state) will split into two parts, one oscillating and the other moving out. The time evolution of resonances is observed.