The synthesis and characterization of a number of oxomolybdenum(V),(Ⅳ) complexes with N-Salicylidene-2-aminophenol(SapH2) as the ONO donor metal-binding substrates are described. The Mo(V) compelxes of the type [MoO(X-sap)(Quin-O)] (X=H,3-CH3O,5,6-B...
The synthesis and characterization of a number of oxomolybdenum(V),(Ⅳ) complexes with N-Salicylidene-2-aminophenol(SapH2) as the ONO donor metal-binding substrates are described. The Mo(V) compelxes of the type [MoO(X-sap)(Quin-O)] (X=H,3-CH3O,5,6-Bz and Quin-O = 8-hydroxyquinolinate) are derived from the [MoOCl(X-sap) (MeOH)] by Cl and MeOH substitution with Quin-OH.The Mo(Ⅳ)complexes [MoO2(Sap) (D)] are obtained by treatment of (PyH)[MoOCl2(X-sap)] or [MoOCl(X-sap) (MeOH)] with each of pyridine(Py),r-picoline(r-Pic),dimethylsulfoxide(DMSO),and dimethylformamide(DMf) as neutral monodentates(D) .The complexes are formulated on the basis of elemental analysis, i. r. , n. m. r. , uv/vis. ,and mass spestroscopy.