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      Vertically aligned cupric oxide nanorods for nitrogen monoxide gas detection

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      https://www.riss.kr/link?id=A108731684

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      Utilizing low-dimensional structures of oxide semiconductors is a promising approach to fabricate relevant gas sensors by means of potential enhancement in surface-to-volume ratios of their sensing materials. In this work, vertically aligned cupric oxide (CuO) nanorods are successfully synthesized on a transparent glass substrate via seed-mediated hydrothermal synthesis method with the use of a CuO nanoparticle seed layer, which is formed by thermally oxidizing a sputtered Cu metal film. Structural and optical characterization by x-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy reveals the successful preparation of the CuO nanorods array of the single monoclinic tenorite crystalline phase. From gas sensing measurements for the nitrogen monoxide (NO) gas, the vertically aligned CuO nanorod array is observed to have a highly responsive sensitivity to NO gas at relatively low concentrations and operating temperatures, especially showing a high maximum sensitivity to NO at 200 ℃ and a low NO detection limit of 2 ppm in dry air. These results along with a facile fabrication process demonstrate that the CuO nanorods synthesized on a transparent glass substrate are very promising for low-cost and high-performance NO gas sensors.
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      Utilizing low-dimensional structures of oxide semiconductors is a promising approach to fabricate relevant gas sensors by means of potential enhancement in surface-to-volume ratios of their sensing materials. In this work, vertically aligned cupric ox...

      Utilizing low-dimensional structures of oxide semiconductors is a promising approach to fabricate relevant gas sensors by means of potential enhancement in surface-to-volume ratios of their sensing materials. In this work, vertically aligned cupric oxide (CuO) nanorods are successfully synthesized on a transparent glass substrate via seed-mediated hydrothermal synthesis method with the use of a CuO nanoparticle seed layer, which is formed by thermally oxidizing a sputtered Cu metal film. Structural and optical characterization by x-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy reveals the successful preparation of the CuO nanorods array of the single monoclinic tenorite crystalline phase. From gas sensing measurements for the nitrogen monoxide (NO) gas, the vertically aligned CuO nanorod array is observed to have a highly responsive sensitivity to NO gas at relatively low concentrations and operating temperatures, especially showing a high maximum sensitivity to NO at 200 ℃ and a low NO detection limit of 2 ppm in dry air. These results along with a facile fabrication process demonstrate that the CuO nanorods synthesized on a transparent glass substrate are very promising for low-cost and high-performance NO gas sensors.

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      참고문헌 (Reference)

      1 박종현 ; 김효진, "수직으로 정렬된 산화아연 나노막대 광전극의 광전기화학적 특성" 한국표면공학회 51 (51): 237-242, 2018

      2 R. W. J. Scott, "Tin dioxide opals and inverted opals : Nearideal microstructures for gas sensors" 13 : 1468-1472, 2001

      3 T. Gao, "Synthesis and properties of multipod-shaped ZnO nanorods for gas-sensor application" 80 : 1451-1454, 2005

      4 박종현 ; 김효진, "Synthesis and Characterization of Zinc Oxide Nanorods for Nitrogen Dioxide Gas Detection" 한국표면공학회 54 (54): 260-266, 2021

      5 C. Wang, "Surface accumulation conduction controlled sensing characteristic of p-type CuO nanorods induced by oxygen adsorption" 18 : 145506-, 2007

      6 N. S. Ramgir, "Sub-ppm H2S sensing at room temperature using CuO thin films" 151 : 90-96, 2010

      7 H. F. Goldstein, "Raman study of CuO single crystals" 41 : 7192-7194, 1990

      8 Y. Xia, "Onedimensional nanostructures: synthesis, characterization, and applications" 15 : 353-389, 2003

      9 Y. Li, "Gas sensing properties of p-type semiconducting Cr-doped TiO2 thin films" 83 : 160-163, 2002

      10 C. Yang, "Gas sensing properties of CuO nanorods synthesized by a microwave-assisted hydrothermal method" 158 : 299-303, 2011

      1 박종현 ; 김효진, "수직으로 정렬된 산화아연 나노막대 광전극의 광전기화학적 특성" 한국표면공학회 51 (51): 237-242, 2018

      2 R. W. J. Scott, "Tin dioxide opals and inverted opals : Nearideal microstructures for gas sensors" 13 : 1468-1472, 2001

      3 T. Gao, "Synthesis and properties of multipod-shaped ZnO nanorods for gas-sensor application" 80 : 1451-1454, 2005

      4 박종현 ; 김효진, "Synthesis and Characterization of Zinc Oxide Nanorods for Nitrogen Dioxide Gas Detection" 한국표면공학회 54 (54): 260-266, 2021

      5 C. Wang, "Surface accumulation conduction controlled sensing characteristic of p-type CuO nanorods induced by oxygen adsorption" 18 : 145506-, 2007

      6 N. S. Ramgir, "Sub-ppm H2S sensing at room temperature using CuO thin films" 151 : 90-96, 2010

      7 H. F. Goldstein, "Raman study of CuO single crystals" 41 : 7192-7194, 1990

      8 Y. Xia, "Onedimensional nanostructures: synthesis, characterization, and applications" 15 : 353-389, 2003

      9 Y. Li, "Gas sensing properties of p-type semiconducting Cr-doped TiO2 thin films" 83 : 160-163, 2002

      10 C. Yang, "Gas sensing properties of CuO nanorods synthesized by a microwave-assisted hydrothermal method" 158 : 299-303, 2011

      11 Y. Min, "Gas response of reactively sputtered ZnO films on Sibased micro-array" 93 : 435-441, 2003

      12 N. L. Hung, "Enhancement of CO gas sensing properties in ZnO thin films deposited on self-assembled Au nanodots" 151 : 127-132, 2010

      13 C. A. Grimes, "Encyclopedia of Sensors" American Scientific Publishers 2006

      14 Y. Ushio, "Effects of interface states on gas-sensing properties of a CuO/ZnO thin-film heterojunction" 17 : 221-226, 1994

      15 D. Sauter, "Development of modular ozone system for application in practical use" 83 : 1-9, 2000

      16 박종현 ; 김효진, "Cupric oxide thin film as an efficient photocathode for photoelectrochemical water reduction" 한국표면공학회 55 (55): 63-69, 2022

      17 R. Poreddy, "Copper oxide as efficient catalyst for oxidative dyhydrogenation of alcohols with air" 5 : 2467-2477, 2015

      18 P. Sinsermsuksakui, "Atomic layer deposition of tin monosulfide thin films" 1 : 1116-1125, 2011

      19 D. S. Murali, "A. Subrahmanyam, Synthesis of Cu2O from CuO thin films" 5 : 047143-, 2015

      20 T. Seiyama, "A new detector for gaseous components using semiconductive thin films" 34 : 1502-1503, 1962

      21 S. C. Naisbitt, "A microstructural model of semiconducting sensor response : The effects of sintering temperature on the response of chromium titanate(CTO)to carbon monoxide" 114 : 969-977, 2006

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