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      중국 젠지고우 연-아연 광상의 돌로마이트 산상과 화학조성 = Occurrence and Chemical Composition of Dolomite from Zhenzigou Pb-Zn Deposit, China

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

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      The Zhenzigou Pb-Zn deposit, one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and monzoritic granite. The Zhenzigou deposit which is a strata bound SEDEX or SEDEX type deposit occurs as layer ore and vein ore in Langzishan formation and Dashiqiao formation of the Paleoproterozoic Liaohe group. Based on mineral petrography and paragenesis, dolomites from this deposit are classified three type (1. dolomite (D<sub>0</sub>) as hostrock, 2. dolomite (D<sub>1</sub>) in layer ore associated with white mica, quartz, K-feldspar, sphalerite, galena, pyrite, arsenopyrite from greenschist facies, 3. dolomite (D<sub>2</sub>) in vein ore associated with quartz, apatite and pyrite from quartz vein). The structural formulars of dolomites are determined to be Ca<sub>1.00-1.03</sub>Mg<sub>0.94-0.98</sub>Fe<sub>0.00-0.06</sub>As<sub>0.00-0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>0</sub>), Ca<sub>0.97-1.16</sub>Mg<sub>0.32-0.83</sub>Fe<sub>0.10-0.50</sub>Mn<sub>0.01-0.12</sub>Zn<sub>0.00-0.01</sub>Pb<sub>0.00-0.03</sub>As<sub>0.00-0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>1</sub>), Ca<sub>1.00-1.01</sub>Mg<sub>0.85-0.92</sub>Fe<sub>0.06-0.11</sub> Mn<sub>0.01-0.03</sub>As<sub>0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>2</sub>), respectively. It means that dolomites from the Zhenzigou deposit have higher content of trace elements compared to the theoretical composition of dolomite. Feo and MnO contents of these dolomites (D<sub>0</sub>, D<sub>1</sub> and D<sub>2</sub>) contain 0.05-2.06 wt.%, 0.00-0.08 wt.% (D<sub>0</sub>), 3.53-17.22 wt.%, 0.49-3.71 wt.% (D<sub>1</sub>) and 2.32-3.91 wt.%, 0.43-0.95 wt.% (D<sub>2</sub>), respectively. The dolomite (D<sub>1</sub>) from layer ore has higher content of these trace elements (FeO, MnO, ZnO and PbO) than dolomite (D<sub>0</sub>) from hostrock and dolomite (D<sub>2</sub>) from quartz vein. Dolomites correspond to Ferroan dolomite (D<sub>0</sub> and D<sub>2</sub>), and ankerite and Ferroan dolomite (D<sub>1</sub>), respectively. Therefore, 1) dolomite (D<sub>0</sub>) from hostrock is a Ferroan dolomite formed by marine evaporative lagoon environment in Paleoproterozoic Jiao Liao Ji basin. 2) Dolomite (D<sub>1</sub>) from layer ore is a ankerite and Ferroan dolomite formed by hydrothermal metasomatism origined metamorphism (greenschist facies) associated with Paleoproterozoic intrusion. 3) Dolomte (D<sub>2</sub>) from quartz vein is a Ferroan dolomite formed by hydrothermal fluid origined Mesozoic intrusion.
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      The Zhenzigou Pb-Zn deposit, one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite,...

      The Zhenzigou Pb-Zn deposit, one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and monzoritic granite. The Zhenzigou deposit which is a strata bound SEDEX or SEDEX type deposit occurs as layer ore and vein ore in Langzishan formation and Dashiqiao formation of the Paleoproterozoic Liaohe group. Based on mineral petrography and paragenesis, dolomites from this deposit are classified three type (1. dolomite (D<sub>0</sub>) as hostrock, 2. dolomite (D<sub>1</sub>) in layer ore associated with white mica, quartz, K-feldspar, sphalerite, galena, pyrite, arsenopyrite from greenschist facies, 3. dolomite (D<sub>2</sub>) in vein ore associated with quartz, apatite and pyrite from quartz vein). The structural formulars of dolomites are determined to be Ca<sub>1.00-1.03</sub>Mg<sub>0.94-0.98</sub>Fe<sub>0.00-0.06</sub>As<sub>0.00-0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>0</sub>), Ca<sub>0.97-1.16</sub>Mg<sub>0.32-0.83</sub>Fe<sub>0.10-0.50</sub>Mn<sub>0.01-0.12</sub>Zn<sub>0.00-0.01</sub>Pb<sub>0.00-0.03</sub>As<sub>0.00-0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>1</sub>), Ca<sub>1.00-1.01</sub>Mg<sub>0.85-0.92</sub>Fe<sub>0.06-0.11</sub> Mn<sub>0.01-0.03</sub>As<sub>0.01</sub>(CO<sub>3</sub>)<sub>2</sub>(D<sub>2</sub>), respectively. It means that dolomites from the Zhenzigou deposit have higher content of trace elements compared to the theoretical composition of dolomite. Feo and MnO contents of these dolomites (D<sub>0</sub>, D<sub>1</sub> and D<sub>2</sub>) contain 0.05-2.06 wt.%, 0.00-0.08 wt.% (D<sub>0</sub>), 3.53-17.22 wt.%, 0.49-3.71 wt.% (D<sub>1</sub>) and 2.32-3.91 wt.%, 0.43-0.95 wt.% (D<sub>2</sub>), respectively. The dolomite (D<sub>1</sub>) from layer ore has higher content of these trace elements (FeO, MnO, ZnO and PbO) than dolomite (D<sub>0</sub>) from hostrock and dolomite (D<sub>2</sub>) from quartz vein. Dolomites correspond to Ferroan dolomite (D<sub>0</sub> and D<sub>2</sub>), and ankerite and Ferroan dolomite (D<sub>1</sub>), respectively. Therefore, 1) dolomite (D<sub>0</sub>) from hostrock is a Ferroan dolomite formed by marine evaporative lagoon environment in Paleoproterozoic Jiao Liao Ji basin. 2) Dolomite (D<sub>1</sub>) from layer ore is a ankerite and Ferroan dolomite formed by hydrothermal metasomatism origined metamorphism (greenschist facies) associated with Paleoproterozoic intrusion. 3) Dolomte (D<sub>2</sub>) from quartz vein is a Ferroan dolomite formed by hydrothermal fluid origined Mesozoic intrusion.

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      참고문헌 (Reference)

      1 유봉철, "검덕 연-아연 광상의 돌로마이트 산상과 화학조성" 한국광물학회 34 (34): 107-120, 2021

      2 Deng, G. Q., "Types and main ore controlling factors of the Liaohe group in the middle of Liaodong" 1 : 53-70, 1983

      3 Zhou, L. L., "Tracing mineralization history from the compositional textures of sulfide association : A case study of the Zhenzigou stratiform Zn-Pb deposit, NE China" 126 : 103792-, 2020

      4 Zhai M., "The geology of North Korea : An overview" 194 : 57-96, 2019

      5 Rajabi, A., "The early Cambrian Chahmir shale-hosted Zn-Pb deposit, Central Iran : An example of vent-proximal SEDEX mineralization" 50 : 571-590, 2015

      6 Biondi, J. C., "The Paleoproterozoic Aripuana Zn-Pb-Ag(Au, Cu)volcanogenic massive sulfide deposit, Mato Grosso, Brazil : Geology, geochemistry of alteration, carbon and oxygen isotope modeling, and implications for genesis" 108 : 781-811, 2013

      7 Chen, C., "Sedimentary characteristics of Mg-rich carbonate fromations and minerogenic fluids of magnesite and talc occurrences in early Proterozoic in eastern Liaoning province, China" 45 : 84-92, 2002

      8 Morrow, D. W., "Regional subsurface dolomitization : Models and constraints" 25 : 57-70, 1998

      9 Johnson, A. W., "Regional studies of dolomites and their included fluids : Recognizing multiple chemically distinct fluids during the complex diagenetic history of Lower Carboniferous(Mississippian)rocks of the Irish Zn-Pb ore field" 96 : 1-18, 2009

      10 Gomez-Rivas, E., "Reactivity of dolomitizing fluids and Mg source evaluation of fault controlled dolomitization at the Benicàssim outcrop analogue(Maestrat basin, E Spain)" 55 : 26-42, 2014

      1 유봉철, "검덕 연-아연 광상의 돌로마이트 산상과 화학조성" 한국광물학회 34 (34): 107-120, 2021

      2 Deng, G. Q., "Types and main ore controlling factors of the Liaohe group in the middle of Liaodong" 1 : 53-70, 1983

      3 Zhou, L. L., "Tracing mineralization history from the compositional textures of sulfide association : A case study of the Zhenzigou stratiform Zn-Pb deposit, NE China" 126 : 103792-, 2020

      4 Zhai M., "The geology of North Korea : An overview" 194 : 57-96, 2019

      5 Rajabi, A., "The early Cambrian Chahmir shale-hosted Zn-Pb deposit, Central Iran : An example of vent-proximal SEDEX mineralization" 50 : 571-590, 2015

      6 Biondi, J. C., "The Paleoproterozoic Aripuana Zn-Pb-Ag(Au, Cu)volcanogenic massive sulfide deposit, Mato Grosso, Brazil : Geology, geochemistry of alteration, carbon and oxygen isotope modeling, and implications for genesis" 108 : 781-811, 2013

      7 Chen, C., "Sedimentary characteristics of Mg-rich carbonate fromations and minerogenic fluids of magnesite and talc occurrences in early Proterozoic in eastern Liaoning province, China" 45 : 84-92, 2002

      8 Morrow, D. W., "Regional subsurface dolomitization : Models and constraints" 25 : 57-70, 1998

      9 Johnson, A. W., "Regional studies of dolomites and their included fluids : Recognizing multiple chemically distinct fluids during the complex diagenetic history of Lower Carboniferous(Mississippian)rocks of the Irish Zn-Pb ore field" 96 : 1-18, 2009

      10 Gomez-Rivas, E., "Reactivity of dolomitizing fluids and Mg source evaluation of fault controlled dolomitization at the Benicàssim outcrop analogue(Maestrat basin, E Spain)" 55 : 26-42, 2014

      11 Ma, Y. B., "Rb-Sr isotopic age of sphalerites from Qingchengzi stratiform Pb-Zn ores and its implication for the ore forming process" 88 : 996-998, 2014

      12 Chen, J. F., "Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China" 48 : 467-476, 2005

      13 Li, J. A., "Paleoproterozoic SEDEXtype stratiform mineralization overprinted by Mesozoic vein-type mineralization in the Qingchenzi Pb-Zn deposit, Northeastern China" 184 : 104009-, 2019

      14 Li, S. Z., "Palaeoproterozoic tectonothermal evolution and deep crustal processes in the Jiao-Liao-Ji belt, North China Craton : A review" 46 : 525-543, 2011

      15 Hendry, J. P., "Origin, characteristics and distribution of fault-related and fracture-related dolomitization : Insights from Mississippian carbonates, Isle of Man, UK" 62 : 717-752, 2015

      16 Grandia, F., "Origin of ore-forming brines in sediment-hosted Zn-Pb deposits of the Basque-Cantabrian Basin, Northern Spain" 98 : 1397-1411, 2003

      17 Wilkinson, J. J., "Ore-forming processes in Irish-Type carbonate-hosted Zn-Pb deposits : Evidence from mineralogy, chemistry, and isotopic composition of sulphides at the Lisheen mine" 100 : 63-86, 2005

      18 Konari, M. B., "Nature and origin of dolomitization associated with sulphide mineralization : New insights from the Tappehsorkh Zn-Pb(-Ag-Ba)deposit, Irankuh mining district, Iran" 53 : 1-21, 2018

      19 Reinhold, C., "Multiple episodes of dolomitization and dolomite recrystallization during shallow burial in Upper Jurassic shelf carbonates : eastern Swabian Alb, southern Germany" 121 : 71-95, 1998

      20 Liu, G. P., "Isospatial metallogenesis in Qingchengzi ore filed, Liaoning" 8 : 277-282, 1999

      21 Li, Z., "Is the Paleoproterozoic Jiao-Liao-Ji belt(North China Craton)a rift?" 106 : 355-375, 2017

      22 Li, D. D., "Iron isotopes as an ore-fluid tracer : Case study of Qingchengzi Pb-Zn-Au(-Ag)orefield in Liaoning, NE China" 71 : 283-295, 2021

      23 Wright, W. R., "Irish Lower Carboniferous replacement dolomite: Isotopic modelling evidence for a diagenetic origin involving low-temperature modified seawater. In: The geometry and petrogenesis of dolomite hydrocarbon reservoirs" 235 : 75-97, 2004

      24 Yu, G., "Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb-Zn-Ag-Au orefield, Northeastern China" 35 : 367-382, 2009

      25 Jiang, S. Y., "Geochemistry of the Qingchengzi lead-zinc deposit" 8 : 20-28, 1989

      26 Ma, Y. B., "Genesis of the stratiform Zhenzigou Pb-Zn deposit in the North China Craton : Rb-Sr and C-O-SPb isotope constraints" 79 : 88-104, 2016

      27 Bouabdellah, M., "Genesis of the Touissit-Bou Beker Mississippi Valley-Type District(Morocco-Algeria)and Its Relationship to the Africa-Europe Collision" 107 : 117-146, 2012

      28 Duan, X. X., "Genesis of the Pb-Zn deposits of the Qingchengzi ore field, eastern Liaoning, China : Constraints from carbonate LA-ICPMS trace element analysis and C-O-SPb isotopes" 89 : 752-771, 2017

      29 Nagy, Z. R., "Early dolomitization and fluid migration through the Lower Carboniferous carbonate platform in the SE Irish Midlands: implications for reservoir attributes. In: The geometry and petrogenesis of dolomite hydrocarbon reservoirs" 235 : 367-392, 2004

      30 Zentmyer, R. A., "Dolomitization on an evaporitic Paleoproterozoic ramp : Widespread synsedimentary dolomite in the Denault Formation, Labrador Trough, Canada" 238 : 116-131, 2011

      31 Ren, Y., "Dolomite geochemistry of the Cambrian Longwangmiao formation, eastern Sichuan basin : Implication for dolomitization and reservoir prediction" 2 : 64-76, 2017

      32 Li, S. Z., "Deformation history of the Paleoproterozoic Liaohe assemblage in the Eastern Block of the North China Craton" 24 : 659-674, 2005

      33 Song, Y. H., "Characteristics of mineralization fluids and tracers of mineralization material sources of the Qingchengzi lead-zinc deposit in Liaoning Province" 53 : 259-269, 2017

      34 Wang, Y. C., "Characteristics of hydrothermal superposition mineralization and fluid origins of the Xiaotongjiapuzi gold deposit in Liaoning Province" 51 : 79-87, 2015

      35 Wilkinson, J. J., "A review of fluid inclusion constraints on mineralization in the Irish ore field and implications for the genesis of sediment-hosted Zn-Pb deposits" 105 : 417-442, 2010

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