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      중금속 오염이 n형 실리콘 태양전지의 전기적 특성에 미치는 영향에 대한 연구

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      https://www.riss.kr/link?id=A105233428

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      The dependency of the photovoltaic performance of p-/n-type silicon solar-cells on the metallic contaminant type (Fe, Cu, and Ni) and concentration was investigated. The minority-carrier recombination lifetime was degraded with increasing metallic contaminant concentration, however, the degradation sensitivity of recombination lifetime was lower at n-type than p-type silicon wafer, which means n-type silicon wafer have an immunity to the effect of metallic contamination. This is because heavy metal ions with positive charge have a much larger capture cross section of electron than hole, so that reaction with electrons occurs much more easily. The power conversion efficiency of n-type solar-cells was degraded by 9.73% when metallic impurities were introduced in the silicon bulk, which is lower degradation compared to p-type solar-cells (15.61% of efficiency degradation). Therefore, n-type silicon solar-cells have a potential to achieve high efficiency of the solar-cell in the future with a merit of immunity against metal contamination.
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      The dependency of the photovoltaic performance of p-/n-type silicon solar-cells on the metallic contaminant type (Fe, Cu, and Ni) and concentration was investigated. The minority-carrier recombination lifetime was degraded with increasing metallic con...

      The dependency of the photovoltaic performance of p-/n-type silicon solar-cells on the metallic contaminant type (Fe, Cu, and Ni) and concentration was investigated. The minority-carrier recombination lifetime was degraded with increasing metallic contaminant concentration, however, the degradation sensitivity of recombination lifetime was lower at n-type than p-type silicon wafer, which means n-type silicon wafer have an immunity to the effect of metallic contamination. This is because heavy metal ions with positive charge have a much larger capture cross section of electron than hole, so that reaction with electrons occurs much more easily. The power conversion efficiency of n-type solar-cells was degraded by 9.73% when metallic impurities were introduced in the silicon bulk, which is lower degradation compared to p-type solar-cells (15.61% of efficiency degradation). Therefore, n-type silicon solar-cells have a potential to achieve high efficiency of the solar-cell in the future with a merit of immunity against metal contamination.

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      목차 (Table of Contents)

      • ABSTRACT
      • 1. 서론
      • 2. 실험
      • 3. 결과 및 고찰
      • 4. 결론
      • ABSTRACT
      • 1. 서론
      • 2. 실험
      • 3. 결과 및 고찰
      • 4. 결론
      • References
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      참고문헌 (Reference)

      1 J. Schmidt, "Structure and transformation of the metastable boron-and oxygen-related defect center in crystalline silicon" 69 : 024107-, 2004

      2 B. G. Streetman, "Solid State Electronic Devices" Pearson Prentice Hall 2006

      3 D. Macdonald, "Recombination activity of interstitial iron and other transition metal point defects in p-and n–type crystalline silicon" 85 : 4061-4063, 2004

      4 P. Papet, "Pyramidal texturing of silicon solar cell with TMAH chemical anisotropic etching" 90 : 2319-2328, 2006

      5 S. M. Sze, "Physics of Semiconductor Devices" John Wiley &Sons, Inc. 2007

      6 F. Feldmann, "Passivated rear contacts for high-efficiency n-type Sisolar cells providing high interface passivation quality and excellent transport characteristics" 120 : 270-274, 2014

      7 S. W. Glunz, "Minority carrier lifetime degradation in boron-doped Czochralski silicon" 90 : 2397-2404, 2001

      8 K. Graff, "Metal impurities in silicon-device fabrication" Springer Science & Business Media 2013

      9 A. A. Istratov, "Iron and its complexes in silicon" 69 : 13-44, 1999

      10 J. Schmidt, "Investigation of carrier lifetime instabilities in Cz-grown silicon" 13-18, 1997

      1 J. Schmidt, "Structure and transformation of the metastable boron-and oxygen-related defect center in crystalline silicon" 69 : 024107-, 2004

      2 B. G. Streetman, "Solid State Electronic Devices" Pearson Prentice Hall 2006

      3 D. Macdonald, "Recombination activity of interstitial iron and other transition metal point defects in p-and n–type crystalline silicon" 85 : 4061-4063, 2004

      4 P. Papet, "Pyramidal texturing of silicon solar cell with TMAH chemical anisotropic etching" 90 : 2319-2328, 2006

      5 S. M. Sze, "Physics of Semiconductor Devices" John Wiley &Sons, Inc. 2007

      6 F. Feldmann, "Passivated rear contacts for high-efficiency n-type Sisolar cells providing high interface passivation quality and excellent transport characteristics" 120 : 270-274, 2014

      7 S. W. Glunz, "Minority carrier lifetime degradation in boron-doped Czochralski silicon" 90 : 2397-2404, 2001

      8 K. Graff, "Metal impurities in silicon-device fabrication" Springer Science & Business Media 2013

      9 A. A. Istratov, "Iron and its complexes in silicon" 69 : 13-44, 1999

      10 J. Schmidt, "Investigation of carrier lifetime instabilities in Cz-grown silicon" 13-18, 1997

      11 C. Gong, "High efficient n-type back-junction back-contact silicon solar cells with screen-printed al-alloyed emitter and effective emitter passivation study" 19 : 781-786, 2011

      12 A. A. Istratov, "Electrical properties and recombination activity of copper, nickel and cobalt in silicon" 66 : 123-136, 1998

      13 U. Jager, "Benefit of selective emitters for p-Type silicon solar cells with passivated surfaces" 3 (3): 621-627, 2013

      14 E. Van Kerschaver, "Back-contact solar cells : a review" 14 : 107-123, 2006

      15 A. Rehman, "Advancements in n-Type base crystalline silicon solar cells and their emergence in the photovoltaic industry" 2013 : 2013

      16 K. Masuko, "Achievement of more than 25% conversion efficiency with crystalline silicon heterojunction solar cell" 4 (4): 1433-1435, 2014

      17 M. Taguchi, "24. 7% Record efficiency HIT solar cell on thin silicon wafer" 4 (4): 96-99, 2014

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