메조포러스 물질의 합성과 응용에 관한 연구 = (A) study on the preparation and applications of mesoporous silica materials

다국어 초록 (Multilingual Abstract)

Highly ordered pure-silica MCM-41 materials possessing well-defined morphology have been successfully prepared with surfactant used as a template. The synthesis of mesoporous silica material has received considerable attention due to the need to develop more efficient materials for catalysis, separations, and chemical sensing. The surface modified MCM-41 was used as adsorbent for biomolecules. Silica-supported organic groups and DNA adsorption on surface modified MCM-41 were investigated by FT-IR and UV-Vis spectrometer. The use of MCM-41 as the modification of electrode sufaces were investigated electrochemical properties of metal mediators with biomolecules. The modified ITO electrodes increased peak currents for the redox process of [Ru(bpy)_(3)]^(2+) relative to the bare electrode. The electrochemical detection of DNA by cyclic voltammetry when the current is saturated in the presence of the mediator appeared more sensitive due to a higher catalytic current on the MCM-41 supported electrodes modified by amine, thiol and carboxylic acid functional groups. The functional groups on the inner, outer, dual surface of MCM-41 interact and react with the NH_(2) groups of DNA. Ordered mesoporous materials with organic group could find applications as DNA sensors.

목차 (Table of Contents)

• 목차 = ⅰ
• 제1장 서론 = 1
• 제2장 이론 = 4
• 제1절 졸-겔 법 = 4
• 1.1 졸-겔 법 = 4
• 1.2 졸-겔 반응 = 7
• 1.3 졸-겔 반응에 영향을 미치는 요소 = 10
• 제2절 순환 전압-전류 곡선 (Cyclic Voltammogram : CV) = 14
• 제3장 실험 = 18
• 제1절 시약 = 18
• 제2절 분석 장치 = 19
• 제3절 실험 방법 = 20
• 3.1 메조 크기의 기공을 갖는 MCM-41의 제조 = 20
• 3.2 MCM-41의 선택적 표면 변형 = 20
• 3.3 표면 변형된 MCM-41의 전기화학적 분석 = 24
• 제4장 결과 및 고찰 = 27
• 제1절 메조 크기의 기공을 가지는 MCM-41의 특성 분석 = 27
• 제2절 MCM-41의 표면 변형 = 34
• 제3절 표면 변형된 MCM-41의 DNA 흡착 = 39
• 제4절 선택적으로 표면 변형된 MCM-41의 전기화학적 특성 = 42
• 제5장 결론 = 48
• 참고문헌 = 49
• Abstract = 53