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      Pulsed-UV 시스템을 이용한 염소계 유기화합물 및 화약류 제거에 관한 연구 = A Study on Remediation of Chlorinated Hydrocarbons and Explosives using Pulsed-UV System

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      https://www.riss.kr/link?id=A101661912

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      다국어 초록 (Multilingual Abstract)

      This study was conducted in order to evaluate the removal process for long-term contamination sources including chlorinated hydrocarbons (TCE and PCE) and explosive compounds (TNT, RDX, and HMX) in underground water using a pulsed-UV system. Crystallized cells containing the contaminants were placed 10, 20, and 40 cm away from a lamp that emits pulsed-UV rays in order to examine how the removal efficiency is influenced by the distance between the source of the light and the compounds. Chlorinated hydrocarbons were completely removed in 30 minutes with a distance of 10 cm, while PCE was completely removed even with a distance of 20 cm. In the case of explosive compounds, removal efficiencies slightly varied depending on the compounds. The majority of the compounds were perfectly removed with a contact time of 10 minutes. In particular, for RDX, the results showed that complete removal was obtained within one minute, regardless of the distance from the UV source. The amount of light energy is in inverse proportion to the distance, and thus the energy reaching the compounds severely diminishes as the distance increases. Therefore, the removal efficiency decreased with increasing distance in the system.
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      This study was conducted in order to evaluate the removal process for long-term contamination sources including chlorinated hydrocarbons (TCE and PCE) and explosive compounds (TNT, RDX, and HMX) in underground water using a pulsed-UV system. Crystalli...

      This study was conducted in order to evaluate the removal process for long-term contamination sources including chlorinated hydrocarbons (TCE and PCE) and explosive compounds (TNT, RDX, and HMX) in underground water using a pulsed-UV system. Crystallized cells containing the contaminants were placed 10, 20, and 40 cm away from a lamp that emits pulsed-UV rays in order to examine how the removal efficiency is influenced by the distance between the source of the light and the compounds. Chlorinated hydrocarbons were completely removed in 30 minutes with a distance of 10 cm, while PCE was completely removed even with a distance of 20 cm. In the case of explosive compounds, removal efficiencies slightly varied depending on the compounds. The majority of the compounds were perfectly removed with a contact time of 10 minutes. In particular, for RDX, the results showed that complete removal was obtained within one minute, regardless of the distance from the UV source. The amount of light energy is in inverse proportion to the distance, and thus the energy reaching the compounds severely diminishes as the distance increases. Therefore, the removal efficiency decreased with increasing distance in the system.

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      참고문헌 (Reference)

      1 안영석, "펄스 UV 램프를 이용한 미생물 소독 및 2-MIB 제거 특성" 대한상하수도학회 23 (23): 69-75, 2009

      2 Stasinakis, A. S., "Use of selected advanced oxidation proeê cesses (AOPs) for wastewater treatment - a mini review" 10 (10): 376-385, 2008

      3 Kazama, M., "Treatment technology of organic waste water using low-pressure ultraviolet method" 18 (18): 1-15, 1987

      4 Guo Zheng Zhao, "Theoretical Studies on Nitramine Explosives with -NH2 and -F Groups" 대한화학회 33 (33): 1913-1918, 2012

      5 Shao, J., "The C-NO2 bond dissociation energies of some nitroaromatic compounds: DFT study" 17 (17): 547-550, 2006

      6 Fang, M., "Substituent Effect of the CNO2 and N-NO2 Bond Dissociation Energies of Nitroaromatic Molecules" 26 : 1112-1128, 2008

      7 Jung, E. T., "Removal of taste and odor causing compounds in drinking water using Pulse UV System" 741-742, 2012

      8 Park, J. S., "Removal Characteristics of Non-biogradable Organics in RO Brine by Pulse UV System" 840-841, 2012

      9 Pruden, L.A., "Photoassisted heterogeneous catalysis: the degradation of trichloroethylene in water" 82 : 404-417, 1983

      10 Shirayama, H., "Phothdegradation of chlorinated hydrocarbons in the presence and absence of dissolved oxygen in water" 35 (35): 1941-1950, 2001

      1 안영석, "펄스 UV 램프를 이용한 미생물 소독 및 2-MIB 제거 특성" 대한상하수도학회 23 (23): 69-75, 2009

      2 Stasinakis, A. S., "Use of selected advanced oxidation proeê cesses (AOPs) for wastewater treatment - a mini review" 10 (10): 376-385, 2008

      3 Kazama, M., "Treatment technology of organic waste water using low-pressure ultraviolet method" 18 (18): 1-15, 1987

      4 Guo Zheng Zhao, "Theoretical Studies on Nitramine Explosives with -NH2 and -F Groups" 대한화학회 33 (33): 1913-1918, 2012

      5 Shao, J., "The C-NO2 bond dissociation energies of some nitroaromatic compounds: DFT study" 17 (17): 547-550, 2006

      6 Fang, M., "Substituent Effect of the CNO2 and N-NO2 Bond Dissociation Energies of Nitroaromatic Molecules" 26 : 1112-1128, 2008

      7 Jung, E. T., "Removal of taste and odor causing compounds in drinking water using Pulse UV System" 741-742, 2012

      8 Park, J. S., "Removal Characteristics of Non-biogradable Organics in RO Brine by Pulse UV System" 840-841, 2012

      9 Pruden, L.A., "Photoassisted heterogeneous catalysis: the degradation of trichloroethylene in water" 82 : 404-417, 1983

      10 Shirayama, H., "Phothdegradation of chlorinated hydrocarbons in the presence and absence of dissolved oxygen in water" 35 (35): 1941-1950, 2001

      11 Brill, T.B., "Kinetics and Mechanism of Thermal Decomposition of Nitroaromatic Explosives" 93 : 2567-2592, 1993

      12 Drijvers, D., "Decomposition of phenol and trichloroethylene by the ultrasound/H2O2/ CuO process" 33 (33): 1187-1194, 1999

      13 Movahedyan, H., "Comparison of different advanced oxidation precesses degrading p-chlorophenol in aqueous solution" 6 (6): 153-160, 2009

      14 Michal, P., "Characterization of C-NO2 Bonds in Nitroaromatic Compounds: A Bond Disproportionation Approach" 7 (7): 131-144, 2010

      15 Choi, K.S., "Assessment of natural organic matter (NOM), chlorine residual, and disinfection by-products formaion in pulsed UV treatment" Graduate School of Kookmin University 2010

      16 Alfons Vogelpohl, "Advanced Oxidation Processes (AOPs) in Wastewater Treatment" 한국공업화학회 10 (10): 33-40, 2004

      17 Mullen, K., "Adsorption of Chlorinated Ethylenes at 1-Octadecanethiol-Modified Silver Surfaces" 66 (66): 478-483, 1994

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      2016 0.3 0.3 0.35
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