알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(Ⅰ)

다국어 초록 (Multilingual Abstract)

Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate materials for the high performance liquid fuel component because of its high density and heat of combustion value. The object of this study was to find out the proper reaction condition to improve the fluidity of THTCPD which is solid state at room temperature. Therefore, we have carried out isomerization reactions using aluminum chloride in the varying reaction condition such as reaction temperature and solvents. The results showed that when using aluminum chloride catalyst, THTCPD isomerization reaction was more active in the polar halogenated reaction media such as dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than in non-polar hydrocarbon media such as n-Hexnae and toluene and was effected by reaction temperature variation.

참고문헌 (Reference)

1 Zhongqiang Xiong, "Study on the oligomerization of cyclopentadiene and dicyclopentadiene to tricyclopentadiene through Diels-Alder reaction" 85 (85): 89-97, 2005

2 정병훈, "Norbornadiene의 이량화반응에 의한 다중고리 탄화수소화합물의 제조" 190-193, 2007

3 Enhui Xing, "Molecular dimensions of tetrahydrodicyclopentadiene isomers and shape selectivity of zeolitic catalysts" ELSEVIER 6 (6): 737-741, 2005