傳導性 高分子/溫度 敏感性 高分子電解質 複合體에 關한 硏究 = (A) study on the conducting polymer thermo-sensitive polyelectrolyte composites

다국어 초록 (Multilingual Abstract)

The mass change by the ion behavior in the redox process of the PPy/PE composite was concerned mainly by the cation, but the insertiodexpulsion of the mono-anion (c104 ) in solution into/from the PPy composite occurred in order to combine/dssociate with the oxidizedreduced PPy in the redox process of the PPy/PE composite when the electroactivity of the PPy was considerable. In the higher sweep rate of the potential, the mass change by the insertiodexpulsion decreased for lower ion mobility and increased for higher ion mobility into/from the PPy composite. The electroactivity of the PPy composite decreased with increasing the temperature. The mass of the PPy/P(AAm/AMPS) was linearly decreased with increasing the temperature, but the slope of the mass decrease of the PPy/P(NiPAAm/AMPS) was changed. The temperature at which the slope change in the mass decrease of the PPy/P(NiPAAm /AMPS) was different in the oxidized and reduced PPy due to the combinatioddissociation of the PPy and poly -anionic dopant (AMPS). From these results, we note that the PPy composite synthesized by the copolymer of the water soluble polymer and the small portion of electrolyte has the considerable electroactivity and the PPy composite synthesized by the themally sensitive polymer and polyelectrolyte copolymer has not only the thermal sensitivity but also the current sensitivity.

목차 (Table of Contents)

• 목차
• List of figures
• List of table
• I. 서론 = 1
• II. 이론
• 2.1 전도성 고분자 = 3
• 2.2 전기화학 분석 장치 = 6
• 2.2 전도성 고분자의 전기화학중합 = 7
• 2.4 전도성 고분자의 산화 ·환원 반응 = 8
• 2.4.1 순환전류전압법 = 8
• 2.4.2 산화 ·환원 반응에 의한 ion의 거동 = 10
• 2.5 열민감성 고분자 = 12
• 2.6 수정 결정 미량 저울 = 14
• III.실험
• 3.1 고분자 전해질과 수용성고분자의 공증합 = 18
• 3.2 Pyrrole의 전기화학중합과 산화 ·환원반응 = 21
• 3.3 Polypyrrole/열민감성 고분자전해질 복합체의 전이온도 변화 = 23
• IV.결과 및 검토
• 4.1 고분자 전해질 공중합체의 조성분석 = 25
• 4.2 Pyrrole의 전기화학중합 = 26
• 4.3 Polypyrrole/고분자 전해질 복합체의 전기활성 = 30
• 4.3.1 단분자전해질 복합체의 전기활성 = 30
• 4.3.2 고분자전해질과 단분자전해질에서 PPy 복합체의 전기활성 = 34
• 4.3.3 수용성고분자의 종류에 의한 PPy 복합체의 전기활성 = 37
• 4.3.4 순환전위의 sweep rate 변화에 의한 이온의 거동 = 40
• 4.3.5 온도변화에 의한 PPy 복합체의 전기활성 = 43
• 4.3.6 고분자전해질 공중합체의 조성변화에 의한 PPy 복합체의 전기활성 = 46
• 4.4 Polypyrrole 복합체의 전이온도 = 49
• V.결론 = 55
• VI.참고문헌 = 57
• ABSTRACT