오존전량 및 대류권 오존 프로파일 산출을 위한 지상관측 MAX-DOAS 원시자료 기반의 최적추정(Optimal Estimation) 기술 = Optimal Estimation (OE) Technique to Retrieve the Ozone Column and Tropospheric Ozone Profile Based on Ground-based MAX-DOAS Measurement

다국어 초록 (Multilingual Abstract)

In this present study, we, for the first time, retrieved total column of ozone (O3) and tropospheric ozone vertical profile using the Optimal Estimation (OE) method based on the MAX-DOAS measurement at the Yonsei University in Seoul, Korea. The optical density fitting is carried out using the OE method to calculate ozone columns. The optical density between the MAX-DOAS data obtained by dividing the measured intensities for each viewing elevated angle by those at the zenith angle. The retrieved total columns of the ozone are 375.4 and 412.6 DU in the morning (08:13) and afternoon (17:55) on 23 May, 2017, respectively. In addition, under 10 km altitude, the O3 vertical profile was retrieved with about 5% of retrieval uncertainty. However, above 10 km altitude, the O3 vertical profile retrieval uncertainty was increased (>10%). The spectral fitting errors are 16.8% and 19.1% in the morning and afternoon, respectively. The method suggested in this present study can be useful to measure the total ozone column using the ground-based hyper-spectral UV sensors.

국문 초록 (Abstract)

본 연구에서는 한반도 서울의 연세대학교에서 Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS)장비로부터 산출된 원시자료를 이용하여 처음으로 최적추정(Optimal Estimation; OE)을 사용하여 오존전량 및 오존의 대류권 프로파일을 산출하였다. 오존전량 및 오존의 대류권 프로파일을 산출하기 위하여 최적추정을 통하여 MAX-DOAS자료의 광학두께 피팅을 수행하였다. 광학두께 피팅은 MAX-DOAS 장비로부터 각각의 기기 고도각별로 관측된 값을 천정각에서 관측된 값으로 나누어 계산된 자료를 통하여 수행하였다. 오존전량은 2017년 5월 23일 오전(08:13)과 오후(17:55)에 각각 375.4와 412.6 DU로 산출되었다. 오존의 대류권 프로파일(<10 km)은 참 값 오존존데와 비교하여 약 5% 이내의 오차로 산출되었다. 하지만 10 km 이상의 높은 고도에서는 산출 에러가 커져 10% 이상 과대추정 하는 것으로 산출되었다. MAX-DOAS 자료의 스펙트럼 피팅에 의한오차는 오전과 오후에 각각 16.8%와 19.1%로 계산되었다. 본 연구에서 제시한 방법은 지상관측 기반의 초분광UV 센서를 이용하여 오존전량과 대류권 오존 프로파일을 산출하는데 유용하게 사용될 수 있다.

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