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      자전연소합성법으로 제조한 80wt% AB_2-15wt% Mg-5wt% Mm 금속수소화물의 cycling특성 = Cycling Properties of 80wt% AB_2-15wt% Mg-5wt% Mm Metal Hydride made by Hydriding Combustion Synthesis

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      https://www.riss.kr/link?id=A104391220

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      다국어 초록 (Multilingual Abstract)

      The effect of cycling on the absorption and desorption characteristics of the 80 wt% AB_2-15 wt% Mg-5wt% Mm system was investigated. The material was made by Hydrogen Combustion Synthesis. The cycling experiment was performed at 298 K, 30 atm for 15 min. During the reaction time, the amount of absorption was fully desorbed. After the full activation, the hydrogen storage capacity was 1.57 wt% and the capacity was maintained until 50 cycles. And the reaction rate does not change with an increase in the number of cycles. This material has good durability and reversible feature.
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      The effect of cycling on the absorption and desorption characteristics of the 80 wt% AB_2-15 wt% Mg-5wt% Mm system was investigated. The material was made by Hydrogen Combustion Synthesis. The cycling experiment was performed at 298 K, 30 atm for 15 m...

      The effect of cycling on the absorption and desorption characteristics of the 80 wt% AB_2-15 wt% Mg-5wt% Mm system was investigated. The material was made by Hydrogen Combustion Synthesis. The cycling experiment was performed at 298 K, 30 atm for 15 min. During the reaction time, the amount of absorption was fully desorbed. After the full activation, the hydrogen storage capacity was 1.57 wt% and the capacity was maintained until 50 cycles. And the reaction rate does not change with an increase in the number of cycles. This material has good durability and reversible feature.

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      참고문헌 (Reference)

      1 A. Suzuki, "Thermodynamic properties of Zr (FexMn1−x)2-H2 systems" 89 : 263-, 1983

      2 M. Dornheim, "Tailoring HydrogenStorage Materials Towards Application" 8 : 377-, 2006

      3 B. K. Singh, "Studies on the synthesis, characterization and hydrogenation behaviour of new Zr1−xMmx(Cr0.8Mo0.2)2 AB2-type hydrogen storage materials" 354 : 315-, 2003

      4 A. Singh, "Studies on Improvement of hydrogen storage capacity of AB5 type : MmNi4.6Fe0.4 alloy" 29 : 1151-, 2004

      5 R. Wakabayashi, "Self-iginition combustion synthesis of TiFe in hydrogen atmosphere" 480 : 592-, 2009

      6 T. Sakai, "Rare earth based alloy electrodes for a nickel metal hydride battery" 172 : 1175-, 1991

      7 A. Zaluska, "Nanocrystalline magnesium for hydrogen storage" 228 : 217-, 1999

      8 D. G. Ivey, "Metal hydrides for energy storage" 3 : 3-, 1981

      9 B. K. Singh, "Improved hydrogen sorption characteristics in Fe Ti1+x Mm material" 21 : 111-, 1996

      10 T. H. Hur, "Hydrogen storage properties of Zr-based AB2-xMx metal hydrides made by HCS" Kor. J. Met. Mater., Submission is scheduled

      1 A. Suzuki, "Thermodynamic properties of Zr (FexMn1−x)2-H2 systems" 89 : 263-, 1983

      2 M. Dornheim, "Tailoring HydrogenStorage Materials Towards Application" 8 : 377-, 2006

      3 B. K. Singh, "Studies on the synthesis, characterization and hydrogenation behaviour of new Zr1−xMmx(Cr0.8Mo0.2)2 AB2-type hydrogen storage materials" 354 : 315-, 2003

      4 A. Singh, "Studies on Improvement of hydrogen storage capacity of AB5 type : MmNi4.6Fe0.4 alloy" 29 : 1151-, 2004

      5 R. Wakabayashi, "Self-iginition combustion synthesis of TiFe in hydrogen atmosphere" 480 : 592-, 2009

      6 T. Sakai, "Rare earth based alloy electrodes for a nickel metal hydride battery" 172 : 1175-, 1991

      7 A. Zaluska, "Nanocrystalline magnesium for hydrogen storage" 228 : 217-, 1999

      8 D. G. Ivey, "Metal hydrides for energy storage" 3 : 3-, 1981

      9 B. K. Singh, "Improved hydrogen sorption characteristics in Fe Ti1+x Mm material" 21 : 111-, 1996

      10 T. H. Hur, "Hydrogen storage properties of Zr-based AB2-xMx metal hydrides made by HCS" Kor. J. Met. Mater., Submission is scheduled

      11 M. Dornheim, "Hydrogen storage in magnesium based hydrides and hydride composite" 56 : 841-, 2007

      12 M. Pozzo, "Hydrogen dissociationand diffusion on transition metal (¼Ti, Zr, V, Fe, Ru, Co, Rh, Ni, Pd, Cu, Ag)-doped Mg(0001) surfaces" 34 : 1922-, 2009

      13 H. K. Birnbaum, "Hydride precipitation in Nb and some properties of NbH" 49 : 357-, 1976

      14 S. J. Choi, "Electrochemical properties of the AB2-type metal hydride electrode prepared by ball milling" 8 : 181-, 1997

      15 ZG. Huang, "Effects of iron oxide (Fe2O3, Fe3O4) on hydrogen storage properties of Mgbased composites" 422 : 299-, 2006

      16 M. T. Hagstrὅm, "Effect of substitution on hyste-resis in some high-pressure AB2 and AB5 metal hydrides" 293 : 67-, 1999

      17 TR. Jensen, "Dehydrogenation kinetics of pure and nickel-doped magnesium hydride investigated by in situ time-resolved powder X-ray diffraction" 31 : 2052-, 2006

      18 D. Liu, "Crystal defect analysis and surface characteristics of Mg2NiH4 produced by hydriding combustion synthesis" 32 : 2417-, 2007

      19 L. Li, "Activation behaviors of Mg2NiH4 at different hydrogen pressures in hydriding combustion synthesis" 26 : 1035-, 2001

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