電解水 精練으로 回收된 세리신을 이용한 纖維의 表面改質 = Surface modification of fabrics with the collected sericin by degumming used in ERW

다국어 초록 (Multilingual Abstract)

To confirm the property of electrolytic water(EW), we conduct an experiment on the basic property test about the distilled water, electrolytic oxidation water(EOW) and electrolytic reduction water(ERW). When it comes to the degumming of silk fabric in using ERW, we made an experiment on the fixation and physical property. And at the same times, we carried out an various coating experiment on the PET, Cotton fabric surface with the collected sericin.
The results obtained in this study are as follows :
1. About stirring time, keeping time, bath condition and temperature, the pH of EW and ERW is almost unchanged. But, the ORP of ERW depend on temperature and keeping time.
2. In the experimental result of surface tension, contact angle, absorption, cleansing and emulsification of ERW, we confirm interfacial tension of ERW. Because of interfacial tension of ERW, the efficiency of no-agent degumming and hydrolysis advance.
3. By degumming of silk used in ERW, the collection of sericin protein polymer of high quality is easy, therefore, it will be very useful to the industrial application.
4. By finishing of sericin, moisture absorption of finished fabrics increased highly and laundry durability was low. But moisture absorption of modified sericin maintained after laundry in several times.
5. Because of the increase in moisture absorption, static electricity decease highly and flexural rigidity increase a little. According to the sericin attachment(％) and composition ratio of the binder, we can't find any difference.

목차 (Table of Contents)

• 목차 = ⅰ
• List of table = ⅳ
• List of figure = ⅴ
• Ⅰ. 서론 = 1
• Ⅱ. 이론적 배경 = 4
• 2.1 실크의 특성 및 정련 = 4
• 2.1.1 실크의 구조와 특성 = 4
• 2.1.2 세리신의 기능과 응용 = 7
• 2.1.3 실크의 정련 = 13
• 2.2 전해환원수를 이용한 실크의 정련 = 19
• 2.2.1 전해수의 정의와 특성 = 19
• 2.2.2 전해수 제조장치 = 21
• 2.2.3 전해수 생성메카니즘 = 25
• 2.2.4 전해수 응용 분야 = 26
• 2.3 표면개질 = 29
• 2.3.1 DMDHEU = 29
• 2.3.2 PU = 30
• 2.3.3 PEGDGE = 31
• Ⅲ. 실험 = 33
• 3.1 전해수 특성 실험 = 33
• 3.1.1 격막식 전해수 제조장치 = 33
• 3.1.2 전해수 성질 및 평가 = 33
• 3.2 전해수애 의한 실크의 정련 = 38
• 3.2.1 실험재료 = 38
• 3.2.2 실크정련 = 38
• 3.2.3 정련 평가 = 40
• 3.3 직물의 표면개질 실험 = 41
• 3.3.1 PET 표면개질 = 41
• 3.3.2 Cotton 표면개질 = 41
• 3.3.3 표면개질 측정방법 = 42
• Ⅳ. 결과 및 고찰 = 44
• 4.1 전해환원수의 특성 = 44
• 4.1.1 안정성 = 44
• 4.1.2 계면활성 = 49
• 4.1.3 세정력 = 49
• 4.1.4 침투 · 흡수력 = 52
• 4.1.5 표면장력 = 57
• 4.1.6 접촉각 = 58
• 4.1.7 전기전도도 = 60
• 4.2 전해 환원수의 실크 정련특성 = 61
• 4.3.1 실크의 정련율 = 61
• 4.2.2 정련직물의 특성 = 68
• 4.3 세리신에 의한 표면개질 = 74
• 4.3.1 PET의 표면개질 = 74
• 4.3.2 Cotton 표면개질 = 77
• Ⅴ. 결론 = 83
• References = 85
• ABSTRACT = 89