Introduction to thermal analysis : techniques and applications

목차 (Table of Contents)

• CONTENTS
• Preface = ⅸ
• 1. Introduction = 1
• 1.1 Definition and history = 1
• 1.2 Thermal analysis instruments = 3
• 1.3 Types of measurement = 3
• 1.4 The main techniques = 3
• 1.5 References = 4
• 2. Thermal events = 5
• 2.1 Reactions of solids = 5
• 2.2 References = 6
• 3. Thermogravimetry (TG) = 7
• 3.1 Introduction = 7
• 3.2 The balance = 7
• 3.3 Heating the sample = 10
• 3.4 The atmosphere = 12
• 3.5 The sample = 15
• 3.6 Temperature measurement and calibration = 15
• 3.7 Temperature programmers = 17
• 3.8 Interpretation of TG and DTG curves = 17
• 3.9 Applications of TG = 19
• 3.10 References = 21
• 4. Differential thermal analysis (DTA) and differential scanning calorimetry (DSC) = 23
• 4.1 Classical DTA = 23
• 4.2 Calorimetric DTA or heat-flux DSC = 25
• 4.3 Differential scanning calorimetry (DSC) = 25
• 4.4 Comparison of the principles of DTA and DSC = 28
• 4.5 Sample containers and sampling = 30
• 4.6 Quantitative aspects of DTA and DSC curves = 30
• 4.7 Interpretation of DTA and DSC curves = 34
• 4.8 Measurement of heat capacity = 35
• 4.9 Measurement of thermal conductivity = 38
• 4.10 Determination of phase diagrams = 41
• 4.11 General applications of DTA and DSC = 43
• 4.12 References = 49
• 5. Thermoptometry (TD) = 50
• 5.1 Introduction = 50
• 5.2 Thermomicroscopy = 50
• 5.3 Thermophotometry = 51
• 5.4 Thermoluminescence = 53
• 5.5 Electron microscopy = 54
• 5.6 References = 54
• 6. Thermodilatometry (TD) = 56
• 6.1 Basic principles = 56
• 6.2 Practical details = 57
• 6.3 Interpretation of results = 59
• 6.4 Applications of thermodilatometry = 60
• 6.5 References = 62
• 7. Thermomechanical analysis (TMA) = 63
• 7.1 Basic principles = 63
• 7.2 Practical details = 63
• 7.3 Applications of TMA = 64
• 7.4 References = 68
• 8. Dynamic mechanical analysis (DMA) or dynamic thermomechanometry = 69
• 8.1 Basic principles = 69
• 8.2 Applications of DMA = 77
• 8.3 References = 80
• 9. Combination of thermal analysis techniques = 81
• 9.1 Principles = 81
• 9.2 References = 85
• 10. Evolved gas analysis (EGA) = 86
• 10.1 Basic principles = 86
• 10.2 Evolved gas detection (EGD) = 86
• 10.3 Evolved gas analysis (EGA) = 88
• 10.4 Applications of EGD and EGA = 95
• 10.5 References = 97
• 11. Less-common techniques = 99
• 11.1 Emanation thermal analysis (ETA) = 99
• 11.2 Thermomagnetometry (TM) = 103
• 11.3 Thermoelectrometry = 107
• 11.4 Thermosonimetry (TS) and thermoacoustimetry = 110
• 11.5 References = 116
• 12. The use of microcomputers in thermal analysis = 117
• 12.1 Introduction = 117
• 12.2 Hardware requirements = 118
• 12.3 Software requirements = 121
• 12.4 Data storage = 121
• 12.5 Data processing = 121
• 12.6 Additional benefits = 122
• 12.7 Automation of thermal analysis equipment = 122
• 12.8 References = 126
• 13. Reaction kinetics from thermal analysis = 127
• 13.1 Introduction = 127
• 13.2 Heterogeneous reactions = 127
• 13.3 Formulation of the problem = 128
• 13.4 Differential methods = 134
• 13.5 Integral methods = 137
• 13.6 The influences of various parameters on the shapes of theoretical thermal analysis curves = 144
• 13.7 Conclusion = 150
• 13.8 References = 150
• 14. Purity determination using DSC = 152
• 14.1 Introduction = 152
• 14.2 Phase equilibria = 153
• 14.3 The DSC melting curve = 155
• 14.4 Corrections = 157
• 14.5 Step methods = 160
• 14.6 Conclusions = 160
• 14.7 References = 162
• 15. The literature and nomenclature of thermal analysis = 163
• 15.1 Books = 163
• 15.2 Reviews = 164
• 15.3 Conference proceedings = 165
• 15.4 Journals = 165
• 15.5 Manufacturer's literature = 166
• 15.6 The nomenclature of thermal analysis = 166
• 16. Thermal analysis equipment = 168
• 16.1 Choosing thermal analysis equipment = 168
• 16.2 Major suppliers of thermal analysis equipment = 169
• 17. Conclusion = 170
• Appendix A. Introductory experiments in thermal analysis = 171
• A.1 Differential scanning calorimetry (DSC) = 171
• A.2 Thermogravimetry (TG) = 173
• Appendix B. Thermal analysis software = 174
• B.1.2 Data capture and storage = 174
• B.3 Display of data = 180
• B.4 Modification of the data = 186
• B.5 Processing of the data = 196
• Appendix C. Explanation of the symbols used in the text = 203
• Index = 207