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Samarium Lutidinate 착물형성에 관한 열역학적 연구 = Thermodynamic Parameters of Samarium Lutidinate Complex Formation

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https://www.riss.kr/link?id=A2071999

저자

김인회 (화학과)
발행기관
建陽大學校(KONYANG UNIVERSITY)
학술지명
建陽論叢(JOURNAL OF KONYANG UNIVERSITY)
권호사항

Vol.- No.3 [1994]
발행연도
1994
작성언어
Korean
KDC
040.000
자료형태
학술저널
수록면

189-201(13쪽)
제공처
RISS
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다국어 초록 (Multilingual Abstract)

The thermodynamic parameters of formation of the 1:1 complex between samarium cation and lutidinate have been measured using potentiometric and calorimetric techniques in aqueous solution of 0.50M (NaClO₄) ionic strength at 25℃. The results have been compared with those for the other analogous heterocyclic carboxylate ligands. From the comparison of the thermodynamic data, it was found that the lutidinate ligand was coordinated to the samarium cation by forming the chelate through the ring nitrogen atom at position 1 and the carboxylate group at position 2 of the pyridine ring.

번역하기

The thermodynamic parameters of formation of the 1:1 complex between samarium cation and lutidinate have been measured using potentiometric and calorimetric techniques in aqueous solution of 0.50M (NaClO₄) ionic strength at 25℃. The results have b...

The thermodynamic parameters of formation of the 1:1 complex between samarium cation and lutidinate have been measured using potentiometric and calorimetric techniques in aqueous solution of 0.50M (NaClO₄) ionic strength at 25℃. The results have been compared with those for the other analogous heterocyclic carboxylate ligands. From the comparison of the thermodynamic data, it was found that the lutidinate ligand was coordinated to the samarium cation by forming the chelate through the ring nitrogen atom at position 1 and the carboxylate group at position 2 of the pyridine ring.