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      구형 Ni과 나노 YSZ Powder를 이용하여 제조한 Ni/YSZ Core-shell의 SOFC 연료극 특성 = Characteristics of SOFC Anode of Ni/YSZ Core-shell Manufactured Using sSpherical Ni and Nano YSZ Powders

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      https://www.riss.kr/link?id=A103557456

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      We reviewed the electrical properties of SOFC anode manufactured using spherical Ni and nano YSZ powder. When core-shell is fabricated by using submicron Ni as core and nano-sized YSZ as shell for SOFC anode, the electrical conductivity of the 0.2 μm Ni-YSZ core-shell was 3 times higher than that of 1.0 μm NiO or 1.0 μm Ni-YSZ. Hydrogen selectivity was similar at 800oC, but hydrogen selectivity and methane conversion rate under 750oC was 10~25% higher, Power density was more than 2 times, ASR was about 1/3, when exposed to H2 atmosphere at 750oC for a long time, Ni particles did not have any growth or cut off conduction path.
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      We reviewed the electrical properties of SOFC anode manufactured using spherical Ni and nano YSZ powder. When core-shell is fabricated by using submicron Ni as core and nano-sized YSZ as shell for SOFC anode, the electrical conductivity of the 0.2 μm...

      We reviewed the electrical properties of SOFC anode manufactured using spherical Ni and nano YSZ powder. When core-shell is fabricated by using submicron Ni as core and nano-sized YSZ as shell for SOFC anode, the electrical conductivity of the 0.2 μm Ni-YSZ core-shell was 3 times higher than that of 1.0 μm NiO or 1.0 μm Ni-YSZ. Hydrogen selectivity was similar at 800oC, but hydrogen selectivity and methane conversion rate under 750oC was 10~25% higher, Power density was more than 2 times, ASR was about 1/3, when exposed to H2 atmosphere at 750oC for a long time, Ni particles did not have any growth or cut off conduction path.

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      참고문헌 (Reference)

      1 S. P. Jing, "Sintering Behavior of Ni/Y2O3-ZrO2 Cermet Electrodes of Solid Oxide Fuel Cells" 3775-3782, 2003

      2 N. Q. Minh, "Science and Technology of Ceramic Fuel Cells" Elsevier Science B. V 147-160, 1995

      3 이민진, "SOFC anode용 나노구형 Ni(1-x)-M(x=0~0.15)(M=Co, Fe) alloy 분말 합성 및 그 특성" 한국세라믹학회 51 (51): 367-373, 2014

      4 C. H. Kuo, "Rigidity and Conductivity Percolation Thresholds in Particulate Composites" 43 (43): 397-403, 1995

      5 M. Marinsek, "Preparation of Ni-YSZ Composite Materials for Solid Oxide Fuel Cell Anodes by the Gel-percipitation" 86 (86): 383-389, 2000

      6 S. -D. Kim, "Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells" 177 (177): 931-938, 2006

      7 Y. T. An, "New fabrication technique for a Ni–YSZ composite anode from a core–shell structured particle" 207 : 64-68, 2012

      8 A. Utz, "Microstructure stability studies of Ni patterned anodes for SOFC" 192 : 565-570, 2011

      9 M. J Lee, "Fabrication and performance of solid oxide fuel cell anodes from core-shell structured Ni/yttria-stabilized zirconia (YSZ powder" 42 : 10110-10115, 2016

      10 강영진, "Electrical Conductivity of Ni-YSZ Anode for SOFCs According to the Ni Powder Size Variations in Core-shell Structure" 대한금속·재료학회 53 (53): 287-293, 2015

      1 S. P. Jing, "Sintering Behavior of Ni/Y2O3-ZrO2 Cermet Electrodes of Solid Oxide Fuel Cells" 3775-3782, 2003

      2 N. Q. Minh, "Science and Technology of Ceramic Fuel Cells" Elsevier Science B. V 147-160, 1995

      3 이민진, "SOFC anode용 나노구형 Ni(1-x)-M(x=0~0.15)(M=Co, Fe) alloy 분말 합성 및 그 특성" 한국세라믹학회 51 (51): 367-373, 2014

      4 C. H. Kuo, "Rigidity and Conductivity Percolation Thresholds in Particulate Composites" 43 (43): 397-403, 1995

      5 M. Marinsek, "Preparation of Ni-YSZ Composite Materials for Solid Oxide Fuel Cell Anodes by the Gel-percipitation" 86 (86): 383-389, 2000

      6 S. -D. Kim, "Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells" 177 (177): 931-938, 2006

      7 Y. T. An, "New fabrication technique for a Ni–YSZ composite anode from a core–shell structured particle" 207 : 64-68, 2012

      8 A. Utz, "Microstructure stability studies of Ni patterned anodes for SOFC" 192 : 565-570, 2011

      9 M. J Lee, "Fabrication and performance of solid oxide fuel cell anodes from core-shell structured Ni/yttria-stabilized zirconia (YSZ powder" 42 : 10110-10115, 2016

      10 강영진, "Electrical Conductivity of Ni-YSZ Anode for SOFCs According to the Ni Powder Size Variations in Core-shell Structure" 대한금속·재료학회 53 (53): 287-293, 2015

      11 T. Kawashima, "Analysis of Electrical Conduction Paths in Ni/YSZ Particulate Composites Using Percolation Theory" 37 (37): 1397-1403, 1996

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