The dye adsorption and antibacterial properties of composite polyacrylamide cryogels modified with ZnO

다국어 초록 (Multilingual Abstract)

The present study aimed to modify the surface of polyacrylamide cryogels (PAC) with ZnO nanorods(ZNR) to provide them with antibacterial properties. The synthesized ZNR-modified composite PAC(ZMC) characterized by AAS, FTIR, SEM, XRD, XPS, BET surface analysis and TGA studies. A study of theadsorption of Orange G (OG) and antibacterial effect was performed on the synthesized ZMC. The highestadsorption capacity was determined to be at a dye concentration of 142.79 mg/g at 400 ppm, and a pH of2. From the data obtained, it was found that adsorptionfitted the pseudo-second-order kinetic model andFreundlich isotherm. Modified cryogels could be desorbed in a very short time – such as 30 min – andreused approximately twenty times with 80% efficiency. While ZMC cryogels did not show antibacterialactivity in the dark, inhibition percentages were determined as 99.79

3.94% and 99.811.76%, at1.78 mg/mL cryogel application, MIC90 values were determined as 1.589

0.063 and 0.660

0.028 mg/mL for Escherichia coli, and Staphylococcus aureus, respectively under visible light. The results showed thatthe composite cryogels obtained had a very high potential to be applied both in the removal of dyes fromwastewater and in the purification of microorganism-contaminated water.

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