<P><B>Abstract</B></P> <P>In present work, we prepared nitrogen doped graphene oxide (N-GO) by using 1,3-xylenediamine (XDA) as nitrogen precursor which was further decorated with Co(OH)<SUB>2</SUB> nanoflowe...
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https://www.riss.kr/link?id=A107436098
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2017
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SCI,SCIE,SCOPUS
학술저널
709-719(11쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>In present work, we prepared nitrogen doped graphene oxide (N-GO) by using 1,3-xylenediamine (XDA) as nitrogen precursor which was further decorated with Co(OH)<SUB>2</SUB> nanoflowe...
<P><B>Abstract</B></P> <P>In present work, we prepared nitrogen doped graphene oxide (N-GO) by using 1,3-xylenediamine (XDA) as nitrogen precursor which was further decorated with Co(OH)<SUB>2</SUB> nanoflower. The physiochemical analysis such as X-ray photoelectron spectroscopy and scanning electron microscopy revealed the successful doping of nitrogen on GO and fine dispersion of Co(OH)<SUB>2</SUB> nanoflower on the surface of N-GO. The as prepared N-GO-Co(OH)<SUB>2</SUB> was electrochemically reduced (N-rGO-Co(OH)<SUB>2</SUB>) to precisely adjust its electrochemical properties. The N-rGO-Co(OH)<SUB>2</SUB> was used as a novel electrode modifier for the simultaneous detection of dopamine (DA) and uric acid (UA). From the combined effects of N-doping and excellent electrocatalytic properties of the Co(OH)<SUB>2</SUB> nanoflower, constructed sensor exhibited high electrochemical sensing activity with the wide linear response, limit of detection and limit of quantification of 1.0×10<SUP>−8</SUP> M and 3.0×10<SUP>−8</SUP> M for DA and 1.0×10<SUP>−7</SUP> M and 3.6×10<SUP>−7</SUP> M for UA respectively. The N-rGO-Co(OH)<SUB>2</SUB> nanocomposite showed long-term sensing stability, reproducibility and excellent analytical response in urine for DA and UA detection. Furthermore, N-rGO-Co(OH)<SUB>2</SUB> also revealed remarkable anti-interfering behavior towards other biomolecules including ascorbic acid (AA), serotonin (5-HT) and glucose (Glu). The N-rGO-Co(OH)<SUB>2</SUB> nanocomposite manifests intriguing application potential as the candidate for the application of the electrochemical sensor for simultaneous detection of DA and UA.</P>