<P><B>Abstract</B></P> <P>One of the most important challenges in the improvement of the lithium ion battery (LIB) for electric vehicle (EV) applications is its fast charging capability. However, currently used graphite ...
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https://www.riss.kr/link?id=A107510921
2017
-
SCOPUS,SCIE
학술저널
336-342(7쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>One of the most important challenges in the improvement of the lithium ion battery (LIB) for electric vehicle (EV) applications is its fast charging capability. However, currently used graphite ...
<P><B>Abstract</B></P> <P>One of the most important challenges in the improvement of the lithium ion battery (LIB) for electric vehicle (EV) applications is its fast charging capability. However, currently used graphite anode materials cannot meet this requirement for EVs. Herein, we demonstrate that surface modification of graphite using oxygen-deficient black titanium oxide (TiO<SUB>2−x</SUB>) is an efficient way to improve the fast charging capability of graphite anode material for LIB. The proposed surface engineered anode material, 1 wt% TiO<SUB>2-x</SUB> coated graphite anode material, at a high rate of 5 C-rate, exhibited 98.2% of the capacity obtained at a rate of 0.2 C without any degradation of other performances. Full cell tests adopting LiCoO<SUB>2</SUB> as a cathode material with TiO<SUB>2-x</SUB> coated graphite anode material also confirmed that the TiO<SUB>2-x</SUB> coating layer can improve the fast charging capability of graphite anode material. Such an improvement in the fast charging capability has mainly been attributed to the modified interface between the anode and the electrolyte by surface-engineering of the TiO<SUB>2-x</SUB> layer on the surface of graphite. These results show that the approach presented in this work, interfacial engineering of graphite using oxygen deficient TiO<SUB>2-x</SUB>, deserves to be regarded as one of the most promising ways to develop an anode material with fast charging capability for high power LIB for EV applications.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Core shell structured TiO<SUB>2-x</SUB>@graphite was synthesized via sol-gel method. </LI> <LI> TiO<SUB>2-x</SUB>@graphite anode showed much improved fast charging capability. </LI> <LI> Fast charging capability of TiO<SUB>2-x</SUB>@graphite was confirmed using full cell. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Catalytic Electron Transfer at Nanoporous Indium Tin Oxide Electrodes