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      KCI등재 SCIE SCOPUS

      Fabrication and Operation Characteristics of Electrolyte Impregnated Matrix and Cathode for Molten Carbonate Fuel Cells

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      https://www.riss.kr/link?id=A105257199

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      In this work, an electrolyte impregnated cathode and matrix were fabricated using (Li/Na)2CO3 powders for use in a molten carbonate fuel cell (MCFC). 87% of cathode pores and 90% of matrix pores were filled with electrolyte. A 25 cm2 single cell was used with electrolyte impregnated components. Cell performance of the single cell with electrolyte impregnated components showed a similar performance to a conventional single cell. After cell operation, electrolyte was found to have moved to the anode, cathode and matrix. The remaining electrolyte in matrix pores, cathode pores and anode pores are 94.62%, 42.75%, was 21.56%, respectively. By using electrolyte impregnated components, the change of the wet-seal height was decreased 86.78% (to 0.23 mm) comparing with the conventional cell. Electrolyte impregnated components will provide simplified pretreatment process and remove problems in the pretreatment condition such as non-uniform electrolyte melting.
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      In this work, an electrolyte impregnated cathode and matrix were fabricated using (Li/Na)2CO3 powders for use in a molten carbonate fuel cell (MCFC). 87% of cathode pores and 90% of matrix pores were filled with electrolyte. A 25 cm2 single cell was u...

      In this work, an electrolyte impregnated cathode and matrix were fabricated using (Li/Na)2CO3 powders for use in a molten carbonate fuel cell (MCFC). 87% of cathode pores and 90% of matrix pores were filled with electrolyte. A 25 cm2 single cell was used with electrolyte impregnated components. Cell performance of the single cell with electrolyte impregnated components showed a similar performance to a conventional single cell. After cell operation, electrolyte was found to have moved to the anode, cathode and matrix. The remaining electrolyte in matrix pores, cathode pores and anode pores are 94.62%, 42.75%, was 21.56%, respectively. By using electrolyte impregnated components, the change of the wet-seal height was decreased 86.78% (to 0.23 mm) comparing with the conventional cell. Electrolyte impregnated components will provide simplified pretreatment process and remove problems in the pretreatment condition such as non-uniform electrolyte melting.

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      참고문헌 (Reference)

      1 Kim, J.-E., "Using Aluminum and $Li_2CO_3$ Particles to Reinforce the ${\alpha}-LiAlO2$ Matrix for Molten Carbonate Fuel Cells" 34 (34): 9227-9232, 2009

      2 Williams, M. C., "The U.S. Department of Energy, Office of Fossil Energy Stationary Fuel Cell Program" 143 (143): 191-196, 2005

      3 Patil, K. Y., "The Effect of Lithium Addition on Aluminum-Reinforced ${\alpha}-LiAlO2$ Matrices for Molten Carbonate Fuel Cells" 36 (36): 6237-6247, 2011

      4 Morita, H., "Performance Analysis of Molten Carbonate Fuel Cell Using a Li/Na Electrolyte" 112 (112): 509-518, 2002

      5 Bischoff, M., "Operating Experience with a 250 kWel Molten Carbonate Fuel Cell (MCFC) Power Plant" 105 (105): 216-221, 2002

      6 Mitsushima, S., "Improvement of MCFC Cathode Stability by Additives" 47 (47): 3823-3830, 2002

      7 Lee, C.-W., "Improved Performance of Molten Carbonate Fuel Cells with $(Li/Na)_2CO_3$ Electrolytes by Using BYS Coated Cathode at Low Operating Temperatures" 42 (42): 18514-18523, 2017

      8 Min Goo Kang, "Fabrication of electrolyte-impregnated cathode by dry casting method for molten carbonate fuel cells" 한국화학공학회 29 (29): 876-885, 2012

      9 Saito, T., "Electrolyte Management of Molten-Carbonate Fuel Cells" 36 (36): 529-535, 1991

      10 Yuh, C.-Y., "Electrolyte Management in Liquid Electrolyte Fuel Cells" 65 (65): 75-86, 2015

      1 Kim, J.-E., "Using Aluminum and $Li_2CO_3$ Particles to Reinforce the ${\alpha}-LiAlO2$ Matrix for Molten Carbonate Fuel Cells" 34 (34): 9227-9232, 2009

      2 Williams, M. C., "The U.S. Department of Energy, Office of Fossil Energy Stationary Fuel Cell Program" 143 (143): 191-196, 2005

      3 Patil, K. Y., "The Effect of Lithium Addition on Aluminum-Reinforced ${\alpha}-LiAlO2$ Matrices for Molten Carbonate Fuel Cells" 36 (36): 6237-6247, 2011

      4 Morita, H., "Performance Analysis of Molten Carbonate Fuel Cell Using a Li/Na Electrolyte" 112 (112): 509-518, 2002

      5 Bischoff, M., "Operating Experience with a 250 kWel Molten Carbonate Fuel Cell (MCFC) Power Plant" 105 (105): 216-221, 2002

      6 Mitsushima, S., "Improvement of MCFC Cathode Stability by Additives" 47 (47): 3823-3830, 2002

      7 Lee, C.-W., "Improved Performance of Molten Carbonate Fuel Cells with $(Li/Na)_2CO_3$ Electrolytes by Using BYS Coated Cathode at Low Operating Temperatures" 42 (42): 18514-18523, 2017

      8 Min Goo Kang, "Fabrication of electrolyte-impregnated cathode by dry casting method for molten carbonate fuel cells" 한국화학공학회 29 (29): 876-885, 2012

      9 Saito, T., "Electrolyte Management of Molten-Carbonate Fuel Cells" 36 (36): 529-535, 1991

      10 Yuh, C.-Y., "Electrolyte Management in Liquid Electrolyte Fuel Cells" 65 (65): 75-86, 2015

      11 Lee, C.-W., "Effect of the Flow Directions on a $100cm^2$ MCFC Single Cell with Internal Flow Channels" 41 (41): 18747-18760, 2016

      12 Morita, H., "Degradation Mechanism of Molten Carbonate Fuel Cell Based on Long-Term Performance: Long-Term Operation by Using Bench-Scale Cell and Post-Test Analysis of the Cell" 195 (195): 6988-6996, 2010

      13 이성호, "Continuous Fabrication of Bio-Inspired Water Collecting Surface via Roll-Type Photolithography" 한국정밀공학회 1 (1): 119-124, 2014

      14 Yuh, C., "Carbonate Fuel Cell Materials" 15 (15): 457-462, 2006

      15 Huijsmans, J. P. P., "An Analysis of Endurance Issues for MCFC" 86 (86): 117-121, 2000

      16 이창환, "A New Levelling Process Using Skew-Arranged Roll Sets for the Doubly-Curved Plate" 한국정밀공학회 17 (17): 1275-1284, 2016

      17 Standard A., ""C373-88," Standard Test Method for Water Absorption, Bulk Density, Apparent Density and the Apparent Specific Gravity of Fired Whiteware Products American Society for Testing Materials"

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      학술지 이력

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      연월일 이력구분 이력상세 등재구분
      2023 평가예정 해외DB학술지평가 신청대상 (해외등재 학술지 평가)
      2020-01-01 평가 등재학술지 유지 (해외등재 학술지 평가) KCI등재
      2015-04-01 평가 SCIE 등재 (기타) KCI등재
      2008-06-23 학회명변경 영문명 : Korean Society Of Precision Engineering -> Korean Society for Precision Engineering
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      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 3.62 2.24 0
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0 0 0 0.21
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